公开(公告)号：EP1775304A4

公开(公告)日：2010-04-28

申请号：EP05762068

申请日：2005-07-12

申请人： MITSUBISHI CHEM CORP

发明人： TAKEHARA JUN ,  FUJIWARA NAOYA ,  KAWAI JUNYA ,  ENDOU KYOUKO

IPC分类号： C07J9/00 ,  C07J17/00

CPC分类号： C07J17/00 ,  C07J9/005

公开(公告)号：EP1985621A4

公开(公告)日：2010-05-19

申请号：EP07713600

申请日：2007-01-12

申请人： MITSUBISHI CHEM CORP

发明人： TAKEHARA JUN ,  FUJIWARA NAOYA ,  ENDOU KYOUKO ,  KAWAI JUNYA ,  HOSOKAWA AKEMI ,  SUMITANI NAOKO

IPC分类号： C07J9/00 ,  C07J17/00

CPC分类号： C07J9/005 ,  C07J17/00

公开(公告)号：EP1486493A4

公开(公告)日：2007-04-04

申请号：EP03712723

申请日：2003-03-17

申请人： MITSUBISHI CHEM CORP

发明人： TAKEHARA JUN ,  QU JINGPING ,  KANNO KAZUAKI ,  KAWABATA HIROSHI ,  DEKISHIMA YASUMASA ,  UEDA MAKOTO ,  ENDO KYOKO ,  MURAKAMI TAKESHI ,  SASAKI TOMOKO ,  UEHARA HISATOSHI ,  MATSUMOTO YOUICHI ,  SUZUKI SHIHOMI

IPC分类号： B01J31/18 ,  C07D333/20 ,  C07D333/24 ,  C12P7/04 ,  C12P17/00 ,  C07B53/00

CPC分类号： C12P17/00 ,  B01J31/1805 ,  B01J2231/643 ,  B01J2531/821 ,  C07B2200/07 ,  C07D333/20 ,  C07D333/24 ,  C12P7/04

摘要： A 3-hydroxy-3-(2-thienyl)propionamide compound represented by the following general formula (1), which is useful as an intermediate for medicines, etc.; and a process for industrially producing at low cost an optically active 3-amino-1-(2-thienyl)-1-propanol compound from the propionamide compound in a high reaction yield and high optical yield. The process comprises subjecting a ß-ketocarbonyl compound having a thiophene ring to asymmetric reduction either in the presence of a catalyst comprising a compound of a Group 8 or 9 metal of the Periodic Table (e.g., ruthenium compound) and an asymmetric ligand represented by a specific optically active diamine derivative (e.g., diphenylethylenediamine derivative) or using cells of a microorganism, a product of treatment of the cells, etc. According to need, the product of the asymmetric reduction is subjected to ester group amidation and then amide group reduction. Thus, a 3-amino-1-(2-thienyl)-1-propanol compound is obtained.

公开(公告)号：EP0949243A4

公开(公告)日：2000-12-27

申请号：EP97913440

申请日：1997-11-25

申请人： MITSUBISHI CHEM CORP

发明人： ODA MASATSUGU ,  KATSURADA MANABU ,  SHIGA YASUSHI ,  OHNO FUMIHIKO ,  TANAKA KEN ,  TOMITA HIROFUMI ,  FUKUCHI TOSHIKI ,  SUZUKI SHIGERU ,  OKANO KAZUYA ,  SHIRASAKI MIWA ,  TAKEHARA JUN ,  IWANE HIROSHI

IPC分类号： A01N37/50 ,  C07C45/00 ,  C07C251/48 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07D317/30 ,  C07C29/136 ,  C07C33/22 ,  C07C45/42 ,  C07C239/20 ,  C07C249/04 ,  C07C249/08 ,  C07C249/12 ,  C07C259/04 ,  C07C271/06 ,  C07C309/63

CPC分类号： C07D317/30 ,  A01N37/50 ,  C07C45/00 ,  C07C251/48 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C49/80

摘要： Methoxyiminoacetamide derivatives represented by general formula (I), exhibiting negative specific rotations in chloroform, and having an extremely excellent pesticidal activity, wherein Ar is aryl or heteroaryl; Y is hydrogen, halogeno, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylthio, C2-C6 alkynyloxy, cyano, nitro or aryl; and n is an integer of 1 to 3.

摘要翻译： （上述通式中的下述通式（I）表示的光学活性甲氧衍生物，在芳基或杂芳基团Ar darstellt，Y表示氢原子，卤原子，C1-C4烷基 ，一个C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基，C2-C6炔氧基，氰基，硝基或芳基和n是 上述1〜3）的整数，worin其旋转角度示出在氯仿中的负值具有显着优异的活动，作为农业化学品。