摘要:
The invention provides a base coat composition comprising a dispersion in an aqueous carrier for the composition of polymer microparticles, the polymer microparticles being a mixture of:
(a) 5 to 95% by weight of addition polymer microparticles having a crosslinked core and a stabilising mantle containing salt forming groups and (b) 95 to 5% by weight of addition polymer microparticles having polyoxyalkylene stabiliser units derived from C₁₋₄ alkoxypolyoxyalkylene containing monomers.
摘要:
Novel azo compounds are esters or substitued amides of an azobiscarboxylic acid defined by the formula in which R and R 1 are independently hydrogen or a methyl group, R 2 is an alkyl group containing from 1 to 4 carbon atoms, X is oxygen or a group NR 3 where R 3 is hydrogen or a grouping n has the value 2, 3 or 4 and p is zero or an integer from 1 to 100, preferably from 1 to 50. The compounds are useful as free radical-forming initiators for the polymerisation of ethylenically unsaturated monomers, in either organic or aqueous media according to the solubility properties of the compounds.
摘要:
A silane functional oligomer for use in the formulation of coating compositions having good clarity which has at least one hydrolysable silane group and which is the reaction product of ; (i) a silane coupling agent having a hydrolysable silane group and a secondary amine group, (ii) a polyisocyanate having more than one tertiary isocyanate group, and containing at least 6% by weight of NCO groups, and (iii) optionally, compound having single isocyanate reactive group.
摘要:
A silane functional oligomer for use in the formulation of coating compositions having good clarity which has at least one hydrolysable silane group and which is the reaction product of ;
(i) a silane coupling agent having a hydrolysable silane group and a secondary amine group, (ii) a polyisocyanate having more than one tertiary isocyanate group, and containing at least 6% by weight of NCO groups, and (iii) optionally, compound having single isocyanate reactive group.
摘要:
A curing composition comprising a silane functional acrylic polymer component and a silane functional oligomer component. The polymer component is a co-polymer of functional silyl group-containing units derived from monomers of Formula:- CH₂=CR¹CO₂(CH₂) a L The oligomer component is of formula E(GKL)₆ in which E is derived from a multifunctional isocyanate oligomer, G is of general formula:- -[0(CH₂)₅CO] c [O(CH₂) d OCO(CH₂)₂]- and K is of general formula:- -[NR⁵(CH₂) m ]- and where L is a group of Formula
摘要:
Azocarboxylic esters useful as polymerisation initiators, especially for polymerisation in aqueous medium, have the general formula in which R is the residue of an aliphatic polyhydroxy compound R(OH) q+1 after removal of one hydroxyl group therefrom, R, is a methyl or ethyl group or a grouping of the formula -COO(C n H 2n O) p -R(OH) q ; R 2 is a methyl group or a βcarboxyethoxy group and R 3 is a methyl group or an ethyl group, or R 2 and R 3 together with the intermediate carbon atom form a cyclohexyl group: R 4 is a methyl group and R 6 is a methyl group, an ethyl group, a β-carboxyethoxy group or a β-methoxy-ββ-dimethylethyl group, or R. and R 5 together with the intermediate carbon atom form a cyclohexyl group n has one or more of the values 2. 3 and 4. p is zero or an integer from 1 to 100, preferably from 1 to 50, and q has the value 2 or 4. The esters can be prepared by reacting a corresponding azonitrile or azobisnitrile with a stoichiometrically equivalent amount of an aceral or ketal of the formula wherein R 6 is hydrogen or an alkyl or aryl group and R 7 is an alkyl or artl group, or R 6 and R 7 together with the intermediate carbon atom form a cyclohexyl group, in the presence of hydrogen chloride gas under anhydrous conditiond, followed by hydrolysis of the product.
摘要翻译:可用作聚合引发剂的芳族羧酸酯,特别是用于在水性介质中的聚合,具有通式,其中R是从其中除去一个羟基后的脂族多羟基化合物R(OH)q + 1的残基,R1是 甲基或乙基或式-COO(C n H 2n O)p R(OH)q的基团; R2是甲基或β-羧乙氧基,R3是甲基或乙基,或R2和R3与中间碳原子一起形成环己基:R4是甲基,R5是甲基,乙基 基团,β-甲氧基-β-二甲基乙基的β-羧基乙氧基或R4和R5与中间体碳原子一起形成环己基基团n具有值2,3和4中的一个或多个,p为零 或1至100,优选1至50的整数,q的值2为4.酯可以通过使相应的偶氮腈或偶氮二腈与化学计量当量的式CHEM的丙烯酸或缩酮反应来制备 >其中R6是氢或烷基或芳基,R7是烷基或第一个基团,或R6和R7与中间体碳原子一起形成环己基,在无水条件下在氯化氢气体存在下,然后水解 该产品。
摘要:
Novel azo compounds are esters or substitued amides of an azobiscarboxylic acid defined by the formula in which R and R 1 are independently hydrogen or a methyl group, R 2 is an alkyl group containing from 1 to 4 carbon atoms, X is oxygen or a group NR 3 where R 3 is hydrogen or a grouping n has the value 2, 3 or 4 and p is zero or an integer from 1 to 100, preferably from 1 to 50. The compounds are useful as free radical-forming initiators for the polymerisation of ethylenically unsaturated monomers, in either organic or aqueous media according to the solubility properties of the compounds.