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公开(公告)号：EP2654952B1
公开(公告)日：2019-02-20
申请号：EP11808896.2
申请日：2011-12-15
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2.发明公开PROCEDE D'HYDRODESULFURATION DE COUPES ESSENCES UTILISANT UN CATALYSEUR A BASE D'HETEROPOLYANIONS PIEGES DANS UN SUPPORT SILICIQUE MESOSTRUCTURE 审中-公开方法加氢脱硫汽油馏分与基于在介孔结构的二氧化硅载体甲CATALYST INCLUDED杂多阴离子
公开(公告)号：EP2654952A1
公开(公告)日：2013-10-30
申请号：EP11808896.2
申请日：2011-12-15
发明人： MARCHAND, Karin , DEVERS, Elodie , CHAUMONNOT, Alexandra , BONDUELLE, Audrey , DUFAUD, Véronique , LEFEBVRE, Frédéric , BADER, Manuela , LOPES SILVA, Susana
CPC分类号： C10G45/10 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/033 , B01J37/10 , B01J37/20 , B01J2229/20 , C10G45/04 , C10G45/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/4018 , C10G2400/02
摘要： The invention relates to a method for the hydrodesulphurisation of at least one gasoline fraction, using a catalyst comprising, in the oxide form thereof, at least one metal selected from the group VIB metals and/or at least one metal from the group VIII metals of the periodic table, present in the form of at least one polyoxometalate having formula (HhXxMmOy)q-, wherein: X is an element selected from among phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), said element being taken alone; M is one or more elements selected from among molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co); O is oxygen; H is hydrogen; h is an integer between 0 and 12; x is an integer between 0 and 4; m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18; y is an integer between 17 and 72; and q is an integer between 1 and 20, said polyoxometalates being present inside a mesostructured silica oxide matrix having a pore size between 1.5 and 50 nm and amorphous walls with a thickness of between 1 and 30 nm. The catalyst is sulphurised prior to use in said method.
摘要翻译： 至少一种汽油馏分实现一种催化剂，包含在其氧化物形式，至少一种第VIB族金属的加氢脱硫的方法，和/或选自周期表第VIII族的至少一种金属，存在于至少一种的形式 式的多金属氧酸盐（HhXxMmOy）●worin X是选自磷，硅，硼，镍和钴中选择的元素，M是一种或从钼，钨，镍和钴中选择多个元素（一个或多个）中，h是整数 从0-12，x为0-4的整数，m为整数5，6，7，8，9，10，11，12和/或18，y为17至72的整数，q是一个 的1〜20的整数，多金属氧酸盐是具有1.5-50纳米的孔径和对具有厚度1-30纳米的无定形壁的介孔结构的氧化硅基质中存在，所述催化剂在工艺使用前sulphured。
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3.发明公开PROCEDE D'HYDROTRAITEMENT D'UNE COUPE HYDROCARBONEE DE POINT D'EBULLITION SUPERIEUR A 250 °C EN PRESENCE D'UN CATALYSEUR SULFURE PREPARE AU MOYEN D'UN OLIGOSACCHARIDE CYCLIQUE 有权工艺制氢治疗与沸点ÜBER250℃，烃基硫化物催化剂单的存在请使用至少一个环状低聚糖
公开(公告)号：EP2598612A2
公开(公告)日：2013-06-05
申请号：EP11743262.5
申请日：2011-06-24
IPC分类号： C10G45/08 , B01J23/652 , B01J23/85 , B01J37/08
CPC分类号： B01J27/19 , B01J21/04 , B01J23/652 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/20 , B01J38/14 , C10G45/08 , C10G45/10 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/04
摘要： The invention relates to a method for preparing a catalyst containing at least one Group VIII metal, at least one Group VIB metal, and at least one support, wherein the method includes, in series: i) one of the steps selected from among: i1) a step of placing a precatalyst, containing said Group VIII metal, said Group VIB metal, and said support, in contact with a cyclic oligosaccharide containing at least six glucopyranose subunits bonded at α-(1,4); a step i2) of placing the support in contact with a solution containing a precursor of said Group VIII metal, a precursor of said Group VIB metal, and a cyclic oligosaccharide containing at least six glucopyranose subunits bonded at α-(1,4); and i3) a first step of placing said support in contact with a cyclic oligosaccharide containing at least six glucopyranose subunits bonded at α-(1,4), followed by a second step of placing the solid from the first step in contact with a precursor of said Group VIII metal and a precursor of said Group VIB metal; ii) a drying step; and iii) a heat-treatment step.
