A PROCESS FOR PREPARATION OF DICYANOCARBOXYLATE DERIVATIVES
    7.
    发明公开
    A PROCESS FOR PREPARATION OF DICYANOCARBOXYLATE DERIVATIVES 有权
    用于生产DICYANOCARBOXYLAT衍生物

    公开(公告)号:EP2702039A4

    公开(公告)日:2014-12-31

    申请号:EP12777422

    申请日:2012-02-02

    IPC分类号: C07C253/10 C07C255/19

    摘要: The present disclosure provides a process for preparing 2,3-dicyanopropionic acid ester of formula (I); said process comprising the following steps: i) treating an alkali metal cyanide dissolved in a solvent with a solution of 2-cyano-2-propenoic acid ester of formula (II) at a temperature ranging between 0° C. and 50° C. for a time period ranging between 2 hours and 15 hours followed by cooling below 20° C. to obtain a sodium salt of 2,3-dicyanopropionic acid ester of formula (I); and ii) neutralizing the sodium salt of 2,3-dicyanopropionic acid ester using a neutralizing agent to obtain a 2,3-dicyanopropionic acid ester of formula (I).

    CARBAZOLE DIOXAZINE PIGMENT AND A METHOD FOR ITS PREPARATION
    8.
    发明公开
    CARBAZOLE DIOXAZINE PIGMENT AND A METHOD FOR ITS PREPARATION 有权
    咔唑二恶嗪颜料及其制造方法

    公开(公告)号:EP3008133A4

    公开(公告)日:2016-11-02

    申请号:EP14810946

    申请日:2014-06-11

    摘要: The pigment is synthesized from 3-nitro-N-ethylcarbazole. The first step is nitration of 3-nitro-N-ethylcarbazole to form 3,6-dinitro-N-ethylcarbazole which is reduced to form 3-amino-6-nitro-N-ethylcarbazole. This amino compound is benzoylated to form 3-benzamido-6-nitro-N-ethylcarbazole which is then hydrogenated to form 6-amino-3-benzamido-N-ethylcarbazole. Condensation of 6-amino-3-benzamido-N-ethylcarbazole with chloranil provides an intermediate. Cyclization of the intermediate in the presence of a cyclization reagent provides the compound of Formula-I. The pigment has wavelength of maximum absorption (λmax) at 571 nm in dimethylformamide as a solvent.