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    COPOLYMER OF OLEFIN AND CONJUGATED DIENE, AND PROCESS FOR PRODUCING SAME
    5.
    发明公开
    COPOLYMER OF OLEFIN AND CONJUGATED DIENE, AND PROCESS FOR PRODUCING SAME 有权
    共聚物AUS EINEM OLEFIN UND EINEM KONJUGIERTEN DIEN SOWIE HERSTELLUNGSVERFAHRENDAFÜR

    公开(公告)号：EP2415792A1

    公开(公告)日：2012-02-08

    申请号：EP10758746.1

    申请日：2010-03-30

    申请人： Mitsui Chemicals, Inc.

    发明人： MICHIUE, Kenji ,  ISHII, Sei-ichi ,  MITANI, Makoto ,  KARINO, Takeshi

    IPC分类号： C08F210/02 ,  C08F4/645 ,  C08F4/6592 ,  C08F236/04

    CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F36/04 ,  C08F2420/02 ,  C08F4/6592 ,  C08F236/06 ,  C08F2500/03 ,  C08F2500/20 ,  C08F4/65904 ,  C08F4/65927 ,  C08F4/64113

    摘要： An object of the invention is to provide copolymers which have a double bond in a side chain and are substantially free of unsaturated bonds in the main chain, copolymers which have a cyclic structure and are substantially free of unsaturated bonds in the main chain, and processes for economically synthesizing these copolymers.
    A copolymer of the invention is obtained by copolymerizing at least ethylene and a conjugated diene. In the copolymer, structural units derived from the conjugated diene represent 1 to 90 mol%. Structural units resulting from 1,2-addition of the conjugated diene and having a side-chain double bond represent 0 to 90 mol%, structural units resulting from 1, 4-addition of the conjugated diene represent 0 to 3 mol%, structural units resulting from 1, 3-addition of the conjugated diene represent 0 to 3 mol%, and the total of structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopropane skeleton and structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopentane skeleton represent 4 to 100 mol%.

    摘要翻译： 本发明的目的是提供在侧链中具有双键并且在主链中基本上不含不饱和键的共聚物，具有环状结构且在主链中基本上不含不饱和键的共聚物，以及工艺 用于经济地合成这些共聚物。 本发明的共聚物是通过至少共聚乙烯和共轭二烯获得的。 在共聚物中，衍生自共轭二烯的结构单元表示1〜90摩尔％。 由共轭二烯的1,2-加成而具有侧链双键的结构单元表示0〜90摩尔％，共轭二烯的1,4-加成得到的结构单元为0〜3摩尔％，结构单元 由共轭二烯的1,3-加成得到的共轭二烯的含量为0〜3摩尔％，1,2-共轭二烯的1,2-加成和1,2-环丙烷骨架的结构单元总和由1 共轭二烯的2-加成1,2-环戊烷骨架为4〜100摩尔％。

    POLYMER AND PROCESS FOR PRODUCING THE SAME
    6.
    发明公开
    POLYMER AND PROCESS FOR PRODUCING THE SAME 有权
    POLYMER UND VERFAHREN ZU DESSEN HERSTELLUNG

    公开(公告)号：EP1241194A1

    公开(公告)日：2002-09-18

    申请号：EP01954350.3

    申请日：2001-07-26

    申请人： Mitsui Chemicals, Inc.

    发明人： KASHIWA, Norio ,  KOJOH, Shinichi ,  MATSUO, Shingo ,  SAITO, Junji ,  FUJITA, Terunori ,  MITANI, Makoto ,  TAKAHASHI, Mamoru ,  SATO, Yasuo

    IPC分类号： C08F290/00 ,  C08F10/00 ,  C08F4/60

    CPC分类号： C08F290/06 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F255/00 ,  C08F255/02 ,  C08F290/00 ,  C08F290/042 ,  C08F2420/02 ,  C08F4/64048 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/20 ,  C08F2500/11 ,  C08F210/14 ,  C08F4/65904

    摘要： The present invention relates to a polymer having a melt tension (MT (g)) substantially the same as or lower than that of a conventional polymer which is substantially the same as the polymer in the recurring unit of the main skeleton, the molecular weight, the molecular weight distribution and the crystallinity, and having a flow activation energy (Ea (KJ/mol)) larger than a value obtained by adding 5 KJ/mol to the Ea value of the conventional polymer. A preferred example 'of the polymer is a branched polyolefin comprising 50 to 100 % by mol of recurring units derived from ethylene and 0 to 50 % by mol of recurring units derived from an α-olefin of 3 to 20 carbon atoms and having the following properties: the flow activation energy (Ea (KJ/mol)) and the α-olefin content (C (% by weight)) satisfy a specific relation, and the melt tension (MT (g)) and the melt flow rate (MFR (g/10 min)) satisfy a specific relation. This branched polyolefin is excellent in moldability and mechanical strength.

    摘要翻译： 本发明涉及一种熔体张力（MT（g））基本上等于或低于常规聚合物的聚合物的聚合物，其与主骨架的重复单元中的聚合物基本相同，分子量， 分子量分布和结晶度，并且具有大于通过向常规聚合物的Ea值加入5KJ / mol获得的值的流动活化能（Ea（KJ / mol））。 聚合物的优选实例是包含50至100摩尔％的衍生自乙烯的重复单元和0至50摩尔％的衍生自3-20个碳原子的α-烯烃的重复单元并具有以下的支链聚烯烃 性质：流动活化能（Ea（KJ / mol））和α-烯烃含量（C（重量％））满足特定关系，熔体张力（MT（g））和熔体流动速率（MFR （g / 10分钟））满足特定关系。 该支化聚烯烃的成型性和机械强度优异。