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    METHOD FOR PRODUCING HYDROGENATED CONJUGATED DIENE POLYMER
    1.
    发明公开
    METHOD FOR PRODUCING HYDROGENATED CONJUGATED DIENE POLYMER 审中-公开
    VERFAHREN ZUR HERSTELLUNG EINES HYDRIERTEN KONJUGIERTEN DIENPOLYMERS

    公开(公告)号：EP2957572A1

    公开(公告)日：2015-12-23

    申请号：EP14751252.9

    申请日：2014-02-14

    申请人： JSR Corporation

    发明人： NOSAKA, Naoya ,  SHIBATA, Masahiro ,  TOYODA, Nobuyuki ,  ABE, Shigeru ,  UEDA, Jirou

    IPC分类号： C08C19/26 ,  C08F4/54 ,  C08K3/04 ,  C08K3/36 ,  C08L15/00 ,  C08L101/00

    CPC分类号： C08F236/10 ,  C08C19/02 ,  C08C19/30 ,  C08F4/54 ,  C08F8/04 ,  C08F136/06 ,  C08F297/04 ,  C08K3/04 ,  C08K3/36 ,  C08L15/00 ,  C08L19/006 ,  C08L23/12 ,  C08L67/02 ,  C08L101/00 ,  C08F8/42 ,  C08L67/04 ,  C08L53/025 ,  C08L23/06

    摘要： [Problem]
    To provide a method for producing a hydrogenated conjugated diene polymer that is excellent in the improvement in dispersibility at the time of compounding with a filler, is excellent in the reduction in hysteresis loss after compounding, and enables the formation of a polymer alloy which has excellent processability at the time of compounding with a thermoplastic resin or the like and has excellent physical properties after compounding.
    [Means for solution]
    A method for producing a hydrogenated conjugated diene polymer, the method comprising a step of polymerizing at least a conjugated diene compound in the presence of a polymerization initiator composed of an amine compound having at least one structure of the formulae (x) and (y) and at least one metal compound selected from alkali metal compounds and alkaline earth metal compounds to obtain a conjugated diene polymer and
    a step of hydrogenating the conjugated diene polymer.


    wherein, in the formula (x), R 1 is a hydrocarbylene group, the hydrocarbylene group in R 1 may contain a heteroatom as long as the hydrocarbylene group does not have an active hydrogen atom, and A 1 is a trihydrocarbylsilyl group; in the formula (y), R 2 and R 3 are each independently a hydrocarbylene group, the hydrocarbylene group in each of R 2 and R 3 may contain a heteroatom as long as the hydrocarbylene group does not have an active hydrogen atom, and A 2 is a functional group which has at least one atom selected from a nitrogen atom N, a phosphorus atom P, and a sulfur atom S, has a trihydrocarbylsilyl group, and does not have an active hydrogen atom and in which the atom that is bonded to R 3 is N, P or S; and the above R 1 and A 1 may be bonded to each other to form a cyclic structure and a part of the above R 2 , R 3 , and A 2 may be bonded to each other to form a cyclic structure.

    摘要翻译： 本发明提供一种在与填料混合时分散性提高性优异的氢化共轭二烯系聚合物的制造方法，配合后的滞后损失的降低优异，能够形成聚合物合金 其在与热塑性树脂等配混时具有优异的加工性，并且在配混后具有优异的物理性能。 [解决方案]一种制备氢化共轭二烯聚合物的方法，该方法包括在由具有至少一个式（x）的结构的胺化合物组成的聚合引发剂存在下使至少共轭二烯化合物聚合的步骤 ）和（y）和至少一种选自碱金属化合物和碱土金属化合物的金属化合物，以获得共轭二烯聚合物和氢化共轭二烯聚合物的步骤。 其中，在式（x）中，R 1为亚烃基，只要亚烃基不具有活性氢原子，R 1中的亚烃基可含有杂原子，A 1为三烃基甲硅烷基; 在式（y）中，R 2和R 3各自独立地为亚烃基，只要亚烃基不具有活性氢原子，R 2和R 3各自中的亚烃基可以含有杂原子，并且A 2是具有选自氮原子N，磷原子P和硫原子S中的至少一个原子的官能团，具有三烃基甲硅烷基，不具有活性氢原子，并且其中键合的原子 R 3为N，P或S; 并且上述R 1和A 1可以彼此键合以形成环状结构，并且上述R 2，R 3和A 2的一部分可以彼此键合以形成环状结构。

