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    COMPOSITE MATERIAL AND METHOD FOR PREPARATION THEREOF
    4.
    发明公开
    COMPOSITE MATERIAL AND METHOD FOR PREPARATION THEREOF 审中-公开
    VERFANDSTOFFMATERIAL UND VERFAHREN ZUR HERSTELLUNG DAVON

    公开(公告)号：EP3037258A1

    公开(公告)日：2016-06-29

    申请号：EP16000383.6

    申请日：2002-01-09

    申请人： Daicel-Evonik Ltd.

    发明人： Ikuta, Toru ,  Komada, Hajime ,  Mutsuda, Mitsuteru

    IPC分类号： B32B5/08 ,  B32B25/08

    CPC分类号： B32B27/20 ,  B32B5/08 ,  B32B25/08 ,  B32B27/285 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B2367/00 ,  B32B2375/00 ,  C08J5/121 ,  Y10T428/31511 ,  Y10T428/31554 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31569 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31594 ,  Y10T428/31598 ,  Y10T428/31663 ,  Y10T428/31728 ,  Y10T428/31732 ,  Y10T428/31736 ,  Y10T428/31739 ,  Y10T428/31743 ,  Y10T428/31746 ,  Y10T428/3175 ,  Y10T428/31757 ,  Y10T428/31761 ,  Y10T428/31786 ,  Y10T428/31797 ,  Y10T428/31826 ,  Y10T428/31833 ,  Y10T428/31859 ,  Y10T428/31862 ,  Y10T428/3187 ,  Y10T428/31931 ,  Y10T428/31935 ,  Y10T428/31938

    摘要： A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S = C HOMO , n 2 / E c − E HOMO , n + C LUMO , n 2 / E c − E LUMO , n wherein E c :an orbital energy (eV) of a radical, C HOMO,n :a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, E HOMO,n :an orbital energy (eV) of the HOMO, C LUMO,n :a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, E LUMO,n : an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3. The thermoplastic resin includes a polyamide, a polyester, a PPE, a POM, a PPS, a polyolefinic resins, and the unvulcanized rubber may comprise a vulcanization-activating having plural polymerizable unsaturated bonds. The invention gives the composite of the resin bonded directly to the rubber firmly without adhesives in wide combinations of the resin and the rubber.

    摘要翻译： 使用与自由基发生剂（例如有机过氧化物）硫化的橡胶构件和具有至少2个原子的热塑性树脂，平均从H和H中获得与硫化橡胶构件接合的树脂构件的复合材料， S原子，每个原子具有不低于0.006的由下式（1）表示的轨道相互作用能量系数S：S = C HOMO，n 2 / E c'E HOMO，n + C LUMO，n 2 其中E c：自由基的轨道能量（eV），C HOMO，n：第n个H或S的最高占据分子轨道（HOMO）的分子轨道系数 构成树脂的基本单位的原子E HOMO，n：HOMO的轨道能量（eV），C LUMO，n：第n个H的最低未占分子轨道（LUMO）的分子轨道系数， S原子构成树脂的基本单元，E LUMO，n：LUMO的轨道能量（eV），并且首先代表由半经验值计算的值 椭圆轨道法MOPACPM3。 热塑性树脂包括聚酰胺，聚酯，PPE，POM，PPS，聚烯烃树脂，未硫化橡胶可以包含具有多个可聚合不饱和键的硫化活化。 本发明给出了树脂和橡胶的组合较多的粘合剂，直接粘合到橡胶上的树脂的复合材料。