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公开(公告)号：EP1550170B1
公开(公告)日：2010-08-18
申请号：EP03751089.8
申请日：2003-10-07
申请人： Gen3 Partners, Inc.
发明人： LYUBOMIRSKIY, Alexander , PAVLOV, Valentinovich, Valeriy , TIMONOV, Mikhailovich, Alexander , LOGVINOV, Anatolijevich, Sergey , PIVUNOV, Ivanovich, Dmitriy , VASILJEVA, Viktorovna, Svetlana , SHKOLNIK, Nik , KOGAN, Sam
IPC分类号： H01M4/04
CPC分类号： H01M4/137 , H01G9/0032 , H01G9/0036 , H01G9/04 , H01G11/48 , H01M4/0438 , H01M4/0466 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/667 , H01M4/668 , Y02E60/13
摘要： Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte containins an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/I within the range of potentials from -3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5x10`5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.
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公开(公告)号：EP1547172B1
公开(公告)日：2006-08-09
申请号：EP03754715.5
申请日：2003-09-15
申请人： Gen3 Partners, Inc.
发明人： TIMONOV, Mikhailovich, Alexander , LOGVINOV, Anatolijevich, Sergey , PIVUNOV, Ivanovich, Dmitriy , VASILJEVA, Viktorovna, Svetlana , SHKOLNIK, Nik , KOGAN, Sam
IPC分类号： H01M4/04
CPC分类号： H01M4/0438 , C08G12/06 , H01G9/0036 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/606 , Y02E60/13
摘要： Application of a redox polymer of the poly [Me(R Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from -3.0 V to +1.5 V, and metal complex [Me(R Salen)] dissolved at a concentration of no less than 5.10-5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.
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公开(公告)号：EP1807890A4
公开(公告)日：2010-07-28
申请号：EP04788465
申请日：2004-09-30
申请人： NIPPON CHEMICON , GEN3 PARTNERS INC
发明人： UCHI HIDENORI , TAMAMITSU KENJI , SUEMATSU SHUNZO , TSUMEDA SATORU , TIMONOV ALEXANDER M , LOGVINOV SERGEY A , SHKOLNIK NIKOLAY , KOGAN SAM
IPC分类号： H01M4/60 , H01G11/22 , H01G11/34 , H01G11/42 , H01G11/58 , H01M4/1399 , H01M10/056
CPC分类号： H01M4/60 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/602 , H01M10/0525 , H01M2004/028 , Y02E60/13
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4.发明授权ELECTRODE FOR ENERGY STORAGE DEVICES AND ELECTROCHEMICAL SUPERCAPACITOR BASED ON SAID ELECTRODE 有权电极储能设施和基于电化学电容器超级LEAD
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公开(公告)号：EP1807889A4
公开(公告)日：2009-12-16
申请号：EP04773641
申请日：2004-09-30
申请人： NIPPON CHEMICON , GEN3 PARTNERS INC
发明人： UCHI HIDENORI , TAMAMITSU KENJI , SUEMATSU SHUNZO , TSUMEDA SATORU , TIMONOV ALEXANDER M , LOGVINOV SERGEY A , SHKOLNIK NIKOLAY , KOGAN SAM
CPC分类号： H01G9/155 , H01M4/0438 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/602 , H01M10/0525 , Y02E60/13 , Y02T10/7022
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6.发明公开METHOD FOR PRODUCING ELECTRODE FOR ELECTROCHEMICAL ELEMENT AND METHOD FOR PRODUCING ELECTROCHEMICAL ELEMENT WITH THE ELECTRODE 审中-公开方法制造电极用于电化学元件及其制造方法用于生产电化学元件用铅
公开(公告)号：EP1889270A1
公开(公告)日：2008-02-20
申请号：EP05751144.6
申请日：2005-06-10
发明人： UCHI, Hidenori c/o NIPPON CHEMI-CON CORPORATION , TAMAMITSU, Kenji c/o NIPPON CHEMI-CON CORPORATION , SUEMATSU, Shunzo c/o NIPPON CHEMI-CON CORPORATION , TSUMEDA, Satoru c/o NIPPON CHEMI-CON CORPORATION , TIMONOV, Alexander, M. , LOGVINOV, Sergey, A , SHKOLNIK, Nikolay , KOGAN, Sam
CPC分类号： H01G11/48 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/86 , H01M4/0438 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , H01M4/606 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： To provide a method for producing an electrode for electrochemical element which is improved in energy density and is excellent in output characteristics. The present invention provides a method for producing an electrode for an electrochemical element, characterized by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area of 100 to 3000m2g-1 and having an average pore diameter in the range of 0.4 to 100nm, performing electrolysis polymerization by applying pulse voltage using said conductive porous material as an electrode in electrolyte solution to stack said monomers for polymerization, and forming a conductive polymer layer on the surface of the conductive porous material : wherein a thin and uniform electrode film is formed, namely the electrode for electrochemical element which is excellent in output characteristics and improves energy density is manufactured according to the method. In addition, the present invention provides a method for producing an electrochemical element, characterized by forming a conductive polymer layer on the surface of the conductive porous material within an outer casing by a step of absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area of 100 to 3000m2g-1 and having an average pore diameter in the range of 0.4 to 100nm forming a electrochemical cell by using the conductive porous material wherein the monomers for polymerization are absorbed in the pores, putting said electrochemical cell and the electrolyte solution in an outer casing , and performing electrolysis polymerization of the monomers for polymerization in said electrolyte solution by applying pulse voltage from a external electrode of the outer casing to stack said monomer for polymerization : wherein it is possible to produce an electrochemical element with the said electrode for the electrochemical element in the series of the steps through the electrolysis polymerization, thereby reducing the number of steps required for producing the electrochemical element.
