摘要:
The present disclosure relates to a positive electrode active material which reduces lithium by-products and improves structural stability and includes a lithium-nickel based transition metal composite oxide in which an alkaline earth metal having oxidation number of +2 is doped and a phosphate coated layer formed on the outer surface of the composite oxide. Accordingly, a second battery including the positive electrode active material has excellent capacity characteristics, and also improves structural stability during charging/discharging and prevents swelling, thereby being capable of exhibiting excellent life characteristics. Therefore, the present invention may be easily applied to industry in need thereof, and particularly to electric vehicles industry requiring high capacity and long-term life characteristics.
摘要:
Disclosed are a precursor of an electrode active material for a lithium secondary battery, in which a metal material ionizable through electrolytic decomposition is uniformly coated on a surface of a primary precursor formed of a transition metal hydrate, and a method of preparing the same.
摘要:
The present invention relates to a cathode active material comprising: a lithium-nickel based transition metal composite oxide which is doped with an alkali earth metal having an oxidation state of +2; and a phosphorous oxide coating layer formed on the outer surface of the composite oxide, such that a lithium by-product is reduced and structural stability is improved. Accordingly, a secondary battery comprising the cathode active material has an excellent capacity property and at the same time, has improved structural stability during charging and discharging, and has a superior lifespan by suppressing swelling. Thus, the present invention can be easily applied to industries that require the present invention, particularly, to industries that require high capacity and a long-term lifespan of an electric vehicle and the like.
摘要:
The present invention relates to a cathode active material comprising: a lithium-nickel based transition metal composite oxide which is doped with an alkali earth metal having an oxidation state of +2; and a phosphorous oxide coating layer formed on the outer surface of the composite oxide, such that a lithium by-product is reduced and structural stability is improved. Accordingly, a secondary battery comprising the cathode active material has an excellent capacity property and at the same time, has improved structural stability during charging and discharging, and has a superior lifespan by suppressing swelling. Thus, the present invention can be easily applied to industries that require the present invention, particularly, to industries that require high capacity and a long-term lifespan of an electric vehicle and the like.
摘要:
The present invention provides a positive electrode active material for a secondary battery which includes a lithium transition metal oxide, wherein the positive electrode active material has three peaks in a differential graph (ERC curve) obtained by differentiating a pH value against an amount of acid (HC1) added, which is obtained by pH titration of 10 g of the lithium transition metal oxide using 0.5 M HCl, wherein a y-axis (dpH/dml) value of a first peak at the smallest x-axis value among the three peaks is - 1.0 or less.
摘要:
Disclosed are a cathode active material and a lithium secondary battery including the same, and a method of manufacturing the cathode active material, the method including: (a) manufacturing a lithium metal oxide according to formula 1 below:
Li 1+z Ni a Mn b Co 1-(a+b) O2 (1)
wherein 0≤z≤0.1, 0.1≤a≤0.8, 0.1≤b≤0.8 and a+b (b) dry mixing the lithium metal oxide, and a precursor including zirconium and fluorine; and (c) changing the precursor including zirconium and fluorine into ZrO 2 and substituting some of oxygen (O) anions with F by heat-treatment after dry mixing of step (b), wherein the cathode active material is coated with ZrO 2 and F.
摘要翻译:公开了一种正极活性物质和包含该正极活性物质的锂二次电池及其制造方法,所述方法包括:(a)制备下式1的锂金属氧化物:€ƒ€ƒ€ ƒ€ƒ€ƒ€ƒ€ƒLi1 + z Ni a Mn b Co 1-(a + b)O2€ƒ€ƒ€ƒ€ƒ(1)其中0‰¤‰¤0.1,0.1‰¤ a‰¤0.8,0.1‰¤b‰¤0.8和a + b <1; (b)将锂金属氧化物和包含锆和氟的前体干混; 和(c)通过步骤(b)的干混后,通过热处理将包含锆和氟的前体改变成ZrO 2并用F代替一些氧(O)阴离子,其中正极活性材料涂覆有ZrO 2和F 。
摘要:
Disclosed are a precursor of an electrode active material for a lithium secondary battery, in which a metal material ionizable through electrolytic decomposition is uniformly coated on a surface of a primary precursor formed of a transition metal hydrate, and a method of preparing the same.
摘要:
The present invention relates to a method of preparing a positive electrode active material having a high ratio of charge and discharge capacity at a charge end voltage of 4.1 V to 4.175 V to charge and discharge capacity at a charge end voltage of 4.2 V to 4.275 V and an excellent initial charge and discharge capacity.