    METHOD FOR PRODUCING MODIFIED CONJUGATED DIENE POLYMER, MODIFIED CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION
    6.
    发明公开
    METHOD FOR PRODUCING MODIFIED CONJUGATED DIENE POLYMER, MODIFIED CONJUGATED DIENE POLYMER, AND RUBBER COMPOSITION 有权
    用于生产改性共轭二烯聚合物的改性共轭二烯系聚合物和橡胶组合物

    公开(公告)号：EP2130841A1

    公开(公告)日：2009-12-09

    申请号：EP08738732.0

    申请日：2008-03-21

    申请人： JSR Corporation ,  Bridgestone Corporation

    发明人： MATSUMOTO, Takaomi ,  SHIBATA, Masahiro ,  SONE, Takuo ,  TADAKI, Toshihiro ,  TANAKA, Ken ,  NAKAGAWA, Ryuji

    IPC分类号： C08C19/42 ,  C08K3/04 ,  C08K3/36 ,  C08L15/00

    CPC分类号： C08C19/44 ,  C08C19/12 ,  C08C19/16 ,  C08K3/013 ,  C08K3/16 ,  C08K3/24 ,  C08K5/54 ,  C08L9/00 ,  C08L9/06 ,  C08L15/00 ,  C08L21/00 ,  C08L2666/08

    摘要： The method for producing a modified conjugated diene based (co)polymer, according to the present invention comprises
    a step (a) for obtaining a primarily modified polymer by conducting a primary modification reaction wherein at least one member selected from the group consisting of an alkoxysilane compound and a silanol compound is introduced into the active alkali metal terminal of a conjugated diene based (co)polymer having an active alkali metal terminal, and
    a step (b) for obtaining a secondarily modified polymer (a modified conjugated diene based (co)polymer) by subjecting the above-obtained primarily modified polymer to reactions including the following step (b1) and step (b2), and can produce a conjugated diene based (co)polymer having a high Mooney viscosity and excellent shape stability.
    Step (a): a reaction with a condensation accelerator containing a metal element.
    Step (b): a reaction with at least one member selected from the group consisting of inorganic acids and metal halides.

    摘要翻译： 用于生产改性共轭的方法，发球基于（共）聚合物，雅丁到本发明包括步骤（a）用于通过进行一次改性反应worin获得一个一次改性聚合物选自的烷氧基硅烷的由至少一个构件 化合物和硅烷醇化合物引入共轭服务系（共）具有碱金属活性末端的聚合物的活性碱金属端，以及一个步骤（b）用于获得二次改性聚合物（改性共轭发球基于（共） 聚合物）通过使上面得到的一次改性聚合物反应，包括下述工序（b1）和工序（b2）中，并能产生一个共轭服务基于（共）具有高门尼粘度和优良的形状稳定性的聚合物。 步骤（a）：用缩合促进剂含有金属元素的反应。 步骤（b）：与选自无机酸和金属卤化物中选出的至少一个成员的反应。

    CONJUGATED DIOLEFIN COPOLYMER RUBBER, METHOD FOR PRODUCING THE SAME, RUBBER COMPOSITION AND TIRE
    7.
    发明公开
    CONJUGATED DIOLEFIN COPOLYMER RUBBER, METHOD FOR PRODUCING THE SAME, RUBBER COMPOSITION AND TIRE 有权
    轮胎和THAT共轭二烯烃共聚橡胶，橡胶制品和合成方法

