Phthalocyanine compound, its intermediate, process for producing the compound, and use thereof
    1.
    发明公开
    Phthalocyanine compound, its intermediate, process for producing the compound, and use thereof 有权
    酞菁化合物,其中间体,制备该化合物的方法及其用途

    公开(公告)号:EP0928816A2

    公开(公告)日:1999-07-14

    申请号:EP98310559.4

    申请日:1998-12-22

    摘要: The invention relates to a novel phthalocyanine compound absorbing in the near infrared region of the spectrum with a high absorption coefficient which features high solubility in solvents, good compatibility with resins and high aging resistance, thus finding application as a near infrared ray absorbing material or a light-heat conversion material with great advantage and to a process for producing the phthalocyanine compound.
    The novel phthalocyanine compound has the following general formula:
    wherein R represents alkyl or alkoxyalkyl; X represents halogen, alkylthio, phenylthio which may be substituted, or naphthylthio which may be substituted; M represents a couple of hydrogen atoms, a divalent metal, or a trivalent or tetravalent metal derivative.
    The near infrared ray absorbing and light-heat conversion materials containing the above phthalocyanine compound are also described.

    摘要翻译: 本发明涉及一种新型酞菁化合物,该化合物在光谱的近红外区域吸收具有在溶剂中高溶解性,与树脂良好的相容性和高耐老化性的高吸收系数,因此可用作近红外线吸收材料或 光热转换材料和制造酞菁化合物的方法。 该新型酞菁化合物具有下列通式:其中R代表烷基或烷氧基烷基; X代表卤素,烷硫基,可被取代的苯硫基或可被取代的萘硫基; M代表一对氢原子,二价金属或三价或四价金属衍生物。 还描述了含有上述酞菁化合物的近红外线吸收和光热转换材料。

    Phthalocyanine compound, its intermediate, process for producing the compound, and use thereof
    4.
    发明公开
    Phthalocyanine compound, its intermediate, process for producing the compound, and use thereof 有权
    酞菁化合物,将中间产物,制备该化合物和它们的应用方法

    公开(公告)号:EP0928816A3

    公开(公告)日:1999-11-17

    申请号:EP98310559.4

    申请日:1998-12-22

    摘要: The invention relates to a novel phthalocyanine compound absorbing in the near infrared region of the spectrum with a high absorption coefficient which features high solubility in solvents, good compatibility with resins and high aging resistance, thus finding application as a near infrared ray absorbing material or a light-heat conversion material with great advantage and to a process for producing the phthalocyanine compound. The novel phthalocyanine compound has the following general formula:
    wherein R represents alkyl or alkoxyalkyl; X represents halogen, alkylthio, phenylthio which may be substituted, or naphthylthio which may be substituted; M represents a couple of hydrogen atoms, a divalent metal, or a trivalent or tetravalent metal derivative. The near infrared ray absorbing and light-heat conversion materials containing the above phthalocyanine compound are also described.

    摘要翻译: 本发明涉及一种新颖的酞菁化合物在具有高吸收系数的光谱的近红外区域的哪些功能在溶剂中的高溶解性,与树脂和高的耐老化性良好的相容性吸收,从而找到应用程序作为近红外线吸收材料或 光热转换材料以极大的优势,并提供一种生产的酞菁化合物的方法。 新颖的酞菁化合物具有以下通式: worinřdarstellt烷基或烷氧基烷基; X darstellt卤素,烷硫基,苯可被取代,或者萘可被取代; 中号darstellt几个氢原子,二价金属,或者三价或四价的金属的衍生物。 所述近红外线吸收,因而含有上述酞菁化合物的光热转换材料被描述。

    A phtalide compound and a near infrared absorber and a recording material each comprising the same compound
    7.
    发明公开
    A phtalide compound and a near infrared absorber and a recording material each comprising the same compound 失效
    Eine Phthalidverbindung und ein Absorber ins nahen IR Bereich und ein Aufzeichnungsmaterial。

