公开(公告)号：EP1060791A4

公开(公告)日：2001-07-18

申请号：EP99906506

申请日：1999-02-26

申请人： JAPAN ENERGY CORP

发明人： MATSUZAWA KENJI ,  AIMOTO KOHJIROH ,  SEKI KAZUHIRO

IPC分类号： B01J21/04 ,  B01J21/06 ,  B01J27/02 ,  B01J27/04 ,  B01J27/053 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  C07B61/00 ,  C07C5/22 ,  C07C5/27 ,  C07C6/10 ,  C07C9/15 ,  C07C9/16 ,  C07C45/28 ,  C07C49/813

CPC分类号： B01J21/066 ,  B01J27/053 ,  B01J35/1076 ,  C07C5/2213 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2521/06 ,  Y02P20/582 ,  C07C9/16

摘要： A method for a solid acid catalyst which contains sulfuric acid, exhibits a satisfactorily high activity even when formed into moldings, and also has a satisfactory mechanical strength and an easiness to handle sufficient to practical operation. The carrier of the catalyst is composed of a part comprising zirconia and/or zirconia hydrate and a part comprising alumina and/or alumina hydrate, and the method (a) comprises a step preparing a carrier which has a pore diameter distribution from 0.05 to 10 νm showing a peak in the range of 0.05 to 1 νm and a step supporting sulfuric acid on the carrier, or (b) comprises a step preparing a carrier which has a pore volume of 0.05 to 0.5 ml/g in the range of pore diameter of 0.05 to 1 νm and a pore volume less than 0.05 ml/g in the range of pore diameter more than 1 νm and up to 10 νm and a step supporting sulfuric acid on the carrier.

公开(公告)号：EP1052280A4

公开(公告)日：2002-03-06

申请号：EP99973305

申请日：1999-12-02

申请人： JAPAN ENERGY CORP

发明人： MATSUZAWA KENJI ,  AIMOTO KOHJIROH

IPC分类号： B01J21/06 ,  B01J27/053 ,  B01J37/20 ,  C07C5/22 ,  C10G35/06 ,  C10G45/60 ,  B01J27/055 ,  B01J32/00 ,  C10G61/00

CPC分类号： B01J21/066 ,  B01J27/053 ,  B01J37/20 ,  C07C5/226 ,  C07C2521/06 ,  C07C2523/40 ,  C07C2523/74 ,  C10G35/06 ,  C10G45/60

摘要： A method for isomerization of a hydrocarbon which comprises providing a solid acid catalyst comprising a carrier containing a part comprising zirconia and/or hydrated zirconia and sulfuric acid carried thereon, and contacting the catalyst with a hydrocarbon material having a water content of 5 ppm by weight or less, preferably 1 ppm or less, to thereby produce isomerized hydrocarbons; and a system for practicing the method. The isomerization method does not need the introduction of a chlorine-containing compound during the course of isomerization and uses a catalyst having high activity. The isomerization system comprises a dehydrating apparatus for the material, a vessel for catalytic reaction filled with the above catalyst, a separator for separating a reaction product into the hydrogen to be recycled and a hydrocarbon product, and a compressor which compresses the recycle hydrogen to feed it to the vessel for catalytic reaction.