摘要:
A process for producing an ethylene-vinyl alcohol copolymer resin, including feeding EVOH into an extruder, keeping the temperature of the melting resin in the extruder at 70 to 170 DEG C, adjusting the amount of water in the extruder so that the water content right after being discharged from the extruder is 5 to 40 weight %, and extruding out the EVOH resin. The extruded EVOH resin is cut into EVOH pellets. Thereby, it is possible to obtain resin pellets in which no spherocrystals are observed in the center of the cross section of the resin when the cross section is observed by the use of a polarization microscope, or no lubricant is contained in the resin pellets, and the angle of repose is 23 DEG or less when the resin pellets are laminated. Thus, it is possible to provide an ethylene-vinyl alcohol copolymer (EVOH) resin pellet having a reduced discharging load to the environment and capable of being fed into an extruder smoothly without being blocked, extruding stability, and thermal stability (long-run property).
摘要:
Provided is a method for producing an aqueous ethylene-vinyl alcohol copolymer (EVOH) composition that ensures efficient removal of alcohol not worsening the environment in and around working areas. Also provided are EVOH pellets of the aqueous composition, which can be produced stably and can be washed rapidly. The production method comprises introducing an EVOH solution that contains at least 50 parts by weight, relative to 100 parts by weight of EVOH therein, of an alcohol having a boiling point of not higher than 100°C, into a vessel, and contacting it with water vapor in the vessel, thereby letting the alcohol out along with water vapor and taking the resulting aqueous EVOH composition that contains from 0 to 10 parts by weight of the alcohol and from 10 to 500 parts by weight of water, relative to 100 parts by weight of EVOH therein, out of the vessel. The EVOH pellets are obtained by cutting the aqueous EVOH composition obtained in the production method.
摘要:
A process for producing an ethylene-vinyl alcohol copolymer resin, including feeding EVOH into an extruder, keeping the temperature of the melting resin in the extruder at 70 to 170°C, adjusting the amount of water in the extruder so that the water content right after being discharged from the extruder is 5 to 40 weight %, and extruding out the EVOH resin. The extruded EVOH resin is cut into EVOH pellets. Thereby, it is possible to obtain resin pellets in which no spherocrystals are observed in the center of the cross section of the resin when the cross section is observed by the use of a polarization microscope, or no lubricant is contained in the resin pellets, and the angle of repose is 23 ° or less when the resin pellets are laminated. Thus, it is possible to provide an ethylene-vinyl alcohol copolymer (EVOH) resin pellet having a reduced discharging load to the environment and capable of being fed into an extruder smoothly without being blocked, extruding stability, and thermal stability (long-run property).
摘要:
A process for producing an ethylene-vinyl alcohol copolymer resin, including feeding EVOH into an extruder, keeping the temperature of the melting resin in the extruder at 70 to 170°C, adjusting the amount of water in the extruder so that the water content right after being discharged from the extruder is 5 to 40 weight %, and extruding out the EVOH resin. The extruded EVOH resin is cut into EVOH pellets. Thereby, it is possible to obtain resin pellets in which no spherocrystals are observed in the center of the cross section of the resin when the cross section is observed by the use of a polarization microscope, or no lubricant is contained in the resin pellets, and the angle of repose is 23 ° or less when the resin pellets are laminated. Thus, it is possible to provide an ethylene-vinyl alcohol copolymer (EVOH) resin pellet having a reduced discharging load to the environment and capable of being fed into an extruder smoothly without being blocked, extruding stability, and thermal stability (long-run property).
摘要:
A process for producing vinyl acetate polymers comprises, after polymerization of at least one monomer comprising vinyl acetate, adding a conjugated polyene having a boiling point of at least 20°C. Saponified products of the vinyl acetate polymers obtained by this process can give molded articles causing little coloring and generation of gel-like agglomerates.