摘要:
Process for making a polyisocyanurate composite which process comprises combining a polyisocyanate, a polyether polyol and a trimerization catalyst with a to-be-bonded material to form a reactive composite, and allowing in a next step this reactive composite to react at elevated temperature, wherein the amount of the reactive binder composition is 1 - 60 % by weight and the amount of the to-be-bonded material is 40 - 99 % by weight, both calculated on the amount of the reactive binder composition plus the amount of th e to-be-bonded material, wherein the amount of the polyisocyanate and the polyol is such that the index is 150 - 10000, characterized in that the polyol is a polyol having an average equivalent weight of 100 - 2500 and an oxyethylene content of at least 50 % by weight. The reactive composite is claimed as well together with composites obtained from this process and from these reactive composites.
摘要:
A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 150 to 5000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 80- 100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'- diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25°C and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 20-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 50-90% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyo l a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b) and wherein the hardblock content is at most 49%.
摘要:
A stable partly cured polyisocyanate composition is disclosed which comprises polyisocyanurate (intermediate polyisocyanurate comprising material) and which is further curable. Furthermore a process for making the intermediate (partly cured) polyisocyanurate comprising materialand a process for further curing the partly cured polyisocyanurate composition is disclosed. Also polyisocyanurate comprising materials made or obtainable from partly cured intermediate polyisocyanurate comprising material are disclosed and processes for further curing a partly cured polyisocyanurate comprising composition (intermediate material).
摘要:
A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate-reactive composition, wherein the reaction is conducted at an isocyanate index of 1600 to 100,000 and in the presence of a trimerisation catalyst, wherein the polyisocyanate comprises a) 75-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'- diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25°C and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 25-0% by weight of another polyisocyanate (polyisocyanate b), the amount of polyisocyanate a) and polyisocyanate b) being calculated on the total amount of this polyisocyanate a) and polyisocyanate b), and wherein the isocyanate-reactive composition comprises a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 1100-5000 and an oxyethylene (EO) content of 65-100% by weight and b) 20-0% by weight of one or more other isocyanate-reactive compounds, the amount of polyol a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b).
摘要:
A curable polyisocyanate composition comprising at least one or more polyisocyanate compounds, at least one or more trimerization catalyst compounds, at least one or more aldehyde compounds wherein the aldehyde compound is selected from compounds with the structure R-CHO wherein CHO is an aldehyde group and R is a hydrocarbyl group selected from an alkyl, alkenyl or aryl having 1-50 carbon atoms, preferably 1-20 carbon atoms, and at least one or more compounds selected from compounds which comprise a carboxamide group having the structure -CO-NH 2 and/or from compounds which comprise a group having the structure -CO-NH-CO-.
摘要:
The invention provides a cross-linkable mixture of thermoplastic polyurethanes and ethylenic unsaturated compounds and thermoset materials that can obtained therefrom. The invention also provides application of the cross-linkable mixtures and processes in a solvent-less coating process.
摘要:
A process for preparing a polyisocyanurate polyurethane material, which process comprises reacting a polyisocyanate and an isocyanate -reactive composition, wherein the reaction is conducted at an isocyanate index of 150 to 1500 and in the presence of a trimerisation catalyst, wherein the polyisocyanate consists of a) 80-100% by weight of diphenylmethane diisocyanate comprising at least 40%, preferably at least 60% and most preferably at least 85% by weight of 4,4'-diphenylmethane diisocyanate and/or a variant of said diphenylmethane diisocyanate which variant is liquid at 25'C and has an NCO value of at least 20% by weight (polyisocyanate a), and b) 20-0% by weight of another polyisocyanate (polyisocyanate b), and wherein the isocyanatereactive composition consists of a) 80-100% by weight of a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 150-1000, an average molecular weight of 600-5000, an oxyethylene (EO) content of 75-100% by weight and b) 200% by weight of one or more other isocyanate-reactive compounds excluding water, the amount of polyol a) and isocyanate-reactive compound b) being calculated on the total amount of this polyol a) and compound b).