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公开(公告)号：EP1547105A1
公开(公告)日：2005-06-29
申请号：EP03751085.6
申请日：2003-10-03
申请人： Gen3 Partners, Inc.
发明人： TIMONOV, Mikhailovich, Alexander , LOGVINOV, Anatolijevich, Sergey , PIVUNOV, Ivanovich, Dmitriy , VASILJEVA, Viktorovna Svetlana , SHKOLNIK, Nik , KOGAN, Sam
CPC分类号： H01M4/602 , H01G9/042 , H01G9/22 , H01G11/02 , H01G11/26 , H01G11/32 , H01G11/48 , Y02E60/13 , Y10T29/417
摘要： The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly-[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH30-, C2H50-, HO-, -CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/1 and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from -3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.
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8.发明公开METHOD FOR PRODUCING ELECTRODE FOR ELECTROCHEMICAL ELEMENT AND METHOD FOR PRODUCING ELECTROCHEMICAL ELEMENT WITH THE ELECTRODE 审中-公开方法制造电极用于电化学元件及其制造方法用于生产电化学元件用铅
公开(公告)号：EP1889270A4
公开(公告)日：2010-05-26
申请号：EP05751144
申请日：2005-06-10
申请人： NIPPON CHEMICON , GEN3 PARTNERS INC
发明人： UCHI HIDENORI , TAMAMITSU KENJI , SUEMATSU SHUNZO , TSUMEDA SATORU , TIMONOV ALEXANDER M , LOGVINOV SERGEY A , SHKOLNIK NIKOLAY , KOGAN SAM
CPC分类号： H01G11/48 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/86 , H01M4/0438 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , H01M4/606 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
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公开(公告)号：EP1807890A1
公开(公告)日：2007-07-18
申请号：EP04788465.5
申请日：2004-09-30
发明人： UCHI, Hidenori, NIPPON CHEMI-CON CORPORATION , TAMAMITSU, Kenji, NIPPON CHEMI-CON CORPORATION , SUEMATSU, Shunzo, NIPPON CHEMI-CON CORPORATION , TSUMEDA, Satoru, NIPPON CHEMI-CON CORPORATION , TIMONOV, Alexander, M. , LOGVINOV, Sergey A , SHKOLNIK, Nikolay , KOGAN, Sam
CPC分类号： H01M4/60 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/602 , H01M10/0525 , H01M2004/028 , Y02E60/13
摘要： To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula:and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.
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公开(公告)号：EP1547105B1
公开(公告)日：2007-06-20
申请号：EP03751085.6
申请日：2003-10-03
申请人： Gen3 Partners, Inc.
发明人： TIMONOV, Mikhailovich, Alexander , LOGVINOV, Anatolijevich, Sergey , PIVUNOV, Ivanovich, Dmitriy , VASILJEVA, Viktorovna Svetlana , SHKOLNIK, Nik , KOGAN, Sam
CPC分类号： H01M4/602 , H01G9/042 , H01G9/22 , H01G11/02 , H01G11/26 , H01G11/32 , H01G11/48 , Y02E60/13 , Y10T29/417
摘要： The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly-[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH30-, C2H50-, HO-, -CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/1 and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from -3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.
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