摘要:
An improved process for the preparation of perfluoropropene oxide by the reaction of perfluoropropene with hydrogen peroxide in an aqueous alkaline medium, when the reaction is conducted in the presence of a phase-transfer catalyst selected from quaternary ammonium or phosphonium salts and lipophilic complexing agents for cations, and wherein the alkalinization of the reaction mixture is carried out in a gradual way so as to maintain the reaction temperature constant at a value from -10°C to -60°C.
摘要:
There are described silane quinacridone dyes, composite pigments obtainable therefrom by grafting onto an inorganic substrate or support, and processes for preparing the same. The dyes have the general formula: wherein
X is an -SO 2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, or a phenyl optionally substituted by one or more halogens or alkyl or alkoxy groups having from 1 to 6 carbon atoms; Y and Z indicate a silane group having the formula: wherein R, is an alkoxy group (C 1 -C 2 ); R 2 is an alkyl group (C,-C 4 ) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers such that when q is 1, p is 2 and m is 0, 1 or 2 and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an -S0 3 H group; a, b and c are 0 or 1, selected such that the sum a + b + c is equal to 1.
The composite pigments obtained from said dyes are used in paints, air enamels and stove enamels, in the pigmentation of plastics and in printing inks.
摘要:
There are described silane quinacridone dyes, composite pigments obtainable therefrom by grafting onto an inorganic substrate or support, and processes for preparing the same. The dyes have the general formula: wherein X is an -SO 2 NHR group, where R is an alkyl group, linear or branched, having from 1 to 6 carbon atoms, a cycloalkyl group, or a phenyl optionally substituted by one or more halogens or alkyl or alkoxy groups having from 1 to 6 carbon atoms; Y and Z indicate a silane group having the formula: wherein R, is an alkoxy group (C 1 -C 2 ); R 2 is an alkyl group (C,-C 4 ) or a phenyl group; n is 3, 4 or 5; q is 0 or 1; p and m are integers such that when q is 1, p is 2 and m is 0, 1 or 2 and when q is 0, p is 3 and m is 0, 1, 2 or 3; W indicates an -S0 3 H group; a, b and c are 0 or 1, selected such that the sum a + b + c is equal to 1. The composite pigments obtained from said dyes are used in paints, air enamels and stove enamels, in the pigmentation of plastics and in printing inks.