公开(公告)号：EP1552884A1

公开(公告)日：2005-07-13

申请号：EP03751442.9

申请日：2003-10-10

申请人： Japan Science and Technology Agency ,  National Institute for Materials Science

发明人： NISHIDA, Atsushi ,  ARISAWA, Mitsuhiro ,  TSUKAMOTO, Shiro, Nat. Inst. for Materials Science ,  SHIMODA, Masahiko, Nat. Inst. f. Materials Science

IPC分类号： B01J31/24

CPC分类号： B01J31/1616 ,  B01J31/24 ,  B01J37/0238 ,  B01J2231/4211 ,  B01J2231/4261 ,  B01J2531/824 ,  Y02P20/582

摘要： The present invention relates to a substrate having an organic metal complex bonded on the surface thereof, which is prepared by the vapor deposition of a sulfur atom onto a substrate followed by bonding of an organic metal complex such as tetrakis-triphenylphosphine palladium [Pd(PPh 3 ) 4 ] to the surface of the substrate; a substrate bonded transition metal catalyst using said substrate; and a method for the preparation thereof. The above substrate and metal catalyst allow the solution of some problems with respect to the safety and stability of an organic metal complex in its use, the removal of trace amounts of metals in a reaction product, waste water treatment and the like.

摘要翻译： 本发明涉及通过将硫原子气相沉积到基板上，然后将有机金属络合物如四 - 三苯基膦钯ÄPd（PPh 3）键合而制备的表面上结合有有机金属络合物的基材， 4Ü到基材的表面; 使用所述衬底的基底键合过渡金属催化剂; 及其制备方法。 上述底物和金属催化剂允许解决有机金属络合物在使用中的安全性和稳定性的一些问题，在反应产物中除去痕量的金属，废水处理等。