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公开(公告)号：EP0107457A1
公开(公告)日：1984-05-02
申请号：EP83306236.7
申请日：1983-10-14
CPC分类号： C07C209/16 , C07C211/04
摘要： Manufacture of methylamines using a catalyst comprising a levynite-type zeolite, especially zeolite Nu-3. In one preferred form of the invention the use of the sodium/hydrogen form of zeolite Nu-3 leads to selective production of monomethylamine (production of both di- and tri-methylamine being depressed). In a further preferred form of the invention the use of the hydrogen form of zeolite Nu-3 achieves selective production of di- and tri-methylamine and suppresses the formation of trimethylamine, the latter being the least in demand commercially of the three methylamines.
摘要翻译： 使用含有黑云母型沸石，特别是zeelite Nu-3的催化剂制造甲胺。 在本发明的一个优选形式中，使用钠/氢形式的沸石Nu-3导致选择性地生产单甲胺（二甲胺和三甲胺都被抑制的产生）。 在本发明的另一优选形式中，氢形式的沸石Nu-3的使用实现了二 - 和三 - 甲胺的选择性生产，并抑制三甲胺的形成，其中三甲胺的商业需求最少。
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公开(公告)号：EP0107457B1
公开(公告)日：1986-02-26
申请号：EP83306236.7
申请日：1983-10-14
CPC分类号： C07C209/16 , C07C211/04
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4.发明公开
公开(公告)号：EP0118193A3
公开(公告)日：1987-07-01
申请号：EP84300582
申请日：1984-01-30
CPC分类号： B01J21/20
摘要： Deactivation of silica, alumina, silica-alumina and aluminosilicate amination catalysts by coke is inhibited by carrying out the amination reaction in the presence of hydrogen. Alternatively, the coked catalysts may be regenerated in the presence of a stream of hydrogen or of hydrogen and ammonia at somewhat lower temperatures than those commonly used in processes for coke removal by oxidation, thereby reducing the risk of structural damage to the catalyst.
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公开(公告)号：EP0076034B1
公开(公告)日：1985-05-15
申请号：EP82304482.1
申请日：1982-08-25
发明人： Tompsett, Alan John
IPC分类号： C07C85/06
CPC分类号： C07C209/16
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公开(公告)号：EP0118193A2
公开(公告)日：1984-09-12
申请号：EP84300582.8
申请日：1984-01-30
CPC分类号： B01J21/20
摘要： Deactivation of silica, alumina, silica-alumina and aluminosilicate amination catalysts by coke is inhibited by carrying out the amination reaction in the presence of hydrogen. Alternatively, the coked catalysts may be regenerated in the presence of a stream of hydrogen or of hydrogen and ammonia at somewhat lower temperatures than those commonly used in processes for coke removal by oxidation, thereby reducing the risk of structural damage to the catalyst.
摘要翻译： 通过在氢气存在下进行胺化反应来抑制二氧化硅，氧化铝，二氧化硅 - 氧化铝和铝硅酸盐胺化催化剂的失活。 或者，焦化的催化剂可以在氢气流或氢气和氨的存在下在比通常用于通过氧化除焦的方法中常用的那些温度稍低的温度下再生，从而降低对催化剂的结构损伤的风险。
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公开(公告)号：EP0076034A1
公开(公告)日：1983-04-06
申请号：EP82304482.1
申请日：1982-08-25
发明人： Tompsett, Alan John
IPC分类号： C07C85/06
CPC分类号： C07C209/16
摘要： A process for the manufacture of methylamines comprises reacting a feed comprising methanol and/or dimethylether and ammonia over a binderless zeolite A catalyst, preferably a binderless zeolite 5A catalyst. Use of binderless zeolite 5A makes the process attractively selective to dimethylamine in preference to mono- and tri- methylamine. In addition, if the catalyst is essentially free of alkali metal it is not only more active than similar catalysts containing alkali metal but also considerably more selective.
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