公开(公告)号：EP3763714A1

公开(公告)日：2021-01-13

申请号：EP19763778.8

申请日：2019-03-04

Applicant: Japan Science and Technology Agency

Inventor： SAITO Shohei ,  YABU Hiroshi ,  ABE Hiroya

IPC: C07D487/04 ,  C07D471/06 ,  C08G18/38 ,  C07D313/14 ,  C07D405/14 ,  C07D487/22

Abstract: Provided is a compound having higher fluorescence quantum yield and higher optical stability than a conventional FLAP and a polymer compound containing the compound.
The object is achieved by providing a compound represented by the following general Formula (1).

Symbols in general Formula (1) are defined as follows:
A denotes a seven-membered ring or eight-membered ring structure,
Y 1 and Y 2 each denote, independently, a halogen atom or the like,
a1 denotes the number of the substituent groups Y 1 , and a2 denotes the number of the substituent groups Y 2 ,
Y 3 denotes a halogen atom or the like,
b denotes the number of the substituent groups Y 3 ,
m and n each denote, independently, an integer greater than or equal to 0 and less than or equal to 3, when m is an integer greater than or equal to 1 and less than or equal to 3, Y 1 may be substituted with a structure portion defined by m, and similarly, when n is an integer greater than or equal to 1 and less than or equal to 3, Y 2 may be substituted with a structure portion defined by n, and
B 1 and B 2 each denote, independently, any of the structures represented by the following general Formulas (2-1) to (2-3).

Symbols in general Formulas (2-1) to (2-3) are defined as follows:
C 1 denotes a structure containing a cyclic hydrocarbon compound,
C 2 and C 3 each denote a structure containing a cyclic hydrocarbon compound,
D 1 , D 2 , and D 3 each denote a substructure that inhibits aggregation,
E 1 , E 2 , and E 3 each denote a polymerizable substructure,
Z 1 each denote, independently, a hydrogen atom or the like,
c denotes the number of substituent groups Z 1 , and
Z 2 and Z 3 each denote, independently a hydrogen atom or the like, and Z 2 and Z 3 may each form a ring with C 2 , independently.

公开(公告)号：EP3222694A1

公开(公告)日：2017-09-27

申请号：EP15860298.7

申请日：2015-11-16

Applicant: Japan Science and Technology Agency

Inventor： YABU Hiroshi ,  SAITO Yuta ,  SAITO Shohei ,  YAMAGUCHI Shigehiro ,  NOBUSUE Shunpei

IPC: C09K11/06 ,  C08G61/08 ,  C09K9/02

CPC classification number: C08G61/08 ,  C07D209/70 ,  C08G2261/122 ,  C08G2261/135 ,  C08G2261/3324 ,  C08G2261/418 ,  C08G2261/522 ,  C08G2261/62 ,  C08G2261/76 ,  G01L1/24

Abstract: Provided is a mechanochromic resin by which a stress applied to a material can be visualized in real time, and a mechanochromic luminescent material that is used in the synthesis of the mechanochromic resin. Stress can be visualized in real time by means of a mechanochromic luminescent material represented by formula (1) or formula (2) and a mechanochromic resin obtained by crosslinking the mechanochromic luminescent material. [Chemical formula 1] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (1), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.) [Chemical formula 2] (In the formula, Y 1 and Y 2 each denote a substituent group that inhibits aggregation of the mechanochromic luminescent material represented by formula (2), and Y 1 and Y 2 may be same as or different from each other. Z 1 and Z 2 each denote a polymerizable group, and may be same as or different from each other.)

Abstract translation: 提供一种机械变色树脂，通过该树脂可以实时观察施加到材料上的应力，以及用于合成机械变色树脂的机械变色发光材料。 应力可以通过由式（1）或式（2）表示的机械变色发光材料和通过交联机械变色发光材料获得的机械变色树脂实时可视化。 [化学式1]（式中，Y 1和Y 2分别表示抑制式（1）所示的机械致变色性发光材料的凝集的取代基，Y 1和Y 2可以相同也可以不同，Z 1和Z 2 [化学式2]（式中，Y 1和Y 2分别表示抑制式（2）所示的机械致变色发光材料的聚集的取代基，[化学式2] Y 1和Y 2彼此可以相同或不同，Z 1和Z 2各自表示可聚合基团，并且可以彼此相同或不同）。