    公开(公告)号：EP2123687A1

    公开(公告)日：2009-11-25

    申请号：EP08722220.4

    申请日：2008-03-14

    申请人： JSR Corporation

    发明人： TADAKI, Toshihiro ,  SHIBATA, Masahiro ,  NAGAOKA, Tamotsu ,  SONE, Takuo

    IPC分类号： C08F297/04 ,  B60C1/00 ,  C08K3/36 ,  C08L9/06 ,  C08L53/02 ,  C08L91/00

    CPC分类号： C08L15/00 ,  B60C1/0016 ,  C08C19/44 ,  C08F36/04 ,  C08F297/04 ,  C08F297/044 ,  C08L7/00 ,  C08L19/006 ,  C08L53/02 ,  C08F4/08 ,  C08L2666/02

    摘要： A conjugated diolefin copolymer rubber is produced by copolymerization of a conjugated diolefin and an aromatic vinyl compound and has a primary amino group and an alkoxysilyl group bonded to the copolymer chain. The conjugated diolefin copolymer rubber contains the aromatic vinyl compound in an amount of 5 to 60 wt%. The aromatic vinyl compound is densely distributed in one terminal of the copolymer chain, and is scarcely distributed in the other terminal. The conjugated diolefin copolymer rubber has a temperature difference (ΔTg) of 25°C or more. The conjugated diolefin copolymer rubber has low hysteresis loss properties as well as improved abrasion resistance, rupture characteristics, and road grip characteristics without impairing wet skid characteristics. A method for producing the conjugated diolefin copolymer rubber is also disclosed.

    摘要翻译： 共轭二烯烃共聚物橡胶是通过在共轭二烯烃和芳香族乙烯基化合物的共聚得到并且具有伯氨基，并在结合到共聚物链烷氧基甲硅烷基。 共轭二烯烃共聚物橡胶中含有以5〜60重量％的芳香族乙烯基化合物。 作为芳香族乙烯基化合物密集地分布在共聚物链的一个末端，并且几乎不分布在另一端。 共轭二烯烃共聚物橡胶具有25℃以上的温度差（“Tg）的。 共轭二烯烃共聚物橡胶具有低滞后损失性能，以及改进的耐磨性，断裂特性和抓地力的特性而不损害湿滑特性。 因此，一种用于制造共轭二烯烃共聚橡胶的方法是游离缺失盘。

    COMPOSITION AND MOLDED OBJECT
    9.
    发明公开
    COMPOSITION AND MOLDED OBJECT 审中-公开

    公开(公告)号：EP3345969A1

    公开(公告)日：2018-07-11

    申请号：EP16841560.2

    申请日：2016-08-22

    申请人： JSR Corporation

    发明人： MAEDA, Shuugo ,  SHIBATA, Masahiro ,  OOKUBO, Akihiko

    IPC分类号： C08L101/00 ,  C08K3/04 ,  C08L21/00

    CPC分类号： C08J5/042 ,  C08J5/06 ,  C08J2300/22 ,  C08J2347/00 ,  C08K3/04 ,  C08K7/06 ,  C08K9/08 ,  C08L21/00 ,  C08L23/12 ,  C08L101/00 ,  D06M15/227

    摘要： Provided is a composition capable of providing a formed article that, even when using continuous fibers, has excellent interfacial adhesion between the continuous fibers and a matrix resin, and as a result, has excellent mechanical strength (e.g., impact resistance and flexural strength). One aspect of a composition according to the present invention includes a polymer (A) including an amino group, fibers (B), and a thermoplastic resin (C), in which a content ratio of the fibers (B) is 70 parts by mass or more and 250 parts by mass or less based on 100 parts by mass of the thermoplastic resin (C). Another aspect of the composition according to the present invention includes a polymer (A) including an amino group, a non-woven fabric (B'), and a thermoplastic resin (C).