Composite material
    4.
    发明公开
    Composite material 失效
    复合材料

    公开(公告)号:EP0514157A3

    公开(公告)日:1995-04-26

    申请号:EP92304326.9

    申请日:1992-05-13

    摘要: An aromatic heterocyclic copolymer is produced by (a) reacting (i) an aromatic diaminoalkylthio compound, with (ii) an aromatic diamino compound and (iii) a dicarboxylic acid or a reactive derivative thereof to produce a precopolymer; and (b) heating the precopolymer to cause a thiazole ring closure reaction. This aromatic heterocylic copolymer may be incorporated as a reinforcing polymer in a molecular composite material.

    摘要翻译: 通过(a)使(ⅰ)芳族二氨基烷硫基化合物与(ⅱ)芳族二氨基化合物和(ⅲ)二羧酸或其活性衍生物反应来制备芳族杂环共聚物以制备预聚物; 和(b)加热预聚物以引起噻唑闭环反应。 该芳族杂环共聚物可以作为增强聚合物掺入分子复合材料中。

    Method of producing an aromatic polythiazole
    5.
    发明公开
    Method of producing an aromatic polythiazole 失效
    制备芳族聚噻唑的方法

    公开(公告)号:EP0457419A3

    公开(公告)日:1992-02-19

    申请号:EP91301564.0

    申请日:1991-02-26

    IPC分类号: C08G75/32 C08G73/06

    CPC分类号: C08G75/32 C08G73/06

    摘要: An aromatic polythiazole is produced from an aromatic diaminodithiol compound and a dicarboxylic acid derivative, by a method comprising the steps of: (a) selectively reacting the aromatic diaminodithiol compound salt with an alkyl halide having an optionally substituted alkyl group in an alkaline aqueous solvent, such that the hydrogen atoms in the thiol groups of the aromatic diaminodithiol compound are replaced by the alkyl groups; (b) polymerizing the resulting alkyl group-substituted aromatic diaminodithiol compound with the dicarboxylic acid derivative to form an aromatic polythiazole prepolymer; and (c) heating the aromatic polythiazole prepolymer to cause a thiazole ring closure reaction, thereby producing the aromatic polythiazole. By this method, the amino groups of the aromatic diaminodithiol compound salt are selectively reacted with the dicarboxylic acid derivative.

    Molecular composite material including aromatic polythiazole and method of producing same
    7.
    发明公开
    Molecular composite material including aromatic polythiazole and method of producing same 失效
    分子层材料,其包含芳族聚噻唑及其制备方法。

    公开(公告)号:EP0616000A3

    公开(公告)日:1995-08-02

    申请号:EP94301907.5

    申请日:1994-03-17

    IPC分类号: C08G75/32

    CPC分类号: C08G75/32

    摘要: The molecular composite material having excellent properties such as mechanical strength, heat resistance, solvent resistance, etc. is produced by (a) polymerizing an aromatic diaminodithiol compound, of which hydrogen atoms of thiol groups of aromatic diaminodithiol compound are substituted with substituted or unsubstituted alkyl groups, with a dicarboxylic acid derivative to form an aromatic polythiazole prepolymer, (b) dissolving the aromatic polythiazole prepolymer in an organic solvent to prepare a solution thereof; (c) adding a monomer of the matrix polymer to the solution to polymerize the monomer to the matrix polymer in the solution; (d) removing the organic solvent from a mixture of the aromatic polythiazole prepolymer and the matrix polymer; and (e) heating a mixture of the aromatic polythiazole prepolymer and the matrix polymer to cause a thiazole ring closure reaction of the aromatic polythiazole prepolymer.

    Method of producing an aromatic polythiazole
    8.
    发明公开
    Method of producing an aromatic polythiazole 失效
    维他命Zur Herstellung von aromatischem聚噻唑。

    公开(公告)号:EP0457419A2

    公开(公告)日:1991-11-21

    申请号:EP91301564.0

    申请日:1991-02-26

    IPC分类号: C08G75/32 C08G73/06

    CPC分类号: C08G75/32 C08G73/06

    摘要: An aromatic polythiazole is produced from an aromatic diaminodithiol compound and a dicarboxylic acid derivative, by a method comprising the steps of: (a) selectively reacting the aromatic diaminodithiol compound salt with an alkyl halide having an optionally substituted alkyl group in an alkaline aqueous solvent, such that the hydrogen atoms in the thiol groups of the aromatic diaminodithiol compound are replaced by the alkyl groups; (b) polymerizing the resulting alkyl group-substituted aromatic diaminodithiol compound with the dicarboxylic acid derivative to form an aromatic polythiazole prepolymer; and (c) heating the aromatic polythiazole prepolymer to cause a thiazole ring closure reaction, thereby producing the aromatic polythiazole. By this method, the amino groups of the aromatic diaminodithiol compound salt are selectively reacted with the dicarboxylic acid derivative.

    摘要翻译: 通过包括以下步骤的方法由芳族二氨基二硫醇化合物和二羧酸衍生物制备芳族聚噻唑:(a)使芳族二氨基二硫醇化合物盐与在碱性水溶剂中具有任选取代的烷基的烷基卤选择性反应, 使得芳族二氨基二硫醇化合物的硫醇基中的氢原子被烷基取代; (b)使所得的烷基取代的芳族二氨基二硫醇化合物与二羧酸衍生物聚合,形成芳族聚噻唑预聚物; 和(c)加热芳族多噻唑预聚物以引起噻唑闭环反应,从而产生芳族多噻唑。 通过该方法,芳族二氨基二硫醇化合物的氨基与二羧酸衍生物选择性地反应。