公开(公告)号：EP3056273A4

公开(公告)日：2017-08-09

申请号：EP14851906

申请日：2014-10-08

申请人： NAT INST OF ADVANCED IND SCIENCE

发明人： HIMEDA YUICHIRO ,  WANG WAN-HUI ,  MANAKA YUICHI ,  AMAMOTO YUKI

IPC分类号： B01J31/18 ,  C01B3/26 ,  C01B32/50 ,  H01M8/06

CPC分类号： B01J31/2295 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/22 ,  B01J2231/763 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/96 ,  B01J2540/10 ,  C01B3/22 ,  C01B3/26 ,  C01B31/20 ,  C01B32/50 ,  C01B2203/0277 ,  C01B2203/066 ,  C01B2203/1064 ,  C07F15/0033 ,  C07F15/0073 ,  H01M8/0612 ,  H01M8/0618

摘要： A catalyst including, as effective ingredient, complex represented by Formula (1) which contains bidentate ligand including aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms, or represented by Formula (2) which contains bidentate ligand including: aromatic heterocyclic 5-membered ring having 2 or more nitrogen atoms; and 6-membered ring having 1 or more nitrogen atoms, isomer or salt of the complex: where M 1 and M 2 denote transition metal such as iridium; X 1 to X 16 each independently denote nitrogen or carbon; R 1 to R 13 denote, for example, hydrogen atom, alkyl group, or hydroxy group, provided that when X i (where i denotes 13 to 16) is nitrogen, R i is absent at position corresponding to the nitrogen; L 1 and L 2 denote, for example, an aromatic anionic ligand; Z 1 and Z 2 denote any ligand or are absent; and m and n denote positive integer, 0, or negative integer.

摘要翻译： 一种催化剂，其含有式（1）所示的络合物作为有效成分，该络合物含有包含具有2个以上氮原子的芳香族杂环五元环的二齿配体或式（2）所示的含有二齿配体的芳香族杂环5- 具有2个或更多个氮原子的六元环; 以及具有1个或多个氮原子的6元环，该配合物的异构体或盐：其中M 1和M 2表示过渡金属如铱; X 1至X 16各自独立地表示氮或碳; R 1〜R 13表示例如氢原子，烷基或羟基，条件是当X i（其中i表示13至16）为氮时，R i在对应于氮的位置不存在; L 1和L 2表示例如芳族阴离子配体; Z 1和Z 2表示任何配体或不存在; m和n表示正整数，0或负整数。