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4.发明授权CATALYSEUR UTILISABLE EN HYDROTRAITEMENT COMPRENANT DES METAUX DES GROUPES VIII ET VIB ET PREPARATION AVEC DE L'ACIDE ACETIQUE ET DU SUCCINATE DE DIALKYLE C1-C4 有权CATALYST FOR USE加氢脱硫金属集团VII和VIB族和制备用乙酸和二烷基C1-C4
公开(公告)号：EP2512662B1
公开(公告)日：2014-05-07
申请号：EP10805252.3
申请日：2010-12-08
发明人： MARCHAND, Karin , GUICHARD, Bertrand , DIGNE, Mathieu , REBEILLEAU, Michael , LOPEZ , Sylvie , HUGON, Antoine , BONDUELLE, Audrey
CPC分类号： B01J27/14 , B01J23/28 , B01J23/75 , B01J27/19 , B01J37/0201 , C10G45/04 , C10G45/08 , C10G45/46 , C10G45/48 , C10G47/12 , C10G49/04 , C10G2300/1055 , C10G2300/202 , C10G2300/70 , C10G2400/04
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5.发明公开PROCEDE D'HYDRODESULFURATION DE COUPES GAZOLES UTILISANT UN CATALYSEUR A BASE D'HETEROPOLYANIONS PIEGES DANS UN SUPPORT SILICIQUE MESOSTRUCTURE 审中-公开柴油馏分的加氢脱硫方法与基于在介孔结构的二氧化硅载体甲CATALYST INCLUDED杂多阴离子
公开(公告)号：EP2654951A1
公开(公告)日：2013-10-30
申请号：EP11808892.1
申请日：2011-12-15
申请人： IFP Energies nouvelles , CNRS
发明人： MARCHAND, Karin , CHAUMONNOT, Alexandra , BONDUELLE, Audrey , ROY-AUBERGER, Magalie , DUFAUD, Véronique , LEFEBVRE, Frédéric , BADER, Manuela , LOPES SILVA, Susana
CPC分类号： B01J35/1019 , B01J27/186 , B01J27/19 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/1042 , B01J35/1061 , B01J37/10 , B01J37/20 , C10G45/08 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4018
摘要： The invention relates to a method for the hydrodesulphurisation of at least one diesel fraction, using a catalyst comprising, in the oxide form thereof, at least one metal selected from the group VIB metals and/or at least one metal from the group VIII metals of the periodic table, present in the form of at least one polyoxometalate having formula (HhXxMmOy)q-, wherein: X is an element selected from among phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), said element being taken alone; M is one or more elements selected from among molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co); O is oxygen; H is hydrogen; h is an integer between 0 and 12; x is an integer between 0 and 4; m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18; y is an integer between 17 and 72; and q is an integer between 1 and 20, said polyoxometalates being present inside a mesostructured silica oxide matrix having a pore size between 1.5 and 50 nm and amorphous walls with a thickness of between 1 and 30 nm. The catalyst is sulphurised prior to use in said method.
摘要翻译： 本发明涉及一种用于至少一个柴油馏分的加氢脱硫的方法，使用一种催化剂，包含，在其N-氧化物形式，选自VIB族金属和/或选自下组的至少一种金属VIII族金属中的至少一种金属 周期表中，存在于具有至少一个式多金属氧酸盐的形式（HhXxMmOy）●worin：X是选自磷（P），硅（Si），硼（B），镍中选出的元素（Ni）和 钴（Co），所述元件被单独服用; M是选自钼（Mo），钨（W），镍（Ni）和钴（Co）中的一种或多种元素; O是氧; H是氢; h为0至12之间的整数; x为0和4之间的整数; m等于5的整数，6，7，8，9，10，11，12和18; y是17和72之间的整数; 并且q是1至20之间的整数，所述多金属氧酸盐存在具有1.5至50纳米和非晶形的壁之间的孔尺寸，厚度1和30 nm之间的介孔结构的二氧化硅氧化物基质的内部。催化剂在使用前硫化 所述方法。
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6.发明公开PROCEDE D'HYDROCRAQUAGE DE COUPES HYDROCARBONNEES UTILISANT UN CATALYSEUR A BASE D'HETEROPOLYANIONS PIEGES DANS UN SUPPORT OXYDE MESOSTRUCTURE 有权FOR加氢裂化的烃馏分与基于在介孔结构氧化物载体的催化剂的方法。包含杂多阴离子
公开(公告)号：EP2655554A1
公开(公告)日：2013-10-30
申请号：EP11808891.3
申请日：2011-12-15
申请人： IFP Energies nouvelles , CNRS
发明人： MARCHAND, Karin , CHAUMONNOT, Alexandra , BONDUELLE, Audrey , DUFAUD, Véronique , LEFEBVRE, Frédéric , BADER, Manuela , LOPES SILVA, Susana
IPC分类号： C10G3/00 , B01J27/185 , B01J35/10 , C10G47/12 , B01J27/186 , B01J37/16 , C10G65/12 , B01J27/19 , B01J23/847 , B01J27/199 , B01J23/888 , B01J32/00
CPC分类号： C10G47/12 , B01J27/186 , B01J27/19 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/10 , B01J37/20 , C10G3/46 , C10G3/48 , C10G3/50 , C10G65/12 , C10G2300/1011 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4018 , Y02P30/20
摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q-, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.
