摘要:
A commercially available anatase titania catalyst is shown to be catalytically active towards the formation of methacrolein from formaldehyde and propionaldehyde with conversions and selectivities close to 90%. This titania catalyst is readily available, non-toxic, and can be used with formaldehyde and a variety of other aldehyde compounds to make α,β-unsaturated aldehyde compounds. This process benefits from low raw material costs and is economically advantaged due to the elimination of catalyst separation. An additional advantage of this method involves the ability of the catalyst to be fully regenerated after a calcination step at 450° C. in air. This process shows promising stability and selectivity during lifetime studies, particularly when performed in the presence of a hydrogen carrier gas.
摘要:
The present invention relates to a fluorination process, comprising: an activation stage comprising contacting a fluorination catalyst with an oxidizing agent-containing gas flow for at least one hour; and at least one reaction stage comprising reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of the fluorination catalyst, so as to produce a fluorinated compound.
摘要:
This catalyst regeneration method for a COS conversion catalyst is a regeneration method for a Ba/TiO 2 COS conversion catalyst for hydrolyzing carbonyl sulfide (COS) in gasified gases in which a carbon starting material is gasified. Used COS conversion catalyst is dried after water washing, immersed in an aqueous solution of a barium salt for a prescribed period of time, and fired after drying. Thereby, it is possible to make the COS conversion catalyst carry an active component again on the surface thereof and thus regenerate the COS conversion catalyst.
摘要翻译:用于COS转化催化剂的催化剂再生方法是用于水解碳原料气化气化气体中的硫化羰(COS)的Ba / TiO 2 COS转化催化剂的再生方法。 水洗后将COS转化催化剂干燥,浸渍在钡盐水溶液中规定的时间,干燥后进行烧成。 由此,可以使COS转化催化剂在其表面上再次含有活性成分,从而再生COS转化催化剂。
摘要:
The present invention provides a catalyst for producing a hydrocarbon from a syngas, including one of a cobalt metal and a combination of a cobalt metal and cobalt oxides; zirconium oxides; and a noble metal; supported by a catalyst support mainly composed of silica, wherein a content of impurities in the catalyst is less than or equal to 0.15 mass%; a producing method and regenerating method thereof; and a producing method of the hydrocarbon by using the catalyst.
摘要:
There is provided a method for regenerating a spent dehydrogenation catalyst used in the conversion of n-paraffin to olefin. The method comprises method steps for removing the coke by treating the catalyst with an ozone-oxygen stream followed by an oxygen stream. The catalyst is stabilized by passing a nitrogen stream and the stabilized catalyst is rejuvenated by passing an air-nitrogen stream containing a halogenated hydrocarbon. This is followed by reducing the metal oxide in the catalyst by passing hydrogen-nitrogen stream.
摘要:
In a NO x removal catalyst used for removing nitrogen oxides in flue gas, when a silica (Si) component as an inhibitor that causes an increase in a SO 2 oxidation rate accumulates on a surface of the catalyst, the silica component accumulating on the surface of the catalyst is dissolved, thereby regenerating the catalyst. Accordingly, the inhibitor such as the silica component covering the surface of the NO x removal catalyst can be removed, thereby enabling to provide a catalyst without having an increase in the SO 2 oxidation rate of the regenerated NO x removal catalyst.
摘要:
Provided is a method for cleaning a used denitration catalyst, which prevents release of mercury to the atmosphere by collecting and removing mercury which would have been released to the atmosphere in the process of cleaning the used denitration catalyst. The method comprises immersing the used denitration catalyst mainly composed of titanium oxide and having been used in exhaust gas containing mercury in a cleaning liquid, and stirring the cleaning liquid to dissolve and remove catalyst poisons including the mercury from the used denitration catalyst, wherein a waste gas generated in the step of stirring the cleaning liquid is conducted to a flue having a mercury removal device so as to remove the mercury, and then vented to the atmosphere.
摘要:
An in-situ method for regenerating a deactivated catalyst removes a calcium sulfate layer masking active catalyst sites. A reducing agent converts the calcium sulfate to calcium oxide, which is then removed, by reintrainment into the flue gas steam using soot blowers or sonic horns. The method is particularly useful for regenerating selective catalytic reduction (SCR) catalysts used to remove nitrogen oxides from flue gas produced by combustion of coal from the Powder River Basin. The method can be practiced using existing SCR system hardware, and without removing the SCR system from service.