公开(公告)号：EP0477626A1

公开(公告)日：1992-04-01

申请号：EP91115087.8

申请日：1991-09-06

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Moriyasu, Koichi ,  Oda, Kengo ,  Tomiya, Kanji ,  Miura, Tohru ,  Nishida, Makoto ,  Hibi, Sachiko

IPC分类号： C07D207/26 ,  C07D207/27 ,  C07B63/00 ,  A01N43/36

CPC分类号： C07D207/26 ,  A01N43/36

摘要： A 3,4-cis isomer of 4-ethyl-1-(substituted phenyl)-3-(substituted phenyl)pyrrolidin-2-one, when reacted with a base, can be effectively convered into a 3,4-trans isomer thereof which has a high herbicidal activity useful as an effective ingredient for a herbicidal composition. Furthermore, 3,4-trans-4-ethyl-1-(substituted phenyl)-3-(substituted phenyl)pyrrolidin-2-one compounds represented by the formula (III)

(wherein R² is an isopropyl group, and X is a fluorine atom, chlorine atom or bromine atom substituted at the 3-position, or fluorine atoms substituted at the 3- and 4-positions or the 3- and 5-positions)
have an extremely excellent activity particularly as a herbicidally active ingredient of the herbicidal composition for rice paddy fields.

摘要翻译： 4-乙基-1-（取代苯基）-3-（取代苯基）的3,4-顺式异构体吡咯烷-2-酮，当与碱反应时，可有效地convered成3,4-反式异构体及其 其具有作为对除草组合物有效成分是有用的高的除草活性。 进一步，3,4-反-4-乙基-1-（取代苯基）-3-（取代苯基）吡咯烷-2-酮所示的化合物由式（III）（worinř<2>为异丙 基，且X为在3-位上的氟原子，氯原子或溴原子substituiertem，或氟原子substituiertem在3-和4-位或3-和5-位>具有极其优异的活性特别是作为 用于稻田除草组合物的除草活性成分。

公开(公告)号：EP0387869B1

公开(公告)日：1993-07-21

申请号：EP90104905.6

申请日：1990-03-15

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Oda, Kengo ,  Moriyasu, Koichi ,  Arai, Kiyoshi ,  Tomiya, Kanji ,  Miura, Tohru ,  Nishida, Makoto ,  Oyamada, Masami ,  Fujiwara, Akie

IPC分类号： C07D207/26 ,  A01N43/36

CPC分类号： C07D207/27 ,  A01N43/36

公开(公告)号：EP0435186A2

公开(公告)日：1991-07-03

申请号：EP90125078.7

申请日：1990-12-21

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Ishii, Tsutomu ,  Ishikawa, Katsutoshi ,  Gohbara, Masatoshi ,  Iwasaki, Yasunaga ,  Nishida, Makoto

IPC分类号： C07D401/12 ,  A01N43/54

CPC分类号： C07D401/12 ,  A01N43/54

摘要： Pyridyloxypyrimidine derivatives represented by the following formula [I]:

wherein R means a formyl group or an acetal group represented by
R¹ and R² being the same or different and individually denoting an alkyl group having 1-4 carbon atoms or R¹ and R² being coupled together and denoting an alkylene group, R³, having 2-3 carbon atoms; preparation processes of the derivatives; and herbicidal compositions containing one or more of the derivatives as an active ingredient.

摘要翻译： 由下述式[I]表示吡啶基氧嘧啶衍生物： worin R意指甲酰基或由 - [R <1>和R <2>可以相同或不同，各自表示烷基的具有代表缩醛基 1-4个碳原子，或R <1>和R <2>联接在一起和亚烷基的基团表示，R <3>中，具有2-3个碳原子; 该衍生物的制备方法; 和除草组合物含有一种或多种的衍生物作为活性成分。

公开(公告)号：EP0379174A3

公开(公告)日：1991-04-10

申请号：EP90100924.1

申请日：1990-01-17

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Asano, Tamotsu ,  Ozawa, Shuji ,  Arai, Kiyoshi ,  Yamazaki, Hideo ,  Miura, Tohru ,  Gohbara, Masatoshi ,  Oyamada, Masami ,  Nishida, Makoto

IPC分类号： C07D307/78 ,  C07D409/12 ,  C07D407/12 ,  C07D405/12 ,  A01N43/12

CPC分类号： C07D307/79 ,  A01N47/02 ,  A01N47/06 ,  C07D307/82 ,  C07D307/83 ,  C07D405/12 ,  C07D409/12

摘要： Disclosed are novel 2,3-dihydro-3,3-dimethyl-5-trifluoromethanesulfonyloxy benzofurans and herbicides containing them, which are produced, e.g., via the mono-substituted 2-morpholino derivative, by reacting a corresponding 5-hydroxy benzofuran with a trifluoromethanesulfonyl esterifying agent.

