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公开(公告)号：EP1095065B1
公开(公告)日：2005-07-20
申请号：EP99957170.6
申请日：1999-06-09
IPC分类号： C08F2/04
CPC分类号： C08F2/06 , Y02P20/544
摘要： A method of producing a polymer comprises the steps of forming a homogeneous reaction mixture comprising at least one addition polymerisable monomer, a supercritical fluid, and a stabiliser, wherein the stabiliser comprises a chain which is soluble in the supercritical fluid and a functional end-group which is not polymerisable by a free-radical mechanism, and polymerising said at least one monomer in the reaction mixture. In a preferred system for polymerising acrylic monomers, the fluid comprises supercritical carbon dioxide and the stabiliser comprises an acid-functionalised perfluoropolyether.
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公开(公告)号：EP1095065A1
公开(公告)日：2001-05-02
申请号：EP99957170.6
申请日：1999-06-09
IPC分类号： C08F2/04
CPC分类号： C08F2/06 , Y02P20/544
摘要： A method of producing a polymer comprises the steps of forming a homogeneous reaction mixture comprising at least one addition polymerisable monomer, a supercritical fluid, and a stabiliser, wherein the stabiliser comprises a chain which is soluble in the supercritical fluid and a functional end-group which is not polymerisable by a free-radical mechanism, and polymerising said at least one monomer in the reaction mixture. In a preferred system for polymerising acrylic monomers, the fluid comprises supercritical carbon dioxide and the stabiliser comprises an acid-functionalised perfluoropolyether.
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