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公开(公告)号:EP0008939B1
公开(公告)日:1983-02-16
申请号:EP79301816.9
申请日:1979-09-04
IPC分类号: C09D5/18 , D06M15/64 , C09K3/28 , C07D251/00
CPC分类号: D06M15/673 , C07D251/70 , C07F9/091 , C07F9/146 , C07F9/2408 , C07F9/2458 , C09D5/185 , C09K21/10 , C09K21/12
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公开(公告)号:EP0008244A1
公开(公告)日:1980-02-20
申请号:EP79301662.7
申请日:1979-08-15
CPC分类号: D06M15/244 , D04H1/587 , D04H1/64
摘要: There is provided a flame-retarded non-woven material which contains a mixture of flame retardant and vinyl chloride latex, wherein said flame retardant is
or
or a mixture thereof wherein a and b are integers independently selected from 1, 2, 3, 4 and 5, a plus b is from about 6 to about 10, c is an integer of from 1 to 4, and alkylene is a straight chain carbon group having from one to six carbon atoms; and wherein more than 50 percent (by weight) of said flame retardant consists of particles with a diameter of from about 2 to about 25 microns. The non-woven material combines flame retardance with strong and durable bonding to thermoplastic materials. It is useful in upholstery.-
公开(公告)号:EP0008939A2
公开(公告)日:1980-03-19
申请号:EP79301816.9
申请日:1979-09-04
IPC分类号: C09D5/18 , D06M15/64 , C09K3/28 , C07D251/00
CPC分类号: D06M15/673 , C07D251/70 , C07F9/091 , C07F9/146 , C07F9/2408 , C07F9/2458 , C09D5/185 , C09K21/10 , C09K21/12
摘要: There is disclosed an intumescent composition. The applicants disclose such compositions which impart durable flame retardancy to wood, which compositions comprise a cyclic nitrogen compound, a hydroxy-containing organo-phosphorus compound, and organo-phosphorus acid, and water, wherein:
a) said cyclic nitrogen compound is
wherein a, b, and c are integers selected from the group consisting of 1 and 2, a plus b plus c equal about 3 to 6, and X, X', and X" are independently selected from the group consisting of hydrogen and -CH 3 ;
b) said hydroxy-containing organo-phosphorus compound is selected from the group consisting of
and
and mixtures thereof, wherein d is an integer of from 0 to 2, e is an integer of from 0 to 2, f is an integer of from 1 to 3, and d plus e plus f equal 3; z is an integer of 0 to 1; x is an integer of 1 to 2, y is an integer of 1 to 2, and x plus y plus z eqal 3; R R 2 , and R 3 are selected from the group consisting of alkyl radicals containing from about 1 to about 6 carbon atoms and haloalkyl radicals containing from about 2 to about 6 carbon atoms, provided that when R 3 is haloalkyl it contains at least 3 carbon atoms; R 4 and R 5 are selected from the group consisting of hydrogen, alkyl radicals, and haloalkyl radicals, wherein said radicals contain from about 1 to about 6 carbon atoms; and the total number of carbon atoms in the R 1 , R 2 , R 3 , R 4 , and R 5 groups does not exceed about 14; and
c) said acid is selected from the group consisting of
and mixtures thereof, wherein R 6 , R 7 , R 8 and R 9 are independently selected from the group consisting of hydrogen, alkyl of from about 1 to about 3 carbon atoms, haloalkyl of from about 1 to about 3 carbon atoms, and hydroxyalkyl of from 1 to about 3 carbon atoms, provided that the total number of carbon atoms in the R 6 , R 7 , R°, and R 9 groups does not exceed about 5; wherein q is an integer of from 1 to 2, h and i are integers independently selected from the group consisting of 0, 1, and 2, and g plus h plus i equals 3; and wherein R'° and R" are independently selected from the group consisting of alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbons atoms and from 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing 2 to 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, haloalkoxy of from about 2 to about 6 carbon atoms and from about 1 to about 3 halogen atoms,
wherein R 12 is selected from the group consisting of alkylene of from about 2 to about 6 carbon atoms, haloalkylene of from about 3 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, polyalkyleneoxy containing 2 to 6 carbon atoms and 1 to 5 oxygen atoms, and hydroxyalkylene of from 3 to about 6 carbon atoms and 1 to 4 hydroxyls, and R 13 and R 14 are independently selected from the group consisting of hydrogen, hydroxyl, alkyl of from about 1 to about 6 carbon atoms, haloalkyl of from about 1 to about 6 carbon atoms and from about 1 to about 3 halogen atoms, hydroxy-polyalkyleneoxy containing about 2 to about 6 carbon atoms and 2 to 6 oxygen atoms, alkoxy of from about 1 to about 6 carbon atoms, hydroxyalkoxy of from about 2 to about 6 carbon atoms, and haloalkoxy of from about 2 to about 6 carbon atoms and 1 to about 3 halogen atoms, provided that the total number of carbon atoms in the R'° and R 11 groups does not exceed about 8.摘要翻译: 公开了一种膨胀组合物。 申请人公开了对木材赋予持久的阻燃性的组合物,该组合物包含环状氮化合物,含羟基的有机磷化合物和有机磷酸和水,其中:a)所述环状氮化合物是
,其中 a,b和c是选自1和2,a加b加c等于约3至6的整数,X,X min和X sec独立地选自氢和-CH 3; b)所述含羟基的有机磷化合物选自 及其混合物,其中d为0-2的整数,e为0至2的整数,f为从 1到3,d加e加f等于3; z为0〜1的整数; x是1〜2的整数,y是1〜2的整数,x + y + z eq 3; R 1 R 2和R 3选自含有约1至约6个碳原子的烷基和含有约2至约6个碳原子的卤代烷基,条件是当R 3为 卤代烷基含有至少3个碳原子; R 4和R 5选自氢,烷基和卤代烷基,其中所述基团含有约1至约6个碳原子; 并且R 1,R 2,R 3,R 4和R 5基团中的碳原子总数不超过约14; 和c)所述酸选自 及其混合物,其中R 6,R 7,R 8,R 9独立地选自氢,烷基 约1至约3个碳原子的卤代烷基,约1至约3个碳原子的卤代烷基和1至约3个碳原子的羟基烷基,条件是R 6,R 7中的碳原子总数 R 8,R 9和R 9不超过约5; 其中q是1至2的整数,h和i是独立地选自0,1和2的整数,并且g + h + i等于3; 并且其中R 1和R 2独立地选自约1至约6个碳原子的烷基,约1至6个碳原子的卤代烷基和1至约6个碳原子 3个卤素原子,含2至6个碳原子和2至6个氧原子的羟基聚亚烷基氧基,约1至6个碳原子的烷氧基,约2至约6个碳原子的羟基烷氧基,约2至约6个原子的卤代烷氧基 和约1至约3个卤素原子,其中R 1 2选自约2至约6个碳原子的亚烷基,约3至约6个碳原子的卤代亚烷基,和 约1至约3个卤素原子,含有2至6个碳原子和2至5个氧原子的聚亚烷基氧基,3至约6个碳原子和1至4个羟基的羟基亚烷基,R 1和R 3均为氢, 1> 4独立地选自氢,羟基,约1至约6个碳原子的烷基,f的卤代烷基 约1至约6个碳原子和约1至约3个卤素原子,含有约2至约6个碳原子和2至6个氧原子的羟基聚亚烷基氧基,约1至约6个碳原子的烷氧基, 约2至约6个碳原子,以及约2至约6个碳原子和1至约3个卤素原子的卤代烷氧基,条件是R 1和R 2中的碳原子总数< 1>组不超过约8。
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