摘要:
In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having one or more sites capable of initiating copolymerization of epoxides and CO2, wherein the chain transfer agent contains one or more masked hydroxyl groups. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups, a high percentage of carbonate linkages, and substantially all polycarbonate chains having hydroxyl end groups have no embedded chain transfer agent.
摘要:
Chiral spirobiindane skeleton compound and preparation method thereof is disclosed in the present invention. The spirobiindane skeleton compound of the present invention having the structure formula of I or I'; the preparation method for synthesizing the spirobiindane skeleton compound of the present invention comprising the following steps: in the presence of solvent and catalysts, the structure formula compound III reacted through intramolecular Friedel-Crafts reaction to obtain the compound of formula I; the catalyst is a Browsteric acidor Lewis acid. The preparation method of chiral fused spirobiindane skeleton compound of the present invention does not need to adopt chiral starting materials or chiral resolving agents, does not require chiral resolving steps, is simple in method, is simple in post-treatment, and is economic and environment friendly. High product yield, high product optical purity and chemical purity. The catalyst for the asymmetric reaction is obtained from the chiral spirobiindane skeleton ligand of the present invention, under the catalytic reagent of transition metal, the catalyzed hydrogenation reaction can arrive at a remarkable catalytic effect with a product yield of >99%, and a product ee value of up to >99%.
摘要:
A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
摘要:
Disclosed is an effective thermal grease comprising a hyperbranched olefinic fluid and a thermally conductive filler. Property-modifying additives and fillers may also be included. The hyperbranched olefinic fluid is selected to have an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. The thermal grease exhibits a flash point of 180° C. or higher, a pour point of 0° C. or lower, and a kinematic viscosity at 40° C. of no more than 200 cSt (0.0002 m 2/s). The composition may offer improved thermal conductivity, reduced tendency to migrate, and lower cost when compared with many other thermal greases, including silicone-based thermal greases.
摘要:
The problems 1 to be solved by the present invention is to provide a modified solid poiyaikyialuminoxane capable of producing an ±-olefin suppressing adhesion of any Polymer produced as a by-product onto the reactor wall and the stirrer and capable of providing a highly active olefin oligomerization reaction catalyst, and an olefin oligomerization reaction catalyst including the modified solid polyalkylaluminoxane. The present invention relates to a modified solid polyalkylaluminoxane for olefin oligomerization reactions, that comprises structural units represented by the following general formula (a) and structural units represented by the hollowing general formula (b), and whose median diameter is equal to oe larger than 0.1 µm and equal to or smaller than 50 µm, in which 1 the general formula (a) represents an alkyl group having 1 to 20 carbon atoms, and R" in the general formula (b) represents a halogenated alkoxy group having 1 to 20 carbon atoms or a halogenated aryloxy group having 6 to 20 carbon atoms.
摘要:
The present invention relates to improved processes for the preparation of ruthenium or osmium complexes comprising acetate ligands, in particular, ruthenium complexes.
摘要:
Flooding compounds for telecommunications cables. Such flooding compounds contain a polymeric filler and a branched olefinic fluid. The branched olefinic fluid has an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. Additionally, the average number of carbons per molecule in the branched olefinic fluid is from 25 to 200.
摘要:
The present invention provides a method for producing a (meth)acrylate, which comprises the following steps. (Reaction step 1) A step for producing a (meth) acrylate by causing a transesterification reaction of an alcohol and a monofunctional (meth)acrylate with use of the catalyst A and the catalyst B described below in combination. Catalyst A: One or more compounds selected from the group consisting of cyclic tertiary amines having an azabicyclo structure, salts of the cyclic tertiary amines and complexes of the cyclic tertiary amines. Catalyst B: One or more compounds selected from the group consisting of compounds containing zinc. (Catalyst recovery step) A step for separating a solid that contains the catalyst A and/or the catalyst B from a reaction product containing a (meth) acrylate, said reaction product being obtained in the reaction step 1 and/or reaction step 2. (Reaction step 2) A step for producing a (meth)acrylate by causing a transesterification reaction of an alcohol and a monofunctional (meth)acrylate, while using, as a catalyst or as some of the catalyst, the solid that contains the catalyst A and/or the catalyst B and is obtained in the catalyst recovery step.
摘要:
A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R 5 and R 6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R 1 and R 2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R 1 and R 2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms), (B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated compound having a molecular weight of 400 or less, and (D): a polar compound.
摘要:
An electrically conductive hybrid material includes: a covalent organic framework having pores; and a conductor material, wherein the covalent organic framework is supported on the conductor material. The covalent organic framework that does not have electron conductivity is supported on the conductor material such as a carbon material, thereby can be given the electron conductivity, and becomes usable as such a catalyst material and such an electrode material, which involve the electron transfer, these materials including an electrode catalyst material of a fuel cell, and the like.