公开(公告)号：EP0340475A3

公开(公告)日：1991-10-02

申请号：EP89106179.8

申请日：1989-04-07

申请人： NIPPON OIL CO. LTD.

发明人： Harakawa, Michiharu ,  Sohda, Yoshio ,  Katoh, Kenji

IPC分类号： D01F9/145 ,  D01F9/24

CPC分类号： D01F9/145 ,  D01F9/24

摘要： A process for producing pitch-derived carbon fibers from pitch fibers produced by melt-spinning a carbonaceous pitch, which comprises adding a polyoxyethylene alkyl ether of the following formula [I]:
wherein R represents an aliphatic hydrocarbon having 8 to 12 carbon atoms and n represents an integer of 3 to 9,
as an emulsifier in an amount of 1 to 12 wt. %, based on an amino-modified silicone oil, to this oil having a molecular weight of 500 to 5,000 and an amine value of 2 to 15 to obtain an aqueous silicone emulsion and then applying the thus obtained emulsion to the pitch fibers when or before bundling the pitch fibers thereby adhering said oil to the pitch fibers in an amount of 0.01 to 0.8 wt. % based on the fibers.

摘要翻译： 通过熔融纺丝碳质沥青而制造沥青纤维的沥青衍生碳纤维的方法，其包括加入下式[I]的聚氧乙烯烷基醚：其中R表示 碳原子数8〜12的脂肪族烃，n表示3〜9的整数，作为1〜12重量％的乳化剂。 ％，基于氨基改性的硅油，得到分子量为500〜5000，胺值为2〜15的油，得到水性硅氧烷乳液，然后将这样得到的乳液施加到沥青纤维上或之前 将沥青纤维捆扎，从而将所述油以0.01至0.8重量％的量粘附到沥青纤维上。 基于纤维的％。

公开(公告)号：EP0149348B1

公开(公告)日：1989-04-26

申请号：EP84308872.5

申请日：1984-12-18

申请人： NIPPON OIL CO. LTD.

发明人： Uemura, Seiichi ,  Hirose, Takao ,  Sohda, Yoshio ,  Sakamoto, Takayoshi ,  Katoh, Kenji

IPC分类号： D01F9/14

CPC分类号： D01F9/155 ,  D01F9/15 ,  Y10T428/2967

公开(公告)号：EP0149348A3

公开(公告)日：1986-10-01

申请号：EP84308872

申请日：1984-12-18

申请人： NIPPON OIL CO. LTD.

发明人： Uemura, Seiichi ,  Hirose, Takao ,  Sohda, Yoshio ,  Sakamoto, Takayoshi ,  Katoh, Kenji

IPC分类号： D01F09/14

CPC分类号： D01F9/155 ,  D01F9/15 ,  Y10T428/2967

摘要： A process for producing pitch carbon fibers by subjecting pitch fibers obtained by melt-spinning a carbonaceous pitch to infusiblization treatment and then to carbonization treatment or both carbonization treatment and subsequent graphitization treatment, characterized in that a dimethyl polysiloxane having a viscosity at 25°C in the range of 12,000 to 1.000.000 cSt is applied to the fibers after the infusiblization treatment, and the infusiblized fibers with the dimethyl polysiloxane thus applied thereto are then subjected to the carbonization treatment or both the carbonization treatment and the subsequent graphitization treatment.

公开(公告)号：EP0340475A2

公开(公告)日：1989-11-08

申请号：EP89106179.8

申请日：1989-04-07

申请人： NIPPON OIL CO. LTD.

发明人： Harakawa, Michiharu ,  Sohda, Yoshio ,  Katoh, Kenji

IPC分类号： D01F9/145 ,  D01F9/24

CPC分类号： D01F9/145 ,  D01F9/24

摘要： A process for producing pitch-derived carbon fibers from pitch fibers produced by melt-spinning a carbonaceous pitch, which comprises adding a polyoxyethylene alkyl ether of the following formula [I]:
wherein R represents an aliphatic hydrocarbon having 8 to 12 carbon atoms and n represents an integer of 3 to 9,
as an emulsifier in an amount of 1 to 12 wt. %, based on an amino-modified silicone oil, to this oil having a molecular weight of 500 to 5,000 and an amine value of 2 to 15 to obtain an aqueous silicone emulsion and then applying the thus obtained emulsion to the pitch fibers when or before bundling the pitch fibers thereby adhering said oil to the pitch fibers in an amount of 0.01 to 0.8 wt. % based on the fibers.

摘要翻译： 通过熔融纺丝碳质沥青而制造沥青纤维的沥青衍生碳纤维的方法，其包括加入下式[I]的聚氧乙烯烷基醚：其中R表示 碳原子数8〜12的脂肪族烃，n表示3〜9的整数，作为1〜12重量％的乳化剂。 ％，基于氨基改性的硅油，得到分子量为500〜5000，胺值为2〜15的油，得到水性硅氧烷乳液，然后将这样得到的乳液施加到沥青纤维上或之前 将沥青纤维捆扎，从而将所述油以0.01至0.8重量％的量粘附到沥青纤维上。 基于纤维的％。

公开(公告)号：EP0149348A2

公开(公告)日：1985-07-24

申请号：EP84308872.5

申请日：1984-12-18

申请人： NIPPON OIL CO. LTD.

发明人： Uemura, Seiichi ,  Hirose, Takao ,  Sohda, Yoshio ,  Sakamoto, Takayoshi ,  Katoh, Kenji

IPC分类号： D01F9/14

CPC分类号： D01F9/155 ,  D01F9/15 ,  Y10T428/2967

摘要： A process for producing pitch carbon fibers by subjecting pitch fibers obtained by melt-spinning a carbonaceous pitch to infusiblization treatment and then to carbonization treatment or both carbonization treatment and subsequent graphitization treatment, characterized in that a dimethyl polysiloxane having a viscosity at 25°C in the range of 12,000 to 1.000.000 cSt is applied to the fibers after the infusiblization treatment, and the infusiblized fibers with the dimethyl polysiloxane thus applied thereto are then subjected to the carbonization treatment or both the carbonization treatment and the subsequent graphitization treatment.

摘要翻译： 通过将通过将碳质沥青熔融纺丝得到的沥青纤维进行浸渍处理，然后进行碳化处理或碳化处理和随后的石墨化处理来制造沥青碳纤维的方法，其特征在于，在25℃下的粘度为 在熔融处理后对纤维施加12,000〜1,000,000cSt的范围，然后将这样施加的二甲基聚硅氧烷的不熔融纤维进行碳化处理，或者进行碳化处理和随后的石墨化处理。