摘要:
The present invention provides a positive electrode active material for a secondary battery and a secondary battery including the same, which includes a core; a shell located to surround the core; and a buffer layer located between the core and the shell, and including a three-dimensional network structure connecting the core and the shell and a pore, in which the core, the shell, and the three-dimensional network structure in the buffer layer each independently include a lithium nickel-manganese-cobalt-based composite metal oxide, and the positive electrode active material has a BET specific surface area of 0.2 m 2 /g to 0.5 m 2 /g, a porosity of 30 vol% or less, and an average particle size (D 50 ) of 8 µm to 15 µm. The decomposition of the active material may be minimized by a rolling process in the manufacture of an electrode by controlling the specific surface area, average particle diameter and porosity of the active material particles as well as the specific structure, the reactivity with an electrolyte solution may be maximized, and the output and lifespan characteristics of the secondary battery may be improved since the particles forming the shell have crystal structure with orientation which facilitates intercalation and deintercalation of lithium ions.
摘要:
The present invention relates to a method for decomposing a phenolic by-product, and more particularly, to a method for decomposing a phenolic by-product generated in a phenol preparation process, the method including: a step (S10) of adding a phenolic by-product stream, a decomposition apparatus side discharge stream, and process water to a mixing apparatus and mixing the phenolic by-product stream, the decomposition apparatus side discharge stream, and the process water; a step (S20) of adding a mixing apparatus discharge stream discharged from the mixing apparatus to a phase separation apparatus and phase-separating the mixing apparatus discharge stream into an oil phase and an aqueous phase; a step (S30) of feeding an oil phase stream obtained by the phase-separation in the step (S20) and discharged to a decomposition apparatus and decomposing the oil phase stream; and a step (S40) of circulating the decomposition apparatus side discharge stream obtained by the decomposition in the step (S30) to the mixing apparatus in the step (S10).
摘要:
The present invention provides a positive electrode active material for a lithium secondary battery including a core including first lithium cobalt oxide, and a surface modifying layer positioned on a surface of the core. The surface modifying layer includes a lithium compound discontinuously distributed on the surface of the core, and second lithium cobalt oxide distributed while making a contact with or adjacent to the lithium compound, with a Li/Co molar ratio of less than 1. The lithium compound includes at least one lithium reactive element selected from the group consisting of Ti, W, Zr, Mn, Mg, P, Ni, Al, Sn, V, Cr, and Mo. The positive electrode active material according to the present invention forms a lithium deficient structure in the positive electrode active material of lithium cobalt oxide and changes two-dimensional lithium transport path into three-dimensional path. The transport rate of lithium ions may increase when applied to a battery, thereby illustrating improved capacity and rate characteristic without decreasing initial capacity. As a result, the positive electrode active material may be useful as a positive electrode active material of a battery for a high voltage with 4.4 V or more.
摘要:
The present disclosure provides a method for decomposing a phenolic by-product, the method including: a step S10 of feeding a phenolic by-product stream to a decomposition apparatus and thermally cracking the phenolic by-product stream; a step S20 of recovering an active ingredient from a top discharge stream of the decomposition apparatus and discharging a substance having a high boiling point through a bottom discharge stream of the decomposition apparatus; a step S30 of passing a part of the bottom discharge stream of the decomposition apparatus through a reboiler and then feeding the part of the bottom discharge stream of the decomposition apparatus to the decomposition apparatus and discharging a residual stream of the bottom discharge stream of the decomposition apparatus; and a step S40 of feeding a side discharge stream of the decomposition apparatus to the reboiler.
摘要:
The present invention relates to a positive electrode active material for a lithium secondary battery, and a lithium secondary battery including the same, and the positive electrode active material includes lithium cobalt oxide particles. The lithium cobalt oxide particles include lithium cobalt oxide having a Li/Co molar ratio of less than 1 in the particles. Good rate property and life property may be obtained without worrying on the deterioration of initial capacity property.