公开(公告)号：EP0387869A2

公开(公告)日：1990-09-19

申请号：EP90104905.6

申请日：1990-03-15

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Oda, Kengo ,  Moriyasu, Koichi ,  Arai, Kiyoshi ,  Tomiya, Kanji ,  Miura, Tohru ,  Nishida, Makoto ,  Oyamada, Masami ,  Fujiwara, Akie

IPC分类号： C07D207/26 ,  A01N43/36

CPC分类号： C07D207/27 ,  A01N43/36

摘要： 4-Ethyl-3-(phenyl)-1-(3-trifluoromethylphenyl)-2-pyrrolidinones and corresponding compounds bearing a p-substituent on the 1-position phenyl group and/or a substituent on the 3-position phenyl group exhibit selective herbicidal activities against various weeds which cause problems in rice or upland fields, even at extremely low application rates. They can be prepared by reductive dehalogenation of a corresponding a-haloethyl substituted pyrrolidinone or reductive cyclization of a corresponding N-2-butenyl-N-(substituted phenyl)-haloacetyl-3-trifluoromethylaniline.

摘要翻译： 4-乙基-3-（苯基）-1-（3-三氟甲基苯基）-2-吡咯烷酮（I）和相应的化合物轴承，对1位的苯基和/或在3-位的苯基的取代基的p取代基 组展对引起即使在极低的应用率在米饭或旱田问题，各种杂草的选择除草活性。 它们可以通过相应的α--haloethyl substituiertem吡咯烷酮或相应的N-2-丁烯基-N-（取代苯基）的还原性环化的还原性脱卤化来制备卤代乙酰基-3-三氟甲基苯胺。 ÿ

公开(公告)号：EP0374839A1

公开(公告)日：1990-06-27

申请号：EP89123466.8

申请日：1989-12-19

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Gohbara, Masatoshi ,  Asano, Tamotsu ,  Ozawa, Shuji ,  Yamazaki, Hideo ,  Ishii, Tsutomu ,  Nishida, Makoto ,  Watanabe, Junko ,  Sato, Naoki

IPC分类号： C07D239/60 ,  A01N43/54

CPC分类号： C07D239/60 ,  A01N43/54

摘要： Disclosed are herbicidally active pyrimidine derivatives of the formula
wherein R represents a hydrogen atom or an etherifying group, e.g., a lower alkyl, lower alkenyl, lower alkynyl, phenyl-substituted lower alkenyl, lower haloalkenyl, cycloalkyl, substituted phenyl-substituted lower alkenyl or phenyl-substituted lower alkynyl group; or a group represented by the following formula:
wherein R 1 represents a hydrogen atom or a lower alkyl group, X a halogen atom or a lower alkyl or lower alkoxyl group, m and n individually 0-2, and when m is 2, both Xs may be the same or different, and herbicidal compositions containing the same, alone or in combination with another herbicidally active compound, the pyrimidine derivatives being prepared by reaction of 2-(4,6-dimethoxy-2-pyrimidinyloxy)-benzaldehyde with NH 2 0R or with a salt of hydroxylamine followed by reaction with a halide of the formula RY wherein R has the same value as above and Y is CI, Br or I.

摘要翻译： 所公开的是在醚化基团，例如，低级烷基，低级链烯基的式 worinřdarstellt氢原子或除草活性的嘧啶衍生物，低级炔基，苯基 - substituiertem低级烯基，低级卤代链烯基，环烷基，substituiertem苯基substituiertem 低级链烯基或苯基取代的低级链炔基; 或由下式表示的基团： worin - [R <1> darstellt氢原子或低级烷基，X为卤素原子或低级烷基或低级烷氧基，m和n独立0-2，和当 m为2，两个X可以是包含相同或不同，且除草组合物是相同的，单独使用或与另一种除草活性化合物组合，由2-（4,6-二甲氧基-2-嘧啶氧基的反应制备的嘧啶衍生物 ）苯甲醛与NH 2或或随后的反应与式RY worin R的卤化物羟胺的盐具有相同的值如上述，Y是Cl，Br或I.

公开(公告)号：EP0435186A3

公开(公告)日：1991-11-27

申请号：EP90125078.7

申请日：1990-12-21

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Ishii, Tsutomu ,  Ishikawa, Katsutoshi ,  Gohbara, Masatoshi ,  Iwasaki, Yasunaga ,  Nishida, Makoto

IPC分类号： C07D401/12 ,  A01N43/54

CPC分类号： C07D401/12 ,  A01N43/54

摘要： Pyridyloxypyrimidine derivatives represented by the following formula [I]:

wherein R means a formyl group or an acetal group represented by
R¹ and R² being the same or different and individually denoting an alkyl group having 1-4 carbon atoms or R¹ and R² being coupled together and denoting an alkylene group, R³, having 2-3 carbon atoms; preparation processes of the derivatives; and herbicidal compositions containing one or more of the derivatives as an active ingredient.

