DIFLUORPHENYLPYRIMIDYLPYRIDIN-DERIVATE UND IHRE VERWENDUNG IN FLÜSSIGKRISTALLINEN MISCHUNGEN
    2.
    发明公开
    DIFLUORPHENYLPYRIMIDYLPYRIDIN-DERIVATE UND IHRE VERWENDUNG IN FLÜSSIGKRISTALLINEN MISCHUNGEN 失效
    DIFLUORPHENYLPYRIMIDYLPYRIDIN衍生物及其IN的液晶混合物

    公开(公告)号:EP0883618A1

    公开(公告)日:1998-12-16

    申请号:EP96944617.0

    申请日:1996-12-20

    IPC分类号: G02F1 C07D401 C07D405 C09K19

    摘要: The invention relates to difluorophenyl pyrimidyl pyridine derivatives of the formula (I), in which the symbols have the following meanings: X is N and Y is CH or X is CH and Y is N; R1, R2 are independently or both (a) an unbranched or branched alkyl chain with 1 to 20 atoms, in which (aa) one or a plurality of non-adjacent and non-terminal CH¿2?-groups can be replaced by -O-,-CO-O-, -O-CO-, -O-CO-O-, -Si(CH3)2-, and/or (ab) one or a plurality of H-atoms can be replaced by F, and/or (ac) the terminal CH3 group can be replaced by one of the chiral groups (1)-(7) (optically active or racemic); (b) hydrogen, wherein only one of the two radicals R?1, R2¿ may be H, provided that R1 may not be bonded to the pyridine ring by way of -CO-O- or -O-CO-O-; R?3, R4, R5¿ are independently or both hydrogen or a straight-chained or branched alkyl radical with 1-16 C-atoms (with or without an asymmetrical C-atom), in which one or a plurality of non-adjacent, non-terminal CH¿2?-groups can be replaced by -O-, and/ or one or a plurality of H-atoms of the alkyl radical can be substituted by -F; R?4 and R5¿ can also be -(CH¿2?)4- or-(CH2)5- together, when they are bound to a dioxolane system. Said derivatives are particularly suitable as constituents, in particular, for ferroelectric liquid crystal mixtures.