摘要:
The present invention is directed to a novel solvent-free process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic compound which contains one or more primary amino groups in the presence of an acidic catalyst selected from the group consisting of (i) boron trifluoride etherate and (ii) organic acids having pKa values of from 0.1 to 0.8.
摘要:
The present invention is directed to a process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic compound which contains one or more primary amino groups in the presence of a solvent and an acidic catalyst selected from the group consisting of (i) boron trifluoride etherate and (ii) organic acids having pKa values of from 0.1 to 0.8, with the proviso that if the primary amino group containing compound contains no aromatically bound amino groups, the pKa of said organic acid is from 0.1 to less than 0.7.
摘要:
The present invention is directed to novel amino compounds. The present invention is also directed to several processes for preparing amino group containing compounds. More particularly, the present invention is directed to a novel amino compound corresponding to the formula:
where
A represents the polyfunctional radical left by the removal of the hydroxyl groups from a polyol of functionality of n, R represent an arylene radical of from 6 to 21 carbon atoms, and n is an integer of from 2 to 6.
摘要:
The present invention is directed to a process for the preparation of panels or molded products wherein particles of materials capable of being compacted are mixed with a binder and the mixture are subsequently formed into panels or molded products by the application of heat and pressure. The Invention resides in the use of a binder which is a solid polyisocyanate having a melting point above 40°C.
摘要:
The present invention is directed to a novel solvent-free process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic compound which contains one or more primary amino groups in the presence of an acidic catalyst selected from the group consisting of (i) boron trifluoride etherate and (ii) organic acids having pKa values of from 0.1 to 0.8.
摘要:
The present invention is directed to a process for preparing amine terminated compounds by reacting a polyfunctional acetoacetic acid ester with either ammonia or an organic compound which contains one or more primary amino groups in the presence of a solvent and an acidic catalyst selected from the group consisting of (i) boron trifluoride etherate and (ii) organic acids having pKa values of from 0.1 to 0.8, with the proviso that if the primary amino group containing compound contains no aromatically bound amino groups, the pKa of said organic acid is from 0.1 to less than 0.7.
摘要:
The present invention is directed to a RIM process utilizing amine chain-extenders and amines of the formula: where R₁ is an n-valent group obtained by the removal of hydroxyl groups from an n-hydroxy group containing polyhydroxyl compound having a molecular weight of from about 400 to about 12,000, R₂ represents hydrogen or an inert substituent, y is 1 or 2, and n represents an integer from 2 to 8. Systems of improved flow are obtained.