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    METHOD FOR PRODUCING HYDROGENATED PETROLEUM RESIN
    1.
    发明公开
    METHOD FOR PRODUCING HYDROGENATED PETROLEUM RESIN 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON HYDRIERTEMERDÖLHARZ

    公开(公告)号：EP3124503A1

    公开(公告)日：2017-02-01

    申请号：EP15768950.6

    申请日：2015-03-25

    申请人： Maruzen Petrochemical Co., Ltd.

    发明人： IIJIMA, Yoshikazu ,  KANAI, Koichiro ,  HAYASHI, Yasunori ,  HARUNA, Takeshi

    IPC分类号： C08F8/04 ,  C08F212/06 ,  C08F232/06

    CPC分类号： C08F8/04 ,  C07C2/42 ,  C07C2/50 ,  C07C2602/42 ,  C08F32/04 ,  C08F212/08 ,  C08F232/06 ,  C07C13/42

    摘要： A method for producing a hydrogenated petroleum resin by reacting dicyclopentadiene with a vinyl aromatic compound, subjecting the reaction product obtained by this reaction to thermal polymerization, and then hydrogenating the resulting product, including the following steps (A) to (C):
    (A) a preliminary reaction step of reacting a vinyl aromatic compound represented by the following Formula (1) (in the formula, R 1 is a hydrogen atom or the like) with dicyclopentadiene under the condition that selectivity for a phenylnorbornene derivative, which is a reaction product and is represented by the following Formula (2) {in the formula, R 1 has the same meaning as in the above Formula (1)}, is 90% or more to obtain a reaction liquid containing the phenylnorbornene derivative:
    (B) a polymerization step of heating the reaction liquid, which contains the phenylnorbornene derivative and is obtained in the preliminary reaction step (A), to a temperature of 240 to 300°C to polymerize the reaction liquid, thereby obtaining a polymerization reaction product; and
    (C) a hydrogenation step of hydrogenating the polymerization reaction product, which is obtained in the polymerization step (B), in the presence of a catalyst to obtain a hydrogenated petroleum resin.

    摘要翻译： 一种通过使二环戊二烯与乙烯基芳族化合物反应生成氢化石油树脂的方法，将通过该反应获得的反应产物进行热聚合，然后使所得产物氢化，包括以下步骤（A）至（C）：（A ）将下式（1）表示的乙烯基芳族化合物（式中，R 1为氢原子等）与二环戊二烯反应的反应步骤，其为选择性为苯基降冰片烯衍生物，其为反应 并且由下式（2）表示{式中，R 1与上述式（1）中的含义相同）为90％以上，得到含有苯基降冰片烯衍生物的反应液：（B） 在预备反应步骤（A）中将包含苯基降冰片烯衍生物的反应液加热到240-300℃的温度以使反应物聚合的聚合步骤 在液体上，从而获得聚合反应产物; 和（C）在催化剂存在下，在聚合工序（B）中得到的聚合反应产物氢化的氢化工序，得到氢化石油树脂。

    APPARATUS AND METHOD FOR PRODUCING CYCLIC CARBONATE
    4.
    发明公开
    APPARATUS AND METHOD FOR PRODUCING CYCLIC CARBONATE 有权
    VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON CYCLISCHEM CARBONAT

    公开(公告)号：EP3150588A1

    公开(公告)日：2017-04-05

    申请号：EP15800528.0

    申请日：2015-05-29

    申请人： Maruzen Petrochemical Co., Ltd.

