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公开(公告)号:EP1495802A1
公开(公告)日:2005-01-12
申请号:EP03715625.4
申请日:2003-03-28
发明人: UCHIDA, Yoshitaka, KYUSHU ELEC. POWER CO., INC. , TSUJIMOTO, Keigo, KYUSHU ELEC. POWER CO., INC.
CPC分类号: C01B3/40 , B01J23/002 , B01J23/462 , B01J23/755 , B01J23/83 , B01J23/894 , B01J37/0205 , B01J37/031 , B01J2523/00 , C01B2203/00 , C01B2203/0233 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , Y02P20/52 , B01J2523/31 , B01J2523/3706 , B01J2523/821 , B01J2523/847 , B01J2523/41 , B01J2523/48
摘要: Disclosed is a reforming-catalyst composition, which comprises nickel oxide and lanthanum oxide as a catalytic material for inducing a reaction between stream and either one of methane, natural gas and town gas to produce a hydrogen-containing gas. The nickel oxide and lanthanum oxide are formed as a perovskite-structured compound partly or in their entirety. The reforming-catalyst composition may include an oxide consisting of either one of alumina, silica and zirconia, on which the perovskite-structured compound is formed to serve as a catalyst carrier. Further, the reforming-catalyst composition may include nickel or ruthenium supported by aforesaid catalyst carrier consisting of the perovskite-structured compound. The reforming-catalyst composition of the present invention allows highly concentrated hydrogen to be produced at a low S/C ratio in steam reforming of methane, natural gas or town gas, while maintaining catalytic activity over a long time-period.
摘要翻译: 公开了一种重整催化剂组合物,其包含氧化镍和氧化镧作为用于在流与甲烷,天然气和城镇煤气中的任一种之间的反应的催化材料中产生含氢气体。 氧化镍和氧化镧部分或全部形成为钙钛矿结构化合物。 重整催化剂组合物可以包括氧化铝,二氧化硅和氧化锆中的任一种,其上形成钙钛矿结构化合物作为催化剂载体的氧化物。 此外,重整催化剂组合物可以包括由上述由钙钛矿结构化合物组成的催化剂载体负载的镍或钌。 本发明的重整催化剂组合物允许在甲烷,天然气或城镇煤气的蒸汽重整中以低S / C比率生产高度浓缩的氢气,同时保持长时间的催化活性。