    公开(公告)号:EP0664292A1

    公开(公告)日:1995-07-26

    申请号:EP95300384.5

    申请日:1995-01-23

    摘要: A phthalide compound of general formula (I) and a near infrared absorber and a recording material each utilizing the phthalide compound are disclosed.

    wherein ring A represents a substituent group of the following formula

       where R₁ represents hydrogen, alkyl, alkoxy or halogen; n represents an integer of 1-3; ring B represents a defined aromatic ring; R₂ represents alkyl or aryl; R₃ represents alkyl; R₄ and R₅ independently represent alkyl or unsubstituted or substituted phenyl; R₆ represents hydrogen, alkyl or alkoxy.
    The near infrared absorber and the recorded image on the recording material absorb strongly the near infrared region with no appreciable absorption in the visible region of the spectrum. The near infrared absorber is colorless or pale in color and yet highly capable of absorbing near infrared radiation. The recorded image on the recording material can hardly be read with the eye but can be read with the OCR. Moreover, the effect on the developed shade of any concomitant color former in a recording material is minimal.

    摘要翻译: 公开了通式(I)的酞化合物和近红外吸收剂以及各自使用苯酞化合物的记录材料。 其中环A表示下式的取代基,其中R 1表示氢,烷基,烷氧基或卤素; n表示1-3的整数; 环B表示定义的芳环; R2代表烷基或芳基; R3代表烷基; R4和R5独立地表示烷基或未取代或取代的苯基; R6代表氢,烷基或烷氧基。 记录材料上的近红外吸收体和记录图像强烈地吸收近红外区域,在光谱的可见光区域没有明显的吸收。 近红外吸收剂是无色或浅色的,但能够吸收近红外辐射。 记录材料上记录的图像几乎不能用眼睛读取,但可以用OCR读取。 此外,对记录材料中任何伴随的成色剂的显影性的影响是最小的。

    Method for preparing alkoxyphthalocyanine
    10.
    发明公开
    Method for preparing alkoxyphthalocyanine 失效
    HerstellungsverfahrenfürAlkox氧酞菁。

    公开(公告)号:EP0492508A1

    公开(公告)日:1992-07-01

    申请号:EP91121966.5

    申请日:1991-12-20

    摘要: There is here disclosed a method for preparing an alkoxyphthalocyanine represented by the formula (1):

    wherein each of Rs is independently a secondary alkyl group having 3 to 20 carbon atoms, Met is a divalent metal atom or an oxy metal, and the substitution positions of -ORs are the 1- or 4-position, the 5- or 8-position, the 9- or 12 position, and the 13- or 16-position,
    which comprises the steps of heating a mixture of 3-alkoxyphthalonitrile and an organic base in an alcohol to 90-120°C, adding a metal derivative at the same temperature, and then carrying out reaction, or alternatively the step of reacting a mixture of a 1,3-diimino-4-alkoxyisoindoline and a metal derivative in the presence or absence of an organic base in an aliphatic alcohol having 6 or more carbon atoms. In addition, the ratio of isomers of the alkoxyphthalocyanine can be controlled by regulating the addition time of the organic base.

    摘要翻译: 这里公开了制备由式(1)表示的烷氧基氧酞菁的方法:其中各R各自独立地为具有3-20个碳原子的仲烷基,Met为二价金属原子或氧基金属,和 -ORs的取代位置是1-或4-位,5-或8-位,9-或12位,以及13-或16位,其包括以下步骤:加热3- 烷氧基邻苯二甲腈和醇中的有机碱在90-120℃,在相同温度下加入金属衍生物,然后进行反应,或者将1,3-二亚氨基-4-烷氧基异吲哚啉和 在具有6个或更多个碳原子的脂族醇中存在或不存在有机碱的金属衍生物。 此外,可以通过调节有机碱的添加时间来控制烷氧基酞菁的异构体的比例。