EMULSIFYING AGENT FOR EMULSION POLYMERIZATION
    2.
    发明公开
    EMULSIFYING AGENT FOR EMULSION POLYMERIZATION 有权
    乳化剂,用于乳液聚合

    公开(公告)号:EP2805974A1

    公开(公告)日:2014-11-26

    申请号:EP13738866.6

    申请日:2013-01-09

    IPC分类号: C08F2/24

    摘要: Provided is a reactive emulsifier for emulsion polymerization, capable of enhancing stability during emulsion polymerization, avoiding a processing trouble by reducing foaming in a polymer dispersion, and improving the properties such as water resistance of a polymer film obtained from the polymer dispersion. An emulsifier for emulsion polymerization containing a compound represented by the following general formula (I) is used. In the general formula (I), R 0 represents an alkyl group having 1 to 4 carbon atoms, R 1 represents one or two types of groups selected from the groups shown below, R 2 represents hydrogen or a methyl group, D represents a polymerizable unsaturated group represented by the chemical formula D-1 or D-2 shown below, R 3 represents a hydrogen atom or a methyl group, m1 represents a number of 1 to 2, m2 represents a number of 1 to 4, m3 represents a number of 0 or 1, A represents an alkylene group or a substituted alkylene group having 2 to 4 carbon atoms, n represents an average addition mole number of alkylene oxide and represents a number in the range of 0 to 1,000, X represents a hydrogen atom or an anionic hydrophilic group selected from -(CH 2 ) a -SO 3 M, -(CH 2 ) b -COOM, -PO 3 M 2 , -P(Z)O 2 M, and -CO-CH 2 -CH(SO 3 M)-COOM, wherein a and b each represent a number of 0 to 4, Z represents a residue obtained by removing X from the general formula (I), and M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an ammonium residue, or an alkanolamine residue.

    R 1 :
    D-1:
    D-2:

    Process for production of hydroxycarboxylic acids
    6.
    发明公开
    Process for production of hydroxycarboxylic acids 失效
    Verfahren zur Herstellung vonHydroxycarbonsäuren。

    公开(公告)号:EP0114657A1

    公开(公告)日:1984-08-01

    申请号:EP84100502.8

    申请日:1984-01-18

    摘要: A process for producing hydroxycarboxylic acids which comprises reacting an aldehyde compound, carbon monoxide and water in a reaction medium, said reaction being carried out in the presence of a crystalline aluminosilicate whose X-ray diffraction pattern shows at least five clear diffraction lines at a diffraction angle 20 of 7.9°±0.3°, 8.8°±0.3°, 23.2°±0.3°, 23.7°±0.3°, and 24.4°±0.3° while the concentration of the aldehyde compound in the reaction , mixture is maintained at not more than 15% by weight based on the total weight of the aldehyde compound and the reaction medium.

    摘要翻译: 一种制备羟基羧酸的方法,其包括在反应介质中使醛化合物,一氧化碳和水反应,所述反应在晶体硅铝酸盐的存在下进行,其结晶硅铝酸盐的X射线衍射图在衍射下显示出至少五个透明的衍射线 角度20为7.9°±0.3°,8.8±0.3°,23.2°±0.3°,23.7°±0.3°和24.4°±0.3°,而醛化合物的浓度为 基于醛化合物和反应介质的总重量,将反应混合物保持在不超过15重量%。