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7.发明公开CATALYSEUR UTILISABLE EN HYDROTRAITEMENT COMPRENANT DES METAUX DES GROUPES VIII ET VIB ET PREPARATION AVEC DE L'ACIDE ACETIQUE ET DU SUCCINATE DE DIALKYLE C1-C4 有权CATALYST FOR USE加氢脱硫金属集团VII和VIB族和制备用乙酸和二烷基C1-C4
公开(公告)号：EP2512662A1
公开(公告)日：2012-10-24
申请号：EP10805252.3
申请日：2010-12-08
发明人： MARCHAND, Karin , GUICHARD, Bertrand , DIGNE, Mathieu , REBEILLEAU, Michael , LOPEZ , Sylvie , HUGON, Antoine , BONDUELLE, Audrey
CPC分类号： B01J27/14 , B01J23/28 , B01J23/75 , B01J27/19 , B01J37/0201 , C10G45/04 , C10G45/08 , C10G45/46 , C10G45/48 , C10G47/12 , C10G49/04 , C10G2300/1055 , C10G2300/202 , C10G2300/70 , C10G2400/04
摘要： The invention relates to a catalyst that can be used in hydrotreatment methods, comprising an amorphous support based on alumina, phosphorus, a dialkyl succinate C1-C4, acetic acid, and a hydro-dehydrogenating function comprising at least one element of group VIII and at least one element of the group VIB, preferably consisting of cobalt and molybdenum, the Raman spectrum of the catalyst comprising the strongest bands characteristic of the Keggin heteropolyanions (974 and/or 990 cm
-1 ), the dialkyl succinate C1-C4 and the acetic acid (896 cm
-1 ). Preferably, the dialkyl succinate used is dimethyl succinate and its main band is 853 cm
-1 . The invention also relates to the method for preparing said catalyst, wherein a catalytic precurser comprising the elements of the group VIB and the group VIII, especially the molybdenum-cobalt couple, and phosphorus, that have been introduced by impregnation, then dried at a temperature lower than 180°C, is impregnated by the dialkyl succinate C1-C4, the acetic acid and the phosphorus compound, if the latter has not already been previously fully introduced, and then, after maturation, is dried to a temperature lower than 180°C before being optionally sulfurated. The invention further relates to the use of said catalyst in any hydrotreatment method.-
8.发明授权PROCEDE D'HYDROTRAITEMENT D'UNE COUPE HYDROCARBONEE DE POINT D'EBULLITION SUPERIEUR A 250 °C EN PRESENCE D'UN CATALYSEUR SULFURE PREPARE AU MOYEN D'UN OLIGOSACCHARIDE CYCLIQUE 有权工艺制氢治疗与沸点ÜBER250℃，烃基硫化物催化剂单的存在请使用至少一个环状低聚糖
公开(公告)号：EP2598612B1
公开(公告)日：2014-10-15
申请号：EP11743262.5
申请日：2011-06-24
IPC分类号： C10G45/08 , B01J23/652 , B01J23/85 , B01J37/08
CPC分类号： B01J27/19 , B01J21/04 , B01J23/652 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J35/002 , B01J37/0009 , B01J37/0201 , B01J37/0203 , B01J37/086 , B01J37/20 , B01J38/14 , C10G45/08 , C10G45/10 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2300/4018 , C10G2400/04
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9.发明授权
公开(公告)号：EP2106430B1
公开(公告)日：2013-05-08
申请号：EP07871807.9
申请日：2007-12-07
CPC分类号： C10G65/04 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/08 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/42 , Y02P30/20
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