公开(公告)号：EP0638361B1

公开(公告)日：1999-07-28

申请号：EP94906390.3

申请日：1994-02-15

申请人： IDEMITSU KOSAN COMPANY LIMITED ,  PETROLEUM ENERGY CENTER (PEC) a juridical incorporated foundation

发明人： IINO, Akira ,  IWAMOTO, Ryuichiro ,  MITANI, Tsuyoshi

IPC分类号： B01J23/85

CPC分类号： B01J23/85 ,  B01J37/0236 ,  C10G45/08

摘要： A suspension of alumina gel obtained by dispersing alumina gel into pure water so that the concentration of alumina is in the range of 0.1-12 wt.% and an aqueous solution of metallic salt in which a compound of metal in VIA group and that of metal in VIII group are dissolved are mixed, and the resultant mixture is dried and hardened by evaporating the water while agitating the mixture, whereby these metal components can be supported effectively on the alumina gel up to a sufficiently high support quantity. This enables a high-performance catalyst composition constituting a catalyst the performance, such as activity, of which is superior to that of a hydrogen treated catalyst, and such as a conventional hydrodesulfurized molten catalysts to be obtained easily. When this catalyst composition is brought into contact with sulfur-containing hydrocarbon in the presence of hydrogen, hydrocarbons from which sulfur has been sufficiently removed can be obtained.

公开(公告)号：EP0638361A1

公开(公告)日：1995-02-15

申请号：EP94906390.3

申请日：1994-02-15

申请人： IDEMITSU KOSAN COMPANY LIMITED

发明人： IINO, Akira ,  IWAMOTO, Ryuichiro ,  MITANI, Tsuyoshi

IPC分类号： B01J23/85

CPC分类号： B01J23/85 ,  B01J37/0236 ,  C10G45/08

摘要： A suspension of alumina gel obtained by dispersing alumina gel into pure water so that the concentration of alumina is in the range of 0.1-12 wt.% and an aqueous solution of metallic salt in which a compound of metal in VIA group and that of metal in VIII group are dissolved are mixed, and the resultant mixture is dried and hardened by evaporating the water while agitating the mixture, whereby these metal components can be supported effectively on the alumina gel up to a sufficiently high support quantity. This enables a high-performance catalyst composition constituting a catalyst the performance, such as activity, of which is superior to that of a hydrogen treated catalyst, and such as a conventional hydrodesulfurized molten catalysts to be obtained easily. When this catalyst composition is brought into contact with sulfur-containing hydrocarbon in the presence of hydrogen, hydrocarbons from which sulfur has been sufficiently removed can be obtained.

摘要翻译： 由氧化铝凝胶分散到纯水中得到的氧化铝凝胶中的悬浮液也是如此氧化铝的浓度在0.1-12％（重量）的范围内，在金属盐，其中在VIA族金属的化合物和没有金属的wässrige溶液 在第VIII族溶解混合，并将得到的混合物干燥，并通过蒸发水同时搅拌混合物，由此论文金属组分可在氧化铝凝胶有效地支持至足够高的承载量硬化。 这使得构成催化剂的性能，颜色的高性能的催化剂组合物：其中所有的如活性，优于做了氢处理过的催化剂，并且如常规的加氢脱硫催化剂熔融到可以容易地获得。 当该催化剂组合物被带入与在氢的存在含硫的烃接触，从该硫已被充分去除的烃可制得。