摘要:
Provided is a method of decomposing phenolic by-products, and more particularly, a method of decomposing phenolic by-products including: supplying a phenolic by-product stream to a decomposition device to perform thermal decomposition; separating an upper discharge stream including effective components and a lower discharge stream including materials having a high boiling point in the decomposition device; supplying the lower discharge stream from the decomposition device, a side discharge stream from the decomposition device, and a process water stream to a mixing device and mixing these streams; and supplying a discharge stream from the mixing device to a layer separation device to separate the dischrage stream from the mixing device into an oil phase and an aqueous phase.
摘要:
The present invention relates to a method of decomposing a phenolic by-product, and more particularly, to a method of decomposing a phenolic by-product, the method including: a step of feeding and thermally cracking a phenolic by-product stream to and in a decomposition apparatus, recovering an active ingredient from a top discharge stream, and discharging a high-boiling substance through a bottom discharge stream; a step of pressurizing each of a side discharge stream of the decomposition apparatus and a bottom discharge stream of the decomposition apparatus; a step of mixing the pressurized side discharge stream of the decomposition apparatus and the pressurized bottom discharge stream of the decomposition apparatus with each other to form a mixed stream; and a step of passing a part of the mixed stream through a reboiler, circulating the part of the mixed stream to the decomposition apparatus, and discharging a residual mixed stream.
摘要:
The present invention relates to a positive electrode active material for a secondary battery which includes a lithium composite transition metal oxide including nickel (Ni), cobalt (Co), and manganese (Mn), and a glassy coating layer formed on surfaces of particles of the lithium composite transition metal oxide, wherein, in the lithium composite transition metal oxide, an amount of the nickel (Ni) in a total amount of transition metals is 60 mol% or more, and an amount of the manganese (Mn) is greater than an amount of the cobalt (Co), and the glassy coating layer includes a glassy compound represented by Formula 1.
[Formula 1] Li a M 1 b O c
In Formula 1, M 1 is at least one selected from the group consisting of boron (B), aluminum (Al), silicon (Si), titanium (Ti), and phosphorus (P), and 1≤a≤4, 1≤b≤8, and 1≤c≤20.
摘要:
The present invention relates to a positive electrode material including a spinel-structured lithium manganese-based first positive electrode active material and a lithium nickel-manganese-cobalt-based second positive electrode active material, wherein the first positive electrode active material includes a lithium manganese oxide represented by Formula 1 and a coating layer which is disposed on a surface of the lithium manganese oxide and includes at least one element selected from the group consisting of Al, Ti, W, B, F, P, Mg, Ni, Co, Fe, Cr, V, Cu, Ca, Zn, Zr, Nb, Mo, Sr, Sb, Bi, Si, and S, the second positive electrode active material is represented by Formula 2, and an average particle diameter of the second positive electrode active material is greater than an average particle diameter of the first positive electrode active material, and a positive electrode and a lithium secondary battery which include the positive electrode material.
[Formula 1] Li 1+a Mn 2-b M 1 b O 4-c A c
In Formula 1, M 1 is at least one element selected from the group consisting of Al, Li, Mg, Zn, B, W, Ni, Co, Fe, Cr, V, Ru, Cu, Cd, Ag, Y, Sc, Ga, In, As, Sb, Pt, Au, and Si, A is at least one element selected from the group consisting of F, Cl, Br, I, At, and S, 0≤a≤0.2, 0
[Formula 2] Li 1+x [Ni y Co z Mn w M 2 v ]O 2-p B p
In Formula 2, M 2 is at least one element selected from the group consisting of W, Cu, Fe, V, Cr, Ti, Zr, Zn, Al, In, Ta, Y, La, Sr, Ga, Sc, Gd, Sm, Ca, Ce, Nb, Mg, B, and Mo, B is at least one element selected from the group consisting of F, Cl, Br, I, At, and S, 0≤x≤0.3, 0.50≤y