公开(公告)号：EP0691354A1

公开(公告)日：1996-01-10

申请号：EP95110566.7

申请日：1995-07-06

申请人： MITSUI PETROCHEMICAL INDUSTRIES, LTD.

发明人： Sagane, Toshihiro, c/o Mitsui Petrochem. Ind., Ltd ,  Kawasaki, Masaaki, c/o Mitsui Petrochem. Ind., Ltd ,  Nakahama, Hidenari, c/o Mitsui Petrochem. Ind. Ltd ,  Ishida, Tatsuyoshi, c/o Mitsui Petrochem. Co. Ltd. ,  Takahashi, Katsuya, c/o Mitsui Petrochem. Co. Ltd. ,  Tsutsui, Toshiyuki, c/o Mitsui Petrochem. Co. Ltd. ,  Onishi, Hitoshi, c/o Mitsui Petrochem. Co., Ltd. ,  Yasuda, Masaaki, c/o Mitsui Petrochem. Co., Ltd. ,  Kihara, Noriaki, c/o Mitsui Petrochem. Co., Ltd.

IPC分类号： C08F210/18 ,  C08F236/22

CPC分类号： C08F255/02 ,  C07C2/04 ,  C07C11/21 ,  C07C2531/14 ,  C07C2531/24 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65922 ,  C08F210/18 ,  C08F4/65912 ,  C08F210/06 ,  C08F236/22 ,  C08F2500/17

摘要： A novel unsaturated copolymer of ethylene comprises a random copolymer of (i) ethylene, (ii) an α-olefin of 3 to 20 carbon atoms and (iii) at least one straight chain or branched chain nonconjugated triene or tetraene having one vinyl group in the molecule, which contains 30 - 92 % by mol of ethylene units (i), 6 - 70 % by mol of α-olefin units (ii) and 0.1 - 30 % by mol of triene or tetraene units (iii), and which has a molar ratio of ethylene units (i) to α-olefin units (ii) of 40/60 to 92/8 (ethylene units (i)/α-olefin units (ii)) and an intrinsic viscosity [η], measured in decalin at 135 °C, of 0.05 to 10 dl/g.
This novel unsaturated copolymer of ethylene is excellent in weathering resistance, heat resistance and ozone resistance and has a high vulcanizing rate.

摘要翻译： 乙烯的新型不饱和共聚物包括（i）乙烯，（ii）3-20个碳原子的α-烯烃和（iii）至少一种具有一个乙烯基的直链或支链非共轭三烯或四烯的无规共聚物 该分子含有乙烯单元（i）30-92摩尔％，α-烯烃单元（ii）6-70摩尔％和三烯或四烯单元（iii））0.1-30摩尔％，其中 具有40/60至92/8（乙烯单元（i）/α-烯烃单元（ii））的乙烯单元（i）与α-烯烃单元（ii）的摩尔比和特性粘度ÄetaÜ 在135℃的十氢化萘中，为0.05〜10dl / g。 该新颖的乙烯不饱和共聚物耐候性，耐热性和耐臭氧性优异，硫化速度高。