摘要:
The invention relates to a hybrid crystallized solid having an organic/inorganic matrix having a three-dimensional structure, and containing an inorganic lattice of indium-based metal centers interconnected via organic ligands consisting of the entity -O 2 C-C 6 H 3- N 3 -CO 2 -. Said solid is referred to as IHM-2-N 3 and has an X-ray diffraction pattern as given below.
摘要:
The invention relates to a crystallized hybrid solid having an organic/inorganic matrix with a three-dimensional structure, and containing an inorganic lattice having aluminum-based metal centers interconnected via organic ligands consisting of the entity -O 2 C-C 6 H 3- N 3 -Cθ 2 -. Said solid is referred to as MIL-53-AI-N 3 and has an X-ray diffraction pattern as given below.
摘要:
The invention relates to a crystallized hybrid solid having an organic/inorganic matrix and a three-dimensional structure, containing an inorganic lattice of zinc metal centers connected together by organic ligands consisting of the entities -O 2 C-C 6 H 3 -N 3 -CO 2 - and C 6 H 12 N 2 . Said solid is referred to as DMOF-1-N 3 and has an X-ray diffraction pattern such as given below.
摘要:
The invention relates to a hybrid crystallized solid having an organic/inorganic matrix having a three-dimensional structure, and containing an inorganic lattice of aluminum-based metal centers interconnected via organic ligands consisting of the entity -O 2 C-C 6 H 3- N 3 -CO 2 -. Said solid is referred to as CAU-1-N 3 and has an X-ray diffraction pattern as given below.
摘要:
The invention relates to a novel hybrid crystallized material, referred to as IHM-2, having an organic/inorganic matrix, and containing an inorganic lattice of metal centers containing the element indium, which are interconnected via organic ligands consisting of the entity 2-aminoterephthalate O 2 C-C 6 H 3 -NH 2 -CO 2 . Said material has an X-ray diffraction pattern as given below.
摘要:
The invention relates to a method for preparing, from a hybrid solid having an organic/inorganic matrix, MOF-HH 2 , a hybrid crystallized functionalized solid having an organic/inorganic matrix and at least one reactive group containing a triazole ring, said method including: i) introducing, into a polar solvent S1, said hybrid crystallized solid IvIOF-NH 2 , at least one organic compound Q containing an azide N 3 function and at least one intermediate reactant R containing a nitrite NO 2 function; ii) reacting said reaction mixture; iii) introducing, into the reaction medium, at least one reactant A having an alkyne function or an activated cyanide function, at least one Cu catalyst C and at least one polar solvent S2; iv) reacting said reaction mixture; v) filtration and then washing; and vi) drying said hybrid crystallized functionalized solid.