METHOD FOR PRODUCING (METH)ACRYLATE
    8.
    发明公开
    METHOD FOR PRODUCING (METH)ACRYLATE 审中-公开
    生产(甲基)丙烯酸酯的方法

    公开(公告)号:EP3269700A1

    公开(公告)日:2018-01-17

    申请号:EP16761647.3

    申请日:2016-03-03

    发明人: HASHIMOTO, Naoki

    摘要: The present invention provides a method for producing a (meth)acrylate, which comprises the following steps. (Reaction step 1) A step for producing a (meth) acrylate by causing a transesterification reaction of an alcohol and a monofunctional (meth)acrylate with use of the catalyst A and the catalyst B described below in combination.
    Catalyst A: One or more compounds selected from the group consisting of cyclic tertiary amines having an azabicyclo structure, salts of the cyclic tertiary amines and complexes of the cyclic tertiary amines.
    Catalyst B: One or more compounds selected from the group consisting of compounds containing zinc. (Catalyst recovery step) A step for separating a solid that contains the catalyst A and/or the catalyst B from a reaction product containing a (meth) acrylate, said reaction product being obtained in the reaction step 1 and/or reaction step 2. (Reaction step 2) A step for producing a (meth)acrylate by causing a transesterification reaction of an alcohol and a monofunctional (meth)acrylate, while using, as a catalyst or as some of the catalyst, the solid that contains the catalyst A and/or the catalyst B and is obtained in the catalyst recovery step.

    摘要翻译: 本发明提供了生产(甲基)丙烯酸酯的方法,其包括以下步骤。 (反应工序1)使用后述的催化剂A和催化剂B,使醇与单官能(甲基)丙烯酸酯进行酯交换反应来制造(甲基)丙烯酸酯的工序。 催化剂A:一种或多种选自具有氮杂双环结构的环状叔胺,环状叔胺的盐和环状叔胺的络合物的化合物。 催化剂B:一种或多种选自含锌化合物的化合物。 (催化剂回收步骤)从包含(甲基)丙烯酸酯的反应产物中分离含有催化剂A和/或催化剂B的固体的步骤,所述反应产物在反应步骤1和/或反应步骤2中获得。 (反应工序2)在使用含有催化剂A的固体作为催化剂或作为催化剂的一部分的同时,使醇与单官能(甲基)丙烯酸酯进行酯交换反应来制造(甲基)丙烯酸酯的工序 和/或催化剂B并且在催化剂回收步骤中获得。