公开(公告)号：EP1550170B1

公开(公告)日：2010-08-18

申请号：EP03751089.8

申请日：2003-10-07

申请人： Gen3 Partners, Inc.

发明人： LYUBOMIRSKIY, Alexander ,  PAVLOV, Valentinovich, Valeriy ,  TIMONOV, Mikhailovich, Alexander ,  LOGVINOV, Anatolijevich, Sergey ,  PIVUNOV, Ivanovich, Dmitriy ,  VASILJEVA, Viktorovna, Svetlana ,  SHKOLNIK, Nik ,  KOGAN, Sam

IPC分类号： H01M4/04

CPC分类号： H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

摘要： Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte containins an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/I within the range of potentials from -3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5x10`5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

公开(公告)号：EP1547172B1

公开(公告)日：2006-08-09

申请号：EP03754715.5

申请日：2003-09-15

申请人： Gen3 Partners, Inc.

发明人： TIMONOV, Mikhailovich, Alexander ,  LOGVINOV, Anatolijevich, Sergey ,  PIVUNOV, Ivanovich, Dmitriy ,  VASILJEVA, Viktorovna, Svetlana ,  SHKOLNIK, Nik ,  KOGAN, Sam

IPC分类号： H01M4/04

CPC分类号： H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

摘要： Application of a redox polymer of the poly [Me(R Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from -3.0 V to +1.5 V, and metal complex [Me(R Salen)] dissolved at a concentration of no less than 5.10-5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

公开(公告)号：EP1550170A1

公开(公告)日：2005-07-06

申请号：EP03751089.8

申请日：2003-10-07

申请人： Gen3 Partners, Inc.

发明人： LYUBOMIRSKIY, Alexander ,  PAVLOV, Valentinovich, Valeriy ,  TIMONOV, Mikhailovich, Alexander ,  LOGVINOV, Anatolijevich, Sergey ,  PIVUNOV, Ivanovich, Dmitriy ,  VASILJEVA, Viktorovna, Svetlana ,  SHKOLNIK, Nik ,  KOGAN, Sam

IPC分类号： H01M4/04

CPC分类号： H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

摘要： Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte containins an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/I within the range of potentials from -3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5x10`5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

公开(公告)号：EP1547172A1

公开(公告)日：2005-06-29

申请号：EP03754715.5

申请日：2003-09-15

申请人： Gen3 Partners, Inc.

发明人： TIMONOV, Mikhailovich, Alexander ,  LOGVINOV, Anatolijevich, Sergey ,  PIVUNOV, Ivanovich, Dmitriy ,  VASILJEVA, Viktorovna, Svetlana ,  SHKOLNIK, Nik ,  KOGAN, Sam

IPC分类号： H01M4/04

CPC分类号： H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

摘要： Application of a redox polymer of the poly [Me(R Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from -3.0 V to +1.5 V, and metal complex [Me(R Salen)] dissolved at a concentration of no less than 5.10-5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

摘要翻译： 聚[Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，其中两者都被浸没在含有有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性（浓度不小于0.01mol / l）的离子，以及溶解在金属络合物[Me（R-Salen） 浓度不小于5-10-5mol / l（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双 - （水杨醛）的残基， 乙二胺在希夫的基地。