摘要:
Provided is a hot-dip Al-Zn-Mg-Si coated steel sheet having good corrosion resistance in flat parts and edge parts, and also having excellent worked part corrosion resistance. The hot-dip Al-Zn-Mg-Si coated steel sheet includes a base steel sheet and a hot-dip coating on a surface of the base steel sheet. The hot-dip coating includes an interfacial alloy layer present at an interface with the base steel sheet and a main layer present on the interfacial alloy layer, and contains from 25 mass% to 80 mass% of Al, from greater than 0.6 mass% to 15 mass% of Si, and from greater than 0.1 mass% to 25 mass% of Mg. The Mg content and Si content in the hot-dip coating satisfy formula (1): M Mg / M Si − 0.6 > 1.7 where M Mg represents the Mg content (mass%) and M Si represents the Si content (mass%).
摘要:
A hot-dip Zn-Al alloy coated steel sheet exhibiting a beautiful coating appearance with metallic luster, in which no spangle or very fine spangles are formed, and having excellent blackening resistance and a method for manufacturing the hot-dip Zn-Al alloy coated steel sheet are provided. The hot-dip Zn-Al alloy coated steel sheet includes a hot-dip Zn-Al alloy coating layer containing 1.0 to 10 percent by mass of Al, 0.2 to 1.0 percent by mass of Mg, 0.005 to 0.1 percent by mass of Ni, and the balance being Zn and incidental impurities on at least one surface of a steel sheet. The manufacturing method includes the steps of dipping the steel sheet into a hot-dip Zn-Al alloy coating bath and pulling up and cooling the steel sheet, wherein the steel sheet pulled up from the coating bath is cooled to 250°C at a cooling rate of 1°C to 15°C/sec.
摘要:
A hot-dip Zn-Al alloy coated steel sheet exhibiting a beautiful coating appearance with metallic luster, in which no spangle or very fine spangles are formed, and having excellent blackening resistance and a method for manufacturing the hot-dip Zn-Al alloy coated steel sheet are provided. The hot-dip Zn-Al alloy coated steel sheet includes a hot-dip Zn-Al alloy coating layer containing 1.0 to 10 percent by mass of Al, 0.2 to 1.0 percent by mass of Mg, 0.005 to 0.1 percent by mass of Ni, and the balance being Zn and incidental impurities on at least one surface of a steel sheet. The manufacturing method includes the steps of dipping the steel sheet into a hot-dip Zn-Al alloy coating bath and pulling up and cooling the steel sheet, wherein the steel sheet pulled up from the coating bath is cooled to 250°C at a cooling rate of 1°C to 15°C/sec.
摘要:
In a method for prevention of yellowing on a surface of a steel sheet subjected to re-pickling, washing with water and drying after a surface of a continuously annealed steel sheet is pickled to remove Si-containing oxide layer from a surface layer of the steel sheet, the surface of the steel sheet is held at a wet state between the pickling and the re-pickling and between the re-pickling and the washing, and more preferably the washing is carried out with water having an iron ion concentration decreased to not more than 20 g/L, whereby the yellowing on the surface of the steel sheet after the pickling is prevented. Thus, cold rolled steel sheets being excellent in not only the appearance quality but also the phosphatability and corrosion resistance after painting are manufactured stably.
摘要:
An Al-Zn-coated steel sheet that suppresses blistering and offers good corrosion resistance after painting is provided. An Al-Zn-coated steel sheet includes an Al-Zn coating layer on a steel sheet surface, the Al-Zn coating layer including two layers which are an interfacial alloy layer present in an interface with a base steel sheet and an upper layer disposed on the interfacial alloy layer. The upper layer contains compounds of Si and Ca or Si, Ca, and Al, and Ca/Si mass% ratio in the upper layer is 0.72 to 1.4. The interfacial alloy layer contains an Fe-Al compound and/or an Fe-Al-Si compound. In the upper layer, Si content is 0.1 to 2.0 mass% and Ca content is 0.001 to 2.0 mass%.
摘要:
An object of the present invention is to provide an aluminum or aluminum alloy-coated steel material having better corrosion resistance than the conventional aluminum or aluminum alloy-coated steel material, together with a manufacturing method thereof. Specifically, the present invention provides an aluminum or aluminum alloy-coated steel material, comprising: base steel; and a coating layer formed on a surface of the base steel and containing by mass % Mg: 6% to 10%, Si: 3% to 7%, Fe: 0.2% to 2%, Mn: 0.02% to 2%, and the balance as Al and incidental impurities, wherein the coating layer has αAl-Mg 2 Si-(Al-Fe-Si-Mn) pseudoternary eutectic microstructure and area ratio of the microstructure in the coating layer is at least 30%.
摘要:
Provided are a chromium-free surface-treatment agent that allows for the formation of a film on a surface of a metal material, the film being excellent in terms of corrosion resistance in bent portions of steel sheets, solvent resistance, and paintability after alkaline degreasing, and that has excellent storage stability in the state of a one-component agent; a method for producing a coated steel sheet using the surface-treatment agent; and a coated steel sheet. A surface-treatment agent containing a resin compound having a specific bisphenol skeleton, a cationic urethane resin emulsion, a silane coupling agent, an organic titanium chelate compound, a tetravalent vanadyl compound, and water, with predetermined proportions and having a pH of 4 to 5; a method for producing a coated steel sheet using the surface-treatment agent; and a coated steel sheet.
摘要:
A method for making a phosphate-treated galvanized steel sheet, including forming a phosphate film on the surface of a galvanized layer of a galvanized steel sheet using a phosphate treatment solution containing Zn 2+ and Mg 2+ so as to satisfy 2.0 2+ ≤ 5.0 g/L, 2.0 ≤ Mg 2+ ≤ 5.0 g/L, and 0.4 ≤ Mg 2+ /Zn 2+ ≤ 2.5, and satisfying 0.020 ≤ free acidity/total acidity