摘要:
An electrolytic solution comprising N-(fluorosulfonyl)-N-(fluoroalkylsulfonyl)imide or di(fluorosulfonyl)imide, from which a residual solvent that affects the properties of the electrolyte solution material is reduced, is provided. A method for producing an electrolyte solution material containing fluorosulfonyl imide salt represented by the following general formula (1) and an electrolyte solution preparation solvent comprises decompressing and/or heating a solution containing the fluorosulfonyl imide salt and the electrolyte solution preparation solvent to volatilize a production solvent for the fluorosulfonyl imide salt.
In general formula (1), R 1 represents a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms, R 2 represents an alkali metal ion.
摘要:
The present invention provides a method of producing a tetracyanoborate-containing ionic compound in a milder condition more efficiently and less expensively than conventional methods, and a tetracyanoborate-containing ionic compound having a reduced content of impure components. An ionic compound of the present invention is represented by the following general formula (I), has a content of fluorine atom-containing impurities of 3 mol% or less per 100 mol% of the ionic compound, and a method for producing an ionic compound represented by the general formula (I) of the present invention comprises a step of reacting starting materials containing a cyanide and a boron compound.
(In the formula, Kt m+ denotes an organic cation [Kt b ] m+ or an inorganic cation [Kt a ] m+ ; and m denotes an integer of 1 to 3.)
摘要翻译:本发明提供了一种比常规方法更有效且低成本地生产含四氰基硼酸盐的离子化合物的方法,以及具有降低的不纯成分含量的含四氰基硼酸盐的离子化合物。 本发明的离子性化合物由下述通式(I)表示,每100摩尔%的离子性化合物的含氟原子的杂质的含量为3摩尔%以下,以及离子性化合物的制造方法 由本发明的通式(I)表示的方法包括使含有氰化物和硼化合物的原料反应的步骤。 (式中,Kt m +表示有机阳离子[Kt b] m +或无机阳离子[Kt a] m +,m表示1〜3的整数。
摘要:
Provided is a compound represented by Formula (1) below.
M a X b Y c (1)
(In Formula (1), M represents metal other than alkali metal, X represents -N(SO 2 F) 2 , Y represents a coordinating solvent, and a, b, and c are positive numbers.)
摘要:
A compound represented by the following formula (1):
wherein R 1 , R 2 and R 3 each independently represent fluorine, an alkyl group having 1 to 6 carbon atoms or a fluoroalkyl group having 1 to 6 carbon atoms; and M + represents an alkali metal ion.
摘要:
To provide a composition in which when the composition is formed into a solution, the clogging of a filter is less likely to be caused, and the solution can be filtered in a short time. A composition comprising: lithium bis(fluorosulfonyl)imide; and an impurity, wherein when the composition is dissolved in a mixed solvent obtained by mixing ethylene carbonate and ethyl methyl carbonate at a volume ratio of 3:7, to prepare a solution having a concentration of the lithium bis(fluorosulfonyl)imide of 1 M, and 50 mL of the solution is pressure-filtered at a pressure of 0.1 MPa using a membrane filter having a pore diameter of 0.2 µm and a filtration area of 47 mm φ, insoluble particles having an average particle diameter of 5 to 150 µm remain on the membrane filter.
摘要:
Provided is a method with which it is possible to conveniently produce bis(fluorosulfonyl)imide suitable as a nonaqueous electrolyte of a lithium ion secondary cell. The method for producing a bis(fluorosulfonyl)imide alkali metal salt of the invention is a production method for producing a bis(fluorosulfonyl)imide alkali metal salt by reacting bis(fluorosulfonyl)imide and an alkali metal halide in a reaction solution including an organic solvent, the method including a purification step for filtering out the bis(fluorosulfonyl)imide alkali metal from the solution after the reaction.
摘要:
Provided is a method the enables easy production of bis(fluorosulfonyl)imide suitable for a non-aqueous electrolytic solution for a lithium ion secondary battery, etc. The method for producing a bis(fluorosulfonyl)imide alkali metal salt according to the present invention comprises reacting bis(fluorosulfonyl)imide with an alkali metal compound in a reaction solution containing an organic solvent, wherein the organic solvent includes at least one organic solvent (A) selected from the group consisting of carbonate solvents, cyclic ether solvents, linear ether solvents having two or more oxygen atoms in the molecule, cyclic ester solvents, sulfolane solvents, N,N-dimethyl formamide, dimethyl sulfoxide, and N-methyl oxazolidinone.
摘要:
The objective of the present invention is to provide a clear conductive material with less turbidity, methods for producing and purifying the conductive material, and a nonaqueous electrolyte solution and an antistatic agent which contain the conductive material. The conductive material of the present invention comprises a fluorosulfonylimide salt represented by the following formula (1):
wherein X is F of a C 1-6 fluoroalkyl group, and at least one organic solvent selected from the group consisting of a carbonate solvent, an ester solvent, a ketone solvent and an alcohol solvent, wherein a concentration of the fluorosulfonylimide salt is 0.1 mol/L or more, and a turbidity is 50 NTU/mol-LiFSI or less; and the production method of the present invention comprises the step of filtering a solution comprising the fluorosulfonylimide salt and the organic solvent by using a filter medium comprising the specific material.
摘要:
The objective of the present invention is to provide an electrolyte solution of which electrolyte salt concentration is high and by which cycle characteristics hardly deteriorate and battery lifetime can be extended, and a lithium ion secondary battery which contains the above electrolyte solution. The electrolyte solution of the present invention comprises an electrolyte salt and a solvent, wherein a concentration of the electrolyte salt is more than 1.1 mol/L, the electrolyte salt contains a compound represented by the following formula (1) : (XSO 2 ) (FSO 2 )NLi (