SUPERABSORBENT RESIN AND PREPARATION METHOD OF SAME

    公开(公告)号:EP3819330A1

    公开(公告)日:2021-05-12

    申请号:EP19908136.5

    申请日:2019-12-20

    申请人: LG Chem, Ltd.

    摘要: The present disclosure relates to a super absorbent polymer and a preparation method of the same, which not only has excellent basic absorption performance, but also exhibits an improved absorption rate, and the like. The super absorbent polymer includes a base resin powder containing a first cross-linked polymer of a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer containing a second cross-linked polymer in which the first cross-linked polymer is additionally cross-linked by a surface cross-linking agent on the base resin powder, wherein the super absorbent polymer contains less than 9.9% by number of super absorbent polymer particles having an aspect ratio, which is defined as shortest diameter/longest diameter of each super absorbent polymer particle, of less than 0.5, a vortex time is 5 to 55 seconds by a vortex method, and a surface tension is 50 to 80 mN/m.

    METHOD FOR PREPARING SUPER ABSORBENT POLYMER, AND SUPER ABSORBENT POLYMER

    公开(公告)号:EP3763771A1

    公开(公告)日:2021-01-13

    申请号:EP19867685.0

    申请日:2019-09-24

    申请人: LG CHEM, LTD.

    摘要: The present disclosure relates to a preparation method of a super absorbent polymer having excellent basic absorbency and liquid permeability at the same time by optimizing the degree of cross-linking of a base resin powder and a surface cross-linked layer, and a super absorbent polymer prepared therefrom. The preparation method of a super absorbent polymer includes the steps of: forming a hydrogel polymer by cross-linking and polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent, wherein the water-soluble ethylene-based unsaturated monomer has a degree of neutralization of less than 70 mol% in the step of forming a hydrogel polymer, and the preparation method further includes a step of further neutralizing the base resin powder by treating the base resin powder with a basic solution during the step of forming a surface cross-linked layer or after the step of forming a surface cross-linked layer.

    PREPARATION METHOD OF SUPER ABSORBENT POLYMER

    公开(公告)号:EP4282904A1

    公开(公告)日:2023-11-29

    申请号:EP22911708.0

    申请日:2022-12-08

    申请人: LG Chem, Ltd.

    发明人: LEE, Junwye

    IPC分类号: C08J3/24 C08J3/12

    摘要: The present disclosure relates to a preparation method of a super absorbent polymer. More specifically, it relates to a preparation method of a super absorbent polymer, which can improve a drying efficiency in the preparation process and realize excellent absorption-related properties of the prepared super absorbent polymer by using a specific inorganic material in the reassembly process.

    PREPARATION METHOD OF SUPER ABSORBENT POLYMER

    公开(公告)号:EP4269477A1

    公开(公告)日:2023-11-01

    申请号:EP22898922.4

    申请日:2022-11-14

    申请人: LG Chem, Ltd.

    IPC分类号: C08J3/24

    摘要: Provided is a method of preparing a superabsorbent polymer. More particularly, provided is a method of preparing a superabsorbent polymer, in which degradation of physical properties of the polymer due to a mechanical force generated during a surface crosslinking process is minimized by controlling operating conditions of a surface crosslinking reactor in the step of surface crosslinking, thereby improving absorption properties of the superabsorbent polymer finally prepared.

    METHOD FOR PREPARING SUPERABSORBENT POLYMER
    9.
    发明公开

    公开(公告)号:EP3783053A1

    公开(公告)日:2021-02-24

    申请号:EP19893049.7

    申请日:2019-10-01

    申请人: LG CHEM, LTD.

    摘要: The present disclosure relates to a preparation method of a super absorbent polymer capable of preparing a super absorbent polymer exhibiting an improved absorption rate while reducing an amount of a blowing agent used. The preparation method of a super absorbent polymer includes the steps of: preparing a monomer mixture including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; adjusting a dynamic pressure applied to the monomer mixture being transferred to 140 Pa or more by controlling a transfer rate while transferring the monomer mixture to a polymerization reactor; cross-linking and polymerizing the monomer mixture transferred to the polymerization reactor to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent to form a surface cross-linked layer.