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    Composite heat-insulating material containing a cellular urethane
    1.
    发明公开
    Composite heat-insulating material containing a cellular urethane 失效
    Polyurethanschaumstoffenthaltendend zusammengestellteswärmeisolierendes材料。

    公开(公告)号：EP0214747A2

    公开(公告)日：1987-03-18

    申请号：EP86305870.7

    申请日：1986-07-30

    申请人： MITSUBISHI PETROCHEMICAL CO., LTD.

    发明人： Yazaki, Takao ,  Hattori, Satoru ,  Hattori, Kazuhide ,  Matsuno, Takumi ,  Shibuya, Nobuhiro ,  Hayama, Kazuhide ,  Itoh, Isao

    IPC分类号： F25D23/08 ,  B32B5/18 ,  B32B27/40

    CPC分类号： B32B7/12 ,  B32B5/18 ,  B32B27/065 ,  B32B27/32 ,  B32B2266/0278 ,  B32B2323/10 ,  F25D23/064 ,  Y10T428/249985 ,  Y10T428/249992 ,  Y10T428/249993 ,  Y10T428/31576 ,  Y10T428/31587

    摘要： A sheet of a polymer comprising at least 50 mol% of units of an olefin (e.g. polypropylene ) is coated on one surface with an aqueous solution or dispersion

    (A) 55 to 90% of a polymer comprising an olefin;
    (B) 1 to 30% of a copolymer of ethylene and acrylic acid; and
    (C) 10 to 30% of a polymer containing styrene units.

    The sheet optionally contains up to 65% of an inorganic fine powder.
    The adhesive layer adheres strongly to a cellular foamed polyurethane, to form a composite heat-insulating material without voids.
    The polymer sheet can be deep-drawn to shape, adhesive-coated, placed over the metal pressing of a refrigerator body or door, and the urethane components injected through a hole in the sheet so that the poly­urethane is formed between the sheet and the metal pressing and is foamed and adhered in situ ; the sheet can be a laminate having a lustrous outer surface layer.

    摘要翻译： 包含至少50摩尔％的烯烃（例如聚丙烯）单元的聚合物片材在一个表面上用水溶液或分散体涂覆......（A）55-90％的包含烯烃的聚合物; ...（B）乙烯与丙烯酸共聚物的1〜30％ 和（C）含有苯乙烯单元的聚合物的10〜30％。 ......片材任选地含有最多65％的无机细粉末。 粘合剂层牢固地附着在泡沫聚氨酯上，形成无空隙的复合绝热材料。 ...聚合物片材可以被深拉以成形，粘合剂涂覆，放置在冰箱体或门的金属压制上，并且聚氨酯组分通过孔中的孔注入，使得聚氨酯形成在 片材和金属压制，并原位发泡和粘附; 片材可以是具有光泽的外表面层的层压体。

    Thermoformable propylene polymer laminated sheet
    2.
    发明公开
    Thermoformable propylene polymer laminated sheet 失效
    热塑性聚丙烯酸酯

    公开(公告)号：EP0172277A1

    公开(公告)日：1986-02-26

    申请号：EP84305027.9

    申请日：1984-07-24

    申请人： MITSUBISHI PETROCHEMICAL CO., LTD.

    发明人： Hattori, Satoru ,  Yazaki, Takao ,  Hattori, Kazuhide ,  Nishida, Koji ,  Hattori, Hideki ,  Fujimura, Kazumasa

    IPC分类号： B32B27/32

    CPC分类号： B32B27/32 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B2307/704 ,  B32B2323/04 ,  B32B2323/10

    摘要： A propylene polymer laminated sheet comprises at least two layers wherein at least one surface layer (A) comprises 95% by weight or more of a specific crystalline propylene polymer and optionally up to 5% by weight of an inorganic or organic nucleating agent, the thickness of Layer A being from 0.5 to 45% of the total thickness of the sheet, and at least one other layer (B) comprises 40 to 95 parts by weight of a resin component and 60 to 5 parts by weight of an inorganic filler, the resin component comprising from 5 to 85% by weight of a specific crystalline propylene polymer and from 95 to 15% by weight of an ethylene polymer, the thickness of Layer B being from 55 to 99.5% of the total thickness of the sheet.
    This sheet is thermoformable and has excellent deep drawing properties and can produce a product having excellent surface gloss, appearance and impact resistance.

