摘要:
The present invention relates to a method of preparing a positive electrode active material having a high ratio of charge and discharge capacity at a charge end voltage of 4.1 V to 4.175 V to charge and discharge capacity at a charge end voltage of 4.2 V to 4.275 V and an excellent initial charge and discharge capacity.
摘要:
Disclosed is a cathode active material in which lithium cobalt oxide particles and manganese (Mn) or titanium (Ti)-containing lithium transition metal oxide particles co-exist and a method of preparing the same.
摘要:
The present invention relates to a positive electrode active material for a lithium secondary battery, and a lithium secondary battery including the same, and the positive electrode active material includes lithium cobalt oxide particles. The lithium cobalt oxide particles include lithium cobalt oxide having a Li/Co molar ratio of less than 1 in the particles. Good rate property and life property may be obtained without worrying on the deterioration of initial capacity property.
摘要:
Disclosed is a lithium manganese (Mn)-based oxide including Mn as an essential transition metal and having a layered crystal structure, in which the amount of Mn is greater than that of other transition metal(s), the lithium manganese-based oxide exhibits flat level section characteristics in which release of oxygen occurs together with lithium deintercalation during first charging in a high voltage range of 4.4 V or higher, and at least one of a transition metal layer including Mn and an oxygen layer is substituted or doped with a pillar element.
摘要:
Disclosed is a cathode active material in which lithium cobalt oxide particles and manganese (Mn) or titanium (Ti)-containing lithium transition metal oxide particles co-exist and a method of preparing the same.
摘要:
The present invention relates to a method for preparing a positive electrode active material, including: a first step of adding to a reactor, a reaction solution including a transition metal-containing solution containing at least one among nickel, cobalt, and manganese, an ammonium ion-containing solution, and a basic aqueous solution to form seeds of precursor particles; a second step of preparing carbon-introduced precursor particles by adding a carbon source to the reactor when the precursor particles grow until an average particle diameter (D 50 ) of the precursor particles is 30% in size of the average particle diameter (D 50 ) of the finally prepared precursor particles; and a third step of mixing the carbon-introduced precursor particles and a lithium raw material and sintering the mixture at a temperature of 750 °C to 950 °C to prepare positive electrode active material particles, wherein the carbon introduced to the precursor particles is volatilized by the sintering of the third step to form cavities in the positive electrode active material particles, and a cavity ratio of the positive electrode active material is 5% to 20%.
摘要:
The present invention provides a positive electrode active material for a lithium secondary battery that is a lithium composite transition metal oxide including transition metals including nickel (Ni), cobalt (Co), and manganese (Mn), and the lithium composite transition metal oxide is doped with doping elements including cobalt (Co) and titanium (Ti), the lithium composite transition metal oxide includes at least one lithium layer and at least one transition metal layer including the transition metals, the lithium layer and the transition metal layer are alternately arranged, a thickness of the lithium layer is in a range of 2.146 Å to 2.182 Å, and a thickness of the transition metal layer is in a range of 2.561 Å to 2.595 Å.
摘要:
Disclosed are a transition metal precursor for preparation of a lithium composite transition metal oxide, the transition metal precursor including a composite transition metal compound represented by Formula 1 below and a hydrocarbon compound, and a method of preparing the same:
Mn a M b (OH 1-x ) 2 (1)
wherein M is at least two selected from the group consisting of Ni, Co, Mn, Al, Cu, Fe, Mg, B, Cr, and second period transition metals; 0.4≤a≤1; 0≤b≤0.6; a+b≤1; and 0 The transition metal precursor includes a particular composite transition metal compound and a hydrocarbon compound, and thus, when a lithium composite transition metal oxide is prepared using the same, carbon may be present in lithium transition metal oxide particles and/or on surfaces thereof, whereby a secondary battery including the lithium composite transition metal oxide exhibits excellent rate characteristics and long lifespan.