摘要:
A method for producing 3',4'-anhydrovinblastine, which comprises reacting catharanthine with vindoline in the presence of Fe³⁺, removing or inactivating the Fe³⁺, and reacting the reaction product with a reducing agent. 3',4'-Anhydrovinblastine is useful as an antineoplastic drug.
摘要:
A 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]-urea is prepared by a process which comprises alkylating a novel 1-hydroxy-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea with a corresponding alkylating agent selected from the group consisting of a sulfuric acid ester and an alkyl halide in the presence of a basic compound. The 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea has a herbicidal activity. New intermediates and processes for production thereof are also disclosed.
摘要:
The present invention relates to herbicidal compositions containing a urea compound represented by the following formula [I]:
[wherein Ar is any one of a group represented by the formula:
(wherein R 1 to R 5 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxy group,
R 6 represents a hydrogen atom, a lower alkyl group, a lower alkoxyl group, or a hydroxyl group; a pair of R 1 and R 5 or a pair of R 5 and R 6 each, taken together, may represent an alkylene linkage which may be substituted by lower alkyl group, and may form 4 to 6 membered-ring with carbon atoms to which they are bound, or R 1 and R 2 , taken together, may form an ethylenedioxyl linkage, or R 4 and R 5 , taken together, may form a dichloromethylene linkage), A represents
(wherein X represents a hydrogen atom, a chlorine atom, a nitro group or a trifluoromethyl group) and B represents a hydrogen atom, methyl group or methoxy group] and (ii) a compound represented by the following formula [a]:
(wherein n is 1 or 2, Y is a chlorine atom) or 3,6-dichloropicolinic acid, 2,4-dichlorophenoxy acetic acid, or 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5-(4H)one.
摘要:
The present invention relates to herbicidal compositions containing a urea compound represented by the following formula [I]:
[wherein Ar is any one of a group represented by the formula: (wherein R 1 to R 5 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxy group, R 6 represents a hydrogen atom, a lower alkyl group, a lower alkoxyl group, or a hydroxyl group; a pair of R 1 and R 5 or a pair of R 5 and R 6 each, taken together, may represent an alkylene linkage which may be substituted by lower alkyl group, and may form 4 to 6 membered-ring with carbon atoms to which they are bound, or R 1 and R 2 , taken together, may form an ethylenedioxyl linkage, or R 4 and R 5 , taken together, may form a dichloromethylene linkage), A represents
(wherein X represents a hydrogen atom, a chlorine atom, a nitro group or a trifluoromethyl group) and B represents a hydrogen atom, methyl group or methoxy group] and (ii) a compound represented by the following formula [a]:
(wherein n is 1 or 2, Y is a chlorine atom) or 3,6-dichloropicolinic acid, 2,4-dichlorophenoxy acetic acid, or 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5-(4H)one.
摘要:
A 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]-urea is prepared by a process which comprises alkylating a novel 1-hydroxy-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea with a corresponding alkylating agent selected from the group consisting of a sulfuric acid ester and an alkyl halide in the presence of a basic compound. The 1-lower alkoxy-1-lower alkyl-3-[4-(2-lower alkoxy-2,3-dihydro-7-benzopyranyloxy)phenyl]urea has a herbicidal activity. New intermediates and processes for production thereof are also disclosed.