    摘要翻译： 丙烯聚合物层压片材包括至少两层，其中至少一个表面层（A）包含95重量％以上的特定结晶丙烯聚合物和任选的至多5重量％的无机或有机成核剂，其厚度 层A的厚度为片材总厚度的0.5〜45％，至少一层（B）为40〜95重量份的树脂成分和60〜5重量份的无机填料， 树脂组分包含5至85重量％的特定结晶丙烯聚合物和95至15重量％的乙烯聚合物，层B的厚度为片材总厚度的55至99.5％。 该片材是可热成型的并且具有优异的深拉伸性能，并且可以生产具有优异的表面光泽，外观和耐冲击性的产品。

    Composite heat-insulating material containing a cellular urethane
    4.
    发明公开
    Composite heat-insulating material containing a cellular urethane 失效
    Zellulares Polyurethan enthaltenderwärmeisolierenderVerbundwerkstoff。

    公开(公告)号：EP0150942A2

    公开(公告)日：1985-08-07

    申请号：EP85300217.8

    申请日：1985-01-11

    申请人： MITSUBISHI PETROCHEMICAL CO., LTD.

    发明人： Yazaki, Takao ,  Matsuno, Takumi ,  Hattori, Kazuhide ,  Hayama, Kazuhide ,  Ito, Isao ,  Saito, Yukio

    IPC分类号： C09J3/14 ,  B32B5/20 ,  F25D23/06

    CPC分类号： B32B27/065 ,  B32B5/18 ,  B32B5/20 ,  B32B7/12 ,  B32B15/046 ,  B32B2266/0278 ,  B32B2307/304 ,  B32B2509/10 ,  C09J123/08 ,  F23J15/006 ,  Y10T428/249985 ,  Y10T428/249992 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31924 ,  Y10T428/31928

    摘要： A sheet of a polymer comprising at least 50 mol% of units of an olefin or styrene (e.g. a polyethylene or ABS copolymer) is coated on one surface with an aqueous solution or dispersion of an adhesive comprising 20 to 100 wt% of the solids of a polyolefin having carboxyl groups (e.g. a salt of an ethylene/ acrylic acid copolymer). The adhesive optionally contains up to 80% of a N-containing water-soluble antistatic polymer and/or up to 2% of a F-containing surfactant. The opposite surface may be coated with a surfactant.
    The adhesive layer adheres strongly to a cellular foamed polyurethane, to form a composite heat-insulating material.
    The polymer sheet can be deep-drawn to shape, adhesive-coated, placed over the metal pressing of a refrigerator body or door, and the urethane components injected through a hole in the sheet so that the polyurethane is formed between the sheet and the metal pressing and is foamed and adhered in situ.

    摘要翻译： 包含至少50摩尔％的烯烃或苯乙烯单元（例如聚乙烯或ABS共聚物）的聚合物片材在一个表面上用含有20至100重量％固体的粘合剂的水溶液或分散体 的具有羧基的聚烯烃（例如乙烯/丙烯酸共聚物的盐）。 粘合剂任选地含有高达80％的含N的水溶性抗静电聚合物和/或至多2％的含F表面活性剂。 相对表面可以涂覆有表面活性剂。 粘合剂层牢固地附着在泡沫聚氨酯上，形成复合绝热材料。 ...聚合物片材可以被深拉以成形，粘合剂涂覆，放置在冰箱体或门的金属压制上，并且聚氨酯组分通过孔中的孔注入，使得聚氨酯形成在 片材和金属挤压，并原位发泡和粘合。