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    Preparation of naphtha by conversion of synthesis gas with a fluid catalyst which contains iron
    1.
    发明公开
    Preparation of naphtha by conversion of synthesis gas with a fluid catalyst which contains iron 失效
    石脑油的由合成气通过流动含铁催化剂的方法从反应制备。

    公开(公告)号：EP0012569A1

    公开(公告)日：1980-06-25

    申请号：EP79302804.4

    申请日：1979-12-06

    申请人： MOBIL OIL CORPORATION

    发明人： Butter, Stephen Allan ,  Sherry, Howard Samuel

    IPC分类号： C07C1/04 ,  B01J29/30

    CPC分类号： C10G2/334 ,  B01J29/40 ,  B01J2229/26 ,  B01J2229/42

    摘要： Process for converting synthesis gas in naphta by contacting it at 260-315,55 °C and 446,07-6996,09 kPa and at a GHSV of 400-20000 with a catalyst comprising a crystalline acidic aluminosilicate (ZSM-5) having a silica to alumina ratio of at least 12, a pore size greater than 5Å and a constraint index of 1 to 12, a soliceous matrix and iron; this catalyst is prepared by adding the zeolite to a siliceous hydrogel, homogenizing and spray drying the mixture and impregnating it with an iron salt (e.g. the nitrate). The catalyst may contain clay.

    摘要翻译： 处理用于通过在260接触而将合成气转化成石脑油至315.55℃，446.07到6996.09千帕，在400 GHSV至20,000与一种催化剂，包含结晶硅铝酸盐酸性具有（ZSM-5） 二氧化硅与至少12的氧化铝的比率，孔径大于5埃和1〜12的约束指数，一个soliceous矩阵和铁; 这种催化剂是通过将沸石硅质水凝胶，均质和喷雾干燥该混合物，并用食盐铁（例如，硝酸盐）浸渍了准备。 该催化剂“可能含有粘土。

    Catalyst and conversion of synthesis gas therewith
    4.
    发明公开
    Catalyst and conversion of synthesis gas therewith 失效
    催化剂及其合成气的转化中的应用。

    公开(公告)号：EP0012571A1

    公开(公告)日：1980-06-25

    申请号：EP79302806.9

    申请日：1979-12-06

    申请人： MOBIL OIL CORPORATION

    发明人： Butter, Stephen Allan ,  Chester, Arthur Warren

    IPC分类号： B01J29/34 ,  C07C1/04

    CPC分类号： C07C1/0445 ,  B01J29/40 ,  B01J29/46 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/46

    摘要： A catalyst and process for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 204-44°C (400°F) at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The process involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.

    Conversion of synthesis gas with iron-containing catalyst
    5.
    发明公开
    Conversion of synthesis gas with iron-containing catalyst 失效
    Umwandlung von Synthesegas mit Hilfe eines Eisen enthaltenden Katalysators。

    公开(公告)号：EP0012534A1

    公开(公告)日：1980-06-25

    申请号：EP79302666.7

    申请日：1979-11-22

    申请人： MOBIL OIL CORPORATION

    发明人： Butter, Stephen Allan ,  Schwartz, Albert B. ,  Chester, Arthur Warren

    IPC分类号： C07C1/04 ,  B01J29/06 ,  B01J23/74 ,  B01J37/00

    CPC分类号： B01J23/745 ,  B01J29/46 ,  B01J2229/26 ,  B01J2229/42 ,  C07C1/0425 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/46 ,  C10G2/334

    摘要： A catalyst useful for conversion of synthesis gas to naphtha is prepared by carbon of monoxide treatment of a single particle composite of iron oxide, hydrogel matrix and crystalline zeolite having a silica/alumina ratio greater than 12 and a constraint index of 1 to 12. The iron oxide is present in the composite as a powder, and may be created in situ by oxidation of iron powder. The carbon monoxide may be a component of synthesis gas. The product naphtha is characterised by specific details of boiling range and composition.

    摘要翻译： 可用于将合成气转化为石脑油的催化剂是通过一氧化碳处理碳氧化物，水凝胶基体和二氧化硅/氧化铝比大于12的约束指数为1至12的结晶沸石的一氧化碳处理的碳制备的。 氧化铁作为粉末存在于复合材料中，并且可以通过铁粉的氧化在原位产生。 一氧化碳可以是合成气的成分。 产物石脑油的特征在于沸点范围和组成的具体细节。