公开(公告)号：EP0922709A1

公开(公告)日：1999-06-16

申请号：EP98921862.3

申请日：1998-05-28

申请人： NOF CORPORATION

发明人： KITANO, Shigeru ,  OHTA, Toshihiko ,  SUZUKI, Hiroshi ,  HAYASHI, Akio ,  MURATA, Yoshishige ,  MATSUYAMA, Kazuo ,  NAKAMOTO, Kenichiro

IPC分类号： C07F9/6574 ,  C07F9/09

CPC分类号： C07F9/65742 ,  C07F9/091

摘要： A process for producing a (meth)acrylate derivative including reacting a compound of formula (1) (wherein R 1 is H or CH 3 ; A is C 1 -C 10 alkylene; and p is 1 to 10) with a chloro-dioxaphosphorus compound of formula (2) (wherein q is 0 or 1) in the presence of a secondary amine of formula (3) (wherein R 2 and R 3 are each C 3 -C 8 alkyl, cycloalkyl, C 6 -C 9 aryl, arylalkyl, etc.) to produce a (meth)acrylate derivative of formula (4) and further reacting the same with a tertiary amine of formula (5) (wherein R 4 , R 5 and R 6 are each C 1 -C 4 alkyl etc.) to provide a (meth)acrylate derivative of formula (6).

摘要翻译： 一种制备（甲基）丙烯酸酯衍生物的方法，包括使式（1）的化合物（其中R 1为H或CH 3; A为C 1 -C 10亚烷基; p为1-10）与氯二氧杂磷化合物 式（2）（其中q为0或1）在式（3）的仲胺存在下（其中R 2和R 3各自为C 3 -C 8烷基，环烷基，C 6 -C 9芳基， 芳基烷基等）以制备式（4）的（甲基）丙烯酸酯衍生物，并进一步使其与式（5）的叔胺反应（其中R 4，R 5和R 6各自为 C1-C4烷基等），得到式（6）的（甲基）丙烯酸酯衍生物。

公开(公告)号：EP0922709B1

公开(公告)日：2003-07-09

申请号：EP98921862.3

申请日：1998-05-28

申请人： NOF CORPORATION

发明人： KITANO, Shigeru ,  OHTA, Toshihiko ,  SUZUKI, Hiroshi ,  HAYASHI, Akio ,  MURATA, Yoshishige ,  MATSUYAMA, Kazuo ,  NAKAMOTO, Kenichiro

IPC分类号： C07F9/6574 ,  C07F9/09

CPC分类号： C07F9/65742 ,  C07F9/091

摘要： A process for producing (meth)acrylate derivatives, which comprises reacting a compound of general formula (1) (wherein R1 is H or CH¿3?; A is C1-C10 alkylene; and p is 1 to 10) with a chlorodioxaphosphorus compound of general formula (2) (wherein q is 0 or 1) in the presence of a secondary amine of general formula (3) (wherein R?2 and R3¿ are each C¿3?-C8 alkyl, cycloalkyl, C6-C9 aryl, arylalkyl, etc.) to prepare a (meth)acrylate derivative of general formula (4) and further reacting the same with a tertiary amine of general formula (5) (wherein R?4, R5 and R6¿ are each C¿1?-C4 alkyl etc.), thus providing a (meth)acrylate derivative of general formula (6).