公开(公告)号：EP0402893A1

公开(公告)日：1990-12-19

申请号：EP90111191.4

申请日：1990-06-13

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Oda, Kengo ,  Moriyasu, Koichi ,  Hayashi, Masao ,  Nishida, Makoto ,  Oyamada, Masami ,  Fujiwara, Akie ,  Watanabe, Junko

IPC分类号： C07D207/273 ,  A01N43/36

CPC分类号： C07D207/273 ,  A01N43/36

摘要： 1-(3-Substituted benzyl)-3-halogeno-4-(1-halogenoalkyl)-2-pyrrolidinones of the general formula (I):
where X represents a hydrogen atom or halogen atom, Y and Z each represents a chlorine atom or bromine atom, and R represents an alkyl group with 2 to 4 carbon atoms, are herbicides useful in rice paddy fields to control weeds therein, especially Echinochloa crusgalli and can be produced subjecting the corresponding 3-dihalogeno compounds to dehalogenation to remove one of the halogen atoms or by cyclizing a 2,2-dihalogenoacetamide derivative represented by the general formula (II) under the presence of an appropriate catalyst;
in which X, Y, Z and R respectively have the same meanings as described above.

摘要翻译： 通式（I）的1-（3-取代苄基）-3-卤代-4-（1-卤代烷基）-2-吡咯烷酮：其中X表示氢原子或卤原子，Y和Z各自表示 氯原子或溴原子，R代表具有2至4个碳原子的烷基，是用于稻田的除草剂以控制其中的杂草，特别是稗草，并且可以生产相应的3-二卤代化合物脱卤以去除 一种卤素原子或通过在合适的催化剂存在下环化由通式（II）表示的2,2-二卤代乙酰胺衍生物; 其中X，Y，Z和R分别具有与上述相同的含义。

公开(公告)号：EP0387869A3

公开(公告)日：1990-11-28

申请号：EP90104905.6

申请日：1990-03-15

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Oda, Kengo ,  Moriyasu, Koichi ,  Arai, Kiyoshi ,  Tomiya, Kanji ,  Miura, Tohru ,  Nishida, Makoto ,  Oyamada, Masami ,  Fujiwara, Akie

IPC分类号： C07D207/26 ,  A01N43/36

CPC分类号： C07D207/27 ,  A01N43/36

摘要： 4-Ethyl-3-(phenyl)-1-(3-trifluoromethylphenyl)-2-pyrrolidinones and corresponding compounds bearing a p-substituent on the 1-position phenyl group and/or a substituent on the 3-position phenyl group exhibit selective herbicidal activities against various weeds which cause problems in rice or upland fields, even at extremely low application rates. They can be prepared by reductive dehalogenation of a corresponding a-haloethyl substituted pyrrolidinone or reductive cyclization of a corresponding N-2-butenyl-N-(substituted phenyl)-haloacetyl-3-trifluoromethylaniline.

公开(公告)号：EP0379174A2

公开(公告)日：1990-07-25

申请号：EP90100924.1

申请日：1990-01-17

申请人： MITSUI TOATSU CHEMICALS, Inc.

发明人： Asano, Tamotsu ,  Ozawa, Shuji ,  Arai, Kiyoshi ,  Yamazaki, Hideo ,  Miura, Tohru ,  Gohbara, Masatoshi ,  Oyamada, Masami ,  Nishida, Makoto

IPC分类号： C07D307/78 ,  C07D409/12 ,  C07D407/12 ,  C07D405/12 ,  A01N43/12

CPC分类号： C07D307/79 ,  A01N47/02 ,  A01N47/06 ,  C07D307/82 ,  C07D307/83 ,  C07D405/12 ,  C07D409/12

摘要： Disclosed are novel 2,3-dihydro-3,3-dimethyl-5-trifluoromethanesulfonyloxy benzofurans and herbicides containing them, which are produced, e.g., via the mono-substituted 2-morpholino derivative, by reacting a corresponding 5-hydroxy benzofuran with a trifluoromethanesulfonyl esterifying agent.

摘要翻译： 本发明公开了新颖的2,3-二氢-3,3-二甲基-5-三氟甲磺酰氧基苯并呋喃获得和除草剂含有它们，这是产生的，例如，经由单取代2-吗啉衍生物，通过使相应的5-羟基苯并呋喃用 三氟酯化剂。