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公开(公告)号：EP0031645A3
公开(公告)日：1981-07-15
申请号：EP80304149
申请日：1980-11-20
申请人： FISONS plc
IPC分类号： C07C107/02 , C08F04/04 , C07D231/18
CPC分类号： C07C255/65 , C08F4/04
摘要： There is described a process for the production of a compound of formula I,
in which at least one each of Ri, R 2 and R 3 , and of R 4 , R 5 and R 6 , represents an electron withdrawing group, or one of R 1 , R 2 and R 3 together with one of R 4 , R 5 and R 6 form a -CO- group, and the remainder of Ri, R 2 , R 3 , R 4 , R 5 and R 6 , which may be the same or different, each represent an electron withdrawing group, alkyl, cycloalkyl, phenyl or phenylalkyl,
or R 1 and R 2 , or R 4 and R 5 , and R 1 and R 4 , may together form a -(CH 2 )n- chain, in which n is a whole number up to 5, the alkyl, cycloalkyl, phenyl or phenylalkyl group or the -(CH 2 ) n ,- chain optionally being substituted, which comprises reacting a compound of formula II,
in which Ria, R 2 a and R 3 a have the same significances as Ri, R 2 , and R 3 above, and some additional significances, with a compound of formula III,
in which R 4 a, R 5 a and R 6 a have the same significances as R 4 , R 5 and R 6 above, and some additional significances, the reaction being carried out in an aqueous medium in the presence of a base and a surfactant.-
公开(公告)号：EP0145220A3
公开(公告)日：1985-10-23
申请号：EP84307460
申请日：1984-10-30
CPC分类号： C08F26/02
摘要： In a process for producing a polymer of monoallylamine comprising polymerizing monoallylamine, the polymerization is carried out using as a monomer inorganic acid salts (e.g., hydrochloride, sulfate, etc.) of monoallylamine in the presence of an azo type radical initiator such as 2,2'-azobis(2-methylpropionamidoxime), 2,2'-azobis(2-methyl- propionhydroxamic acid), etc. in a polar solvent such as water, an aqueous solution of zinc chloride, etc. By the process, polymers of monoallylamine having a high degree of polymrization can be obtained in high yield.
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3.发明公开Process for production of sterically stabilised, wholly non-charged aqueous polymer dispersions 失效生产非稳定的非充气水性聚合物分散体的方法
公开(公告)号：EP0095263A3
公开(公告)日：1984-02-29
申请号：EP83302507
申请日：1983-05-04
CPC分类号： C08F2/24
摘要： Sterically stabilised aqueous polymer dispersions free from charged species are made by emulsifying in water ethylenically unsaturated monomer(s), soluble in water to the extent of 0.8% - 8% by weight but giving rise to a polymer which is insoluble, and polymerising the monomer(s) in that state in the presence of (a) a non-ionisable azo initiator which is water-soluble and substantially monomer-insoluble and (b) a block or graft copolymer stabiliser of specified structure.
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4.发明公开Thermoplastic resins having excellent thermal resistance and moldability and processes for preparing same 失效具有优异耐热性和可塑性的热塑性树脂及其制备方法
公开(公告)号：EP0259868A3
公开(公告)日：1988-10-19
申请号：EP87113216
申请日：1987-09-09
发明人： Sasaki, Isao , Yamamoto, Naoki , Mori, Hiroshi , Nakata, Akira
IPC分类号： C08F293/00 , C08G81/02 , C08G63/68 , C08F04/04 , G02B01/04 , C08G63/06 , C08G63/18 , C08F220/10 , C08F212/06 , C08F222/30
CPC分类号： C08G63/685 , C08F293/00
摘要： Disclosed are thermoplastic resins comprising block copolymers composed of polyester segments and vinyl polymer segments and having excellent thermal resistance and moldability, as well as several processes for preparing same. Among these thermoplastic resins, block copolymers formed of amorphous aromatic polyester segments and polystyrene resin segments are also useful as optical resins.
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公开(公告)号：EP0107145A3
公开(公告)日：1985-10-30
申请号：EP83110159
申请日：1983-10-12
申请人： BAYER AG
发明人： Rahlwes, Dieter, Dr. , Niesen, Bernd , Goossens, John, Dipl. Ing. , Wallpott, Gottfried , Matner, Martin, Dr.
摘要： Kationische Latices lassen sich in einfacher Weise da durch herstellen, daß man nichtionische Monomere mit bis zu 10 Gew.-% an kationischen Comonomeren in Emulsion in Gegenwart einer kationischen Azoverbindung polymeri siert.