    发明人： OSAKI, Kouzo ,  NANIKI, Takashi ,  HAYASHI, Yasunori ,  HARUNA, Takeshi

    IPC分类号： C07D317/38 ,  C07B61/00

    CPC分类号： C07D317/38 ,  B01J8/0457 ,  B01J2208/027 ,  C07B61/00 ,  Y02P20/544

    摘要： Provided are an apparatus and method for continuously producing a cyclic carbonate which are easily scaled up without requiring a large-sized reactor or excessive ancillary facilities even in the case of producing a cyclic carbonate by using an immobilized catalyst as a catalyst on an industrial scale, are able to produce a cyclic carbonate without impairing the expected catalytic efficiency and catalyst lifetime, are economical, and exhibit excellent industrial productivity. The apparatus includes an adiabatic reactor to be filled with a heterogeneous catalyst for reacting an epoxide with carbon dioxide, a circulation path for returning at least a portion of a fluid mixture in a liquid form flowed out through a reactor outlet into the reactor, a carbon dioxide supply means for continuously supplying carbon dioxide in a liquid form or a supercritical state into the circulation path, and an epoxide supply means for continuously supplying an epoxide in a liquid or solution form into the circulation path.

    摘要翻译： 提供了一种连续生产环状碳酸酯的装置和方法，即使在工业规模上使用固定化催化剂作为催化剂制备环状碳酸酯的情况下，也不需要大型反应器或过量的辅助设备而容易地放大， 能够生产环状碳酸酯而不损害预期的催化效率和催化剂寿命，是经济的并且表现出优异的工业生产率。 该装置包括用于使环氧化物与二氧化碳反应的非均相催化剂的绝热反应器，用于将至少一部分流出反应器出口的液体混合物的至少一部分返回到反应器中的循环路径，碳 用于将液态或超临界状态的二氧化碳连续供应到循环路径中的二氧化物供给装置和用于将液体或溶液形式的环氧化物连续供给到循环路径中的环氧化物供给装置。

    METHOD FOR MANUFACTURING CYCLIC CARBONATE
    5.
    发明公开
    METHOD FOR MANUFACTURING CYCLIC CARBONATE 有权
    VERFAHREN ZUR HERSTELLUNG VON CYCLISCHEN碳酸钙

    公开(公告)号：EP3023418A1

    公开(公告)日：2016-05-25

    申请号：EP14827134.9

    申请日：2014-07-18

    申请人： National Institute of Advanced Industrial Science and Technology ,  Maruzen Petrochemical Co., Ltd.

    发明人： TAKAHASHI, Toshikazu ,  YASUDA, Hiroyuki ,  YAMAMOTO, Shouji ,  NANIKI, Takashi ,  HAYASHI, Yasunori ,  HARUNA, Takeshi ,  FURUKAWA, Takuro

    IPC分类号： C07D317/36 ,  B01J31/02 ,  C07D317/38

    CPC分类号： C07D317/38 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0268 ,  B01J31/0269 ,  B01J2231/341 ,  C07D317/36 ,  Y02P20/142

    摘要： Provided is a method for producing a cyclic carbonate obtained by reacting epoxide and carbon dioxide, the method being capable of efficiently producing a cyclic carbonate at a high conversion rate and a high yield, in which degradation of the catalyst over time is suppressed and catalytic activity hardly decreases.
    A method for producing a cyclic carbonate by reacting epoxide and carbon dioxide in the presence of a quaternary onium salt selected from the group consisting of a quaternary ammonium salt having a halogenated anion as a counter ion and a quaternary phosphonium salt having a halogenated anion as a counter ion, or in the presence of a solid catalyst obtained by immobilizing the quaternary onium salt onto a carrier, wherein an organohalogen compound containing at least one halogen atom in one molecule is added to the reaction system.

    摘要翻译： 提供一种通过使环氧化物和二氧化碳反应得到的环状碳酸酯的制造方法，其能够以高转化率和高收率有效地制造环状碳酸酯，其中催化剂随时间的降低被抑制，催化活性 几乎没有减少。 一种环氧化物和二氧化碳在季铵盐的存在下，通过使季铵盐选自具有卤化阴离子作为抗衡离子的季铵盐和具有卤代阴离子的季鏻盐作为 或在通过将季铵盐固定在载体上得到的固体催化剂的存在下，其中在一个分子中含有至少一个卤素原子的有机卤素化合物加入到反应体系中。