摘要:
A process for producing hydroxycarboxylic acids which comprises reacting an aldehyde compound, carbon monoxide and water in a reaction medium, said reaction being carried out in the presence of a crystalline aluminosilicate whose X-ray diffraction pattern shows at least five clear diffraction lines at a diffraction angle 20 of 7.9°±0.3°, 8.8°±0.3°, 23.2°±0.3°, 23.7°±0.3°, and 24.4°±0.3° while the concentration of the aldehyde compound in the reaction , mixture is maintained at not more than 15% by weight based on the total weight of the aldehyde compound and the reaction medium.
摘要:
A process for producing a crystalline aluminosilicate comprises hydrothermally reacting a starting mixture composed of a silicon compound, an aluminum compound, an alkali metal compound, a compound capable of releasing an organic cation in water and water, the starting mixture comprising at least two colloids having different silicon/aluminum atomic ratios, and the hydrothermal reaction optionally being carried out in the presence of a fluorine compound.
摘要:
A crystalline aluminosilicate (which may contain ftuorine) has in its X-ray diffraction pattern seven diffraction lines showing the following relative intensities at the positions of the following respective diffraction angles (2θ):
Such crystalline aluminosilicates are produced as relatively large crystals by carrying out a hydrothermal synthetic reaction in the presence of a fluorine compound. The crystalline aluminosilicates can be used as an adsorbent for the separation of various compounds, for example. the isomers of hydrocarbons, or can be converted to a solid acid by treatment with an acid such as hydrochloric acid and be used as catalysts for various reactions, for example, the preparation of olefins from methanol or dimethyl ether by the dehydration reaction.
摘要:
p-Cresol is produced in one step by direct oxidation of p-tolualdehyde with a peroxide in formic acid as a solvent while keeping 3 to 15% by weight of water in formic acid on the basis of formic acid and a reaction temperature in a range of 50° to 150°C.
摘要:
A transition element-containing crystalline aluminosilicate having seven diffraction lines showing the following interplanar spacings and relative intensities in its X-ray diffraction pattern:
provided that the relative intensities are shown taking the intensity of any of the diffraction lines showing an interplanar spacing of 10.0 ± 0.4 or 3.83 ± 0.05 A as 100. This crystalline aluminosilicate is useful as an adsorbent or catalyst.