摘要:
The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises a step (a) for obtaining a primarily modified polymer by conducting a primary modification reaction wherein at least one member selected from the group consisting of an alkoxysilane compound and a silanol compound is introduced into the active alkali metal terminal of a conjugated diene based (co)polymer having an active alkali metal terminal, and a step (b) for obtaining a secondarily modified polymer (a modified conjugated diene based (co)polymer) by subjecting the above-obtained primarily modified polymer to reactions including the following step (b1) and step (b2), and can produce a conjugated diene based (co)polymer having a high Mooney viscosity and excellent shape stability. Step (a): a reaction with a condensation accelerator containing a metal element. Step (b): a reaction with at least one member selected from the group consisting of inorganic acids and metal halides.
摘要:
[Problem] To provide a method for producing a hydrogenated conjugated diene polymer that is excellent in the improvement in dispersibility at the time of compounding with a filler, is excellent in the reduction in hysteresis loss after compounding, and enables the formation of a polymer alloy which has excellent processability at the time of compounding with a thermoplastic resin or the like and has excellent physical properties after compounding. [Means for solution] A method for producing a hydrogenated conjugated diene polymer, the method comprising a step of polymerizing at least a conjugated diene compound in the presence of a polymerization initiator composed of an amine compound having at least one structure of the formulae (x) and (y) and at least one metal compound selected from alkali metal compounds and alkaline earth metal compounds to obtain a conjugated diene polymer and a step of hydrogenating the conjugated diene polymer. wherein, in the formula (x), R 1 is a hydrocarbylene group, the hydrocarbylene group in R 1 may contain a heteroatom as long as the hydrocarbylene group does not have an active hydrogen atom, and A 1 is a trihydrocarbylsilyl group; in the formula (y), R 2 and R 3 are each independently a hydrocarbylene group, the hydrocarbylene group in each of R 2 and R 3 may contain a heteroatom as long as the hydrocarbylene group does not have an active hydrogen atom, and A 2 is a functional group which has at least one atom selected from a nitrogen atom N, a phosphorus atom P, and a sulfur atom S, has a trihydrocarbylsilyl group, and does not have an active hydrogen atom and in which the atom that is bonded to R 3 is N, P or S; and the above R 1 and A 1 may be bonded to each other to form a cyclic structure and a part of the above R 2 , R 3 , and A 2 may be bonded to each other to form a cyclic structure.
摘要:
A process for producing a conjugated diene copolymer rubber which comprises: initiating a copolymerization reaction in a reaction system containing a first conjugated diene compound and a first aromatic vinyl compound and completing the reaction; adding a first polyfunctional monomer to the reaction system, optionally further adding a second conjugated diene compound and a second aromatic vinyl compound, and further conducting copolymerization; and subsequently adding a modifier to the reaction system to react them. Thus, a rubber composition can be obtained which has satisfactory processability and comes through vulcanization to have sufficient hardness and reduced rolling resistance.
摘要:
There is provided a method of producing a conjugated diene rubber capable of being used as a starting material for a crosslinked rubber that can be used in applications such as tire treads and can raise the fuel efficiency. This method of producing a conjugated diene rubber comprises (a) a step of reacting a first alkoxysilane compound having in a molecule at least one group convertible to onium by an onium generator and at least one alkoxysilyl group that has at least two alkoxy groups, with a conjugated diene polymer having an alkali metal or alkaline-earth metal active terminal and obtained by polymerizing a conjugated diene compound and an aromatic vinyl compound, thereby to obtain a modified conjugated diene polymer that has the group convertible to onium and the alkoxysilyl group, and (b) a step of mixing the resulting modified conjugated diene polymer with the onium generator and a second alkoxysilane compound having in a molecule at least one alkoxysilyl group and at least one group convertible to onium by the onium generator.
摘要:
A method for producing a modified conjugated diene rubber which can be used as a raw material of a cross-linked rubber which can be used for use in tire treads and the like and can enhance low fuel consumption performance is provided. A method for producing a modified conjugated diene rubber comprising a step (a) of reacting a conjugated diene polymer having an alkali metal or alkaline-earth metal active end, which is obtained by polymerizing a conjugated diene compound or a conjugated diene compound and an aromatic vinyl compound with a hydrocarbyloxysilane compound having one or more of each of the following functional groups (I) and (II) in its molecule to obtain a modified conjugated diene polymer containing a functional group (II), and a step (b) of mixing the modified conjugated diene polymer obtained in the step (a) and one or more selected from the group consisting of organic acid compounds and organic acid derivatives to obtain the modified conjugated diene rubber. Functional group (I): A hydrocarbyloxysilyl group Functional group (II): A nitrogen-containing group in which both of two hydrogen atoms of a primary amino group are substituted with protective groups
摘要:
A composition improves mechanical strength (e.g., impact resistance and flexural strength), and achieves improved mass productivity by reducing a situation in which a strand fuzzes during extrusion. The composition includes a conjugated diene-based polymer (A), fibers (B), and a thermoplastic resin (C), the composition including the conjugated diene-based polymer (A) in a ratio of 0.05 to 30 parts by mass based on 100 parts by mass of the thermoplastic resin (C), and including the fibers (B) in a ratio of 3 to 150 parts by mass based on 100 parts by mass of the thermoplastic resin (C), wherein the conjugated diene-based polymer (A) includes at least one functional group selected from the group consisting of an alkoxysilyl group and an amino group.
摘要:
A rubber composition that can obtain a rubber elastic body having small rolling resistance and excellent impact resilience and a method for producing the same, and a tire having small rolling resistance and excellent impact resilience are provided. The rubber composition of the present invention is obtained by kneading a conjugated diene polymer having a functional group bondable to silica, an acylate compound containing metal and silica. In the present invention, a polymer having no functional group bondable to silica is preferably kneaded as a rubber component other than the conjugated diene polymer, together with the conjugated diene polymer having a functional group bondable to silica, the acylate compound containing metal and the silica.
摘要:
A rubber composition which can obtain a rubber elastic body having small rolling resistance and excellent impact resilience and a method for producing the same, and a tire having small rolling resistance and excellent impact resilience are provided. The rubber composition of the present invention is obtained by kneading a rubber component comprising a conjugated diene polymer having at least one functional group selected from the group consisting of a tertiary amino group, a thiol group, an epoxy group, a thioepoxy group, an oxetane group and a hydrocarbylthio group, a catalyst for condensing silanol, and silica.