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公开(公告)号：EP0796264A1
公开(公告)日：1997-09-24
申请号：EP95932189.0
申请日：1995-09-20
申请人： Kao Corporation
IPC分类号： C07F9
摘要： An organic hydroxyl compound is reacted with a phosphorylating agent comprising phosphorus pentaoxide and at least one compound selected from the group consisting of water, phosphoric acid and polyphosphoric acid and having a value represented by formula (I) of from 0.5 to 1.0, under such a condition that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2; or alternatively, an organic hydroxyl compound is reacted with the above phosphorylating agent under such a condition that the ratio as defined by formula (II) has a value in the range of from exceeding 3.2 up to 6.4 and then phosphorus pentaoxide is added to the reaction product in such an amount that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2 with respect to the total feeds of the starting materials to conduct further reaction. Said process enables the preparation of a phosphoric ester mixture which is excellent in hue and odor, is reduced in the amount of orthophosphoric acid formed as a by-product and contains a phosphoric monoester useful as the component of detergent in an increased amount.
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3.发明授权NOVEL GLYCINE DERIVATIVES, INTERMEDIATES THEREFOR AND CLEANSER COMPOSITIONS COMPRISING THEM 失效新的甘氨酸，其中间体，以及含有清洁组合物
公开(公告)号：EP0752983B1
公开(公告)日：1999-08-11
申请号：EP95913359.6
申请日：1995-03-28
申请人： Kao Corporation
IPC分类号： C07C235/12 , C07C229/16 , C07C255/24 , C07C255/61 , B01F17/22 , B01F17/28 , C11D1/10 , C11D1/52 , A61K7/07
CPC分类号： A61K8/44 , A61Q5/02 , A61Q19/10 , B01F17/0042 , C07C229/16 , C07C233/47 , C07C255/24 , C07C255/29 , C11D1/10
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4.发明公开NOVEL GLYCINE DERIVATIVES, INTERMEDIATES THEREFOR AND CLEANSER COMPOSITIONS COMPRISING THEM 失效新的甘氨酸，其中间体，以及含有清洁组合物
公开(公告)号：EP0752983A1
公开(公告)日：1997-01-15
申请号：EP95913359.0
申请日：1995-03-28
申请人： Kao Corporation
CPC分类号： A61K8/44 , A61Q5/02 , A61Q19/10 , B01F17/0042 , C07C229/16 , C07C233/47 , C07C255/24 , C07C255/29 , C11D1/10
摘要： Glycine derivatives represented by formula (1) and cleanser compositions containing the same, wherein R is a linear or branched alkyl group having 11 to 13 carbon atoms, a linear or branched alkenyl group having 11 to 13 carbon atoms, or a linear or branched hydroxyalkyl group having 11 to 13 carbon atoms, and M1 and M2 are the same or different from each other and each independently is a hydrogen atom, an alkali metal atom, 1/2 (an alkaline earth metal atom), an ammonium group, a monoalkanolammonium group having 1 to 22 carbon atoms, a dialkanolammonium group having 2 to 22 carbon atoms in total, a trialkanolammonium group having 3 to 22 carbon atoms in total, or a protonated basic amino acid, are excellent in foaming, detergency, comfort in use and safety, are antipollutive and can be used for various purposes, for example, a cleanser composition for the hair and body or tableware.
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