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公开(公告)号:EP3251840A1
公开(公告)日:2017-12-06
申请号:EP16743471.1
申请日:2016-01-28
申请人: Kuraray Co., Ltd.
IPC分类号: B32B27/00 , B29C51/10 , C09J7/02 , C09J123/10 , C09J129/14 , C09J153/02 , B29K33/00
CPC分类号: B29C47/065 , B29C51/10 , B29C65/48 , B29K2009/00 , B29K2021/003 , B29K2023/12 , B29K2025/00 , B29L2009/00 , B32B27/00 , B32B27/08 , B32B27/308 , C09J7/20 , C09J7/24 , C09J123/10 , C09J129/14 , C09J153/02 , C09J153/025 , C09J2205/10 , C09J2433/006 , C09J2451/00 , C09J2453/00 , C09J2453/006
摘要: Provided are a multilayer film, a method for producing the multilayer film, and a method for producing a molded body using the multilayer film. The multilayer film: has an adhesive layer; has excellent three-dimensional overlaying formability and adhesiveness after being formed into a three-dimensional overlay; can easily be used when being bonded to an adherend; maintains adhesive strength without breaking or wrinkling in a wide range of range temperatures; and is suitable for forming a vacuum. Specifically, the multilayer film has: an adhesive layer comprising a thermoplastic polymer composition containing a thermoplastic elastomer (A) which is a block copolymer or a hydrogenated product thereof having a polymer block (a1) containing aromatic vinyl compound units and having a polymer block (a2) containing conjugated diene compound units; and a base layer comprising an amorphous resin which has a modulus of elasticity of 2 to 600 MPa at an arbitrary temperature of 110 to 160°C. The tensile elongation at break of the multilayer film at a temperature 5°C lower than the glass transition temperature of the amorphous resin is at least 160%.
摘要翻译: 本发明提供一种多层膜,该多层膜的制造方法以及使用该多层膜的成型体的制造方法。 多层膜:具有粘合剂层; 在形成三维覆盖层之后具有优异的三维重叠成形性和粘附性; 在粘合到被粘物上时可以很容易地使用; 在宽范围温度范围内保持粘合强度而不破裂或起皱; 并适用于形成真空。 具体而言,多层膜具有:含有热塑性聚合物组合物的粘合剂层,该热塑性聚合物组合物含有作为嵌段共聚物的热塑性弹性体(A)或其氢化物,该热塑性弹性体(A)具有含芳香族乙烯基化合物单元的聚合物嵌段(a1) a2)含有共轭二烯化合物单元; 以及在110〜160℃的任意温度下具有2〜600MPa的弹性模量的无定形树脂的基底层。 在比无定形树脂的玻璃化转变温度低5℃的温度下多层膜的断裂拉伸伸长率至少为160%。
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公开(公告)号:EP3636431A1
公开(公告)日:2020-04-15
申请号:EP18813067.8
申请日:2018-06-06
申请人: Kuraray Co., Ltd.
IPC分类号: B32B25/16 , B29C47/06 , B29C47/88 , B29C63/02 , B32B27/00 , C08L23/12 , C08L53/02 , B29K23/00 , B29K25/00 , B29L7/00 , B29L9/00
摘要: The present invention relates to a multilayered film having a high degree of freedom regarding selection of a material and a decoration method, which is not only excellent in handling properties and low-temperature adhesiveness to adherends of various materials but also applicable to decorative molding of every sort in a three-dimensional solid shape, and a method for producing the same. The present invention provides a multilayered film including, as an intermediate layer (X), a thermoplastic resin layer having a bending rigidity of 60 to 30,000 kPa·mm 3 ; a layer (Y) composed of a thermoplastic polymer composition on both surfaces of the intermediate layer (X), the thermoplastic polymer composition containing 0 to 50 parts by mass of a polypropylene-based resin (B) based on 100 parts by mass of a thermoplastic elastomer (A) that is a block copolymer containing a polymer block (a1) composed of an aromatic vinyl compound unit and a polymer block (a2) composed of a conjugated diene compound unit; and a decorative layer (Z) closely arranged on the surface of either one of the layers (Y). The present invention also provides a method for producing the multilayered film, including bringing the thermoplastic resin layer (Y) as a surface layer in a molten state into contact with a roll whose surface is made of a hydrophobic resin.
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公开(公告)号:EP3459735A1
公开(公告)日:2019-03-27
申请号:EP17799483.7
申请日:2017-05-18
申请人: Kuraray Co., Ltd.
摘要: A multilayer film having a structure consisting of at least three layers: a polypropylene resin layer (X), an intermediate layer (Y) formed of a thermoplastic polymer composition containing 100 parts by mass of a thermoplastic elastomer (A), which is a block copolymer containing a polymer block (a1) formed of an aromatic vinyl compound unit and a polymer block (a2) formed of a conjugate diene compound unit or a hydrogenated product thereof, and 1 to 50 parts by mass a polypropylene resin (B) and a decorative layer (Z), in which the layers (X) (Y) and (Z) are stacked in this order, is excellent in preform moldability, successfully and firmly adhering to an adherend to decorate, small in warpage during thermal lamination and satisfactory in coextrusion film formability and weather resistance.
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