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6.发明公开Catalyst components for alpha olephine-polymerizing catalysts and procedure for manufacturing same 失效α-烯烃聚合催化剂的催化剂组分及其制造方法
公开(公告)号：EP0240324A3
公开(公告)日：1987-10-28
申请号：EP87302811
申请日：1987-03-31
申请人： NESTE OY
发明人： Garoff, Thomas
CPC分类号： C08F10/00 , C08F4/6548
摘要： A catalyst component for an alpha-olefin polymerization catalyst (comprising an organoaluminium compound, an external electron donor and a solid catalyst component obtained by reaction of a magnesium-containing compound with a titanium halogen compound) is prepared by the steps of:
(a) precipitating a water-soluble magnesium compound from an aqueous solution thereof using an alkali; (b) separating the solid magnesium component and dissolving it in hydrochloric acid; (c) evaporating the resultant solution until dry; (d)heating the salt mixture obtained at 130 to 150°C; (e) dissolving the magnesium component in ethanol; (f) drying the ethanolic solution of the magnesium component by periodic azeotropic distillation; (g) precipitating a solid carrier component from the ethanolic solution; and (h) reacting the solid carrier component with a titanium halogen compound in the presence of an internal electron donor or without an electron donor.摘要翻译： 通过以下步骤制备用于α-烯烃聚合催化剂（包含有机铝化合物，外部电子给体和通过含镁化合物与钛卤素化合物反应获得的固体催化剂组分）的催化剂组分：（a） 使用碱从水溶液中沉淀出水溶性镁化合物; （b）分离固体镁组分并将其溶解在盐酸中; （c）将所得溶液蒸发至干; （d）加热在130-150℃获得的盐混合物; （e）将镁组分溶解在乙醇中; （f）通过定期共沸蒸馏干燥镁组分的乙醇溶液; （g）从乙醇溶液中沉淀固体载体组分; 和（h）使固体载体组分与钛卤素化合物在内部电子给体存在下或没有电子给体存在下反应。
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公开(公告)号：EP0095233A3
公开(公告)日：1984-03-21
申请号：EP83301719
申请日：1983-03-28
发明人： Harada, Susumu , Hasegawa, Sakuro
CPC分类号： C08F26/02
摘要： By polymerizing an inorganic acid salt of monoallyl amine in a polar solvent in the presence of a radical initiator having, in its molecule, an azo group and a group having cationic nitrogen atom, a polymer of monoallylamine having a high degree of polymerization can be obtained in a high yield.
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8.发明公开Improved process for preparing 2,2'-azobis(2,4-dimethylpentanenitrile) and use of the product as a polymerization initiator 失效制备2,2'-偶氮二（2,4-二甲基苯并噻唑）的改进方法和作为聚合引发剂的产品的使用
公开(公告)号：EP0034437A3
公开(公告)日：1981-10-28
申请号：EP81300452
申请日：1981-02-03
IPC分类号： C07C107/02 , C07C121/00 , C08F04/04
CPC分类号： C08F4/04 , C07C255/65
摘要： A process for the preparation of 2,2'-azobis (2,4-dimethylpentanenitrile) with improved filtering and drying characteristics is described comprising reacting 2-amino-2,4-dimethylpentanenitrile with a metal hypochlorite in the presence of water, a mixture of hexadecyl- trimethylammoniumchloride with dioctyldimethylammonium chloride (or other mixture of tetra-alkylammonium surfactants of specified formula) and ionic bromide wherein the equivalent ratio of ionic bromide to surface active compound is 0.4:1 - 12:1 and the reaction temperature is about -10°C to about 30°C.
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公开(公告)号：EP0142962A3
公开(公告)日：1986-01-15
申请号：EP84307725
申请日：1984-11-08
发明人： Ueda, Toshio , Kato, Tadashi , Mukai, Ryuichi , Harada, Susumu , Sato, Yoshinori
CPC分类号： C08F8/30 , C08F8/02 , C08F8/10 , C08F2810/30 , C08F126/02
摘要： Poly(allylamine salt) of high polymerization degree is obtained in high yield by the polymerization of monoallylamine salt with a specified radical-polymerization initiator having in the molecule an azo group. Various poly(allylamine) derivatives are obtained by reacting said poly(allylamine salt) with cyanic acid salts, acrylic compounds, or formic acid and formaldehyde.
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10.发明公开Process for producing aqueous suspension containing organic azo compound as polymerization initiator 失效生产包含有机AZO化合物的水性悬浮液作为聚合反应器的方法
公开(公告)号：EP0077211A3
公开(公告)日：1985-05-29
申请号：EP82305418
申请日：1982-10-12
摘要： A stable aqueous suspension containing an organic azo compound as polymerization initiator in fine particles, containing substantially no organic solvent and containing no foam which damages dispersing stability of the aqueous suspension and retards polymerization rate can be formed by dissolving an organic azo compound in an organic solvent, emulsifying the resulting solution by adding water and a dispersing agent A and a dispersing agent B therto with stirring, and removing the organic solvent from the emulsified liquid preferably under reduced pressure.
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