Asymmetric esters of fatty acids useful as lubricants
    1.
    发明公开
    Asymmetric esters of fatty acids useful as lubricants 审中-公开
    不对称酯on on Sch Sch Sch en。。。。。。。

    公开(公告)号:EP2444388A1

    公开(公告)日:2012-04-25

    申请号:EP10382263.1

    申请日:2010-10-06

    摘要: Composition comprising at least one ester of one or more saturated C 18 fatty acids and an alcohol, wherein the fatty acids have between 1 and 3 pairs of vicinal ester groups of formula R 1 COO-, the two vicinal ester groups in each pair being different, R 1 is a radical independently selected from linear or branched (C 1 -C 18 ) alkyl; and the alcohol is selected from the group consisting of a (C 1 -C 15 ) linear or branched monohydric alcohol and a (C 2 -C 6 ) polyhydric alcohol having between 2 and 4 hydroxyl groups obtainable by a process comprising: a) epoxidizing a product comprising at least an ester of an unsaturated C 18 fatty acid and of an alcohol; followed by ring opening of the epoxide and b) reacting the compound obtained in step a) with a (C 1 -C 18 ) linear or branched carboxylic acid different from the one used in step a). The composition obtainable by the process of the invention is useful as lubricant base stock oil or as an additive to modulate the viscosity and/or the pour point of lubricant compounds.

    摘要翻译: 包含至少一种或多种饱和C 18脂肪酸和醇的酯的组合物,其中脂肪酸具有1至3对式R 1 COO-的邻位酯基团,每对中的两个连位酯基团不同 ,R 1是独立地选自直链或支链(C 1 -C 18)烷基的基团; 并且所述醇选自(C 1 -C 15)直链或支链一元醇和具有2至4个羟基的(C 2 -C 6)多元醇,其可通过以下方法获得,所述方法包括:a)环氧化 至少包含不饱和C 18脂肪酸和醇的酯的产物; 然后环氧化物开环,和b)使步骤a)中获得的化合物与不同于步骤a)中使用的(C 1 -C 18)直链或支链羧酸反应。 通过本发明的方法获得的组合物可用作润滑剂基础油或用作调节润滑剂化合物的粘度和/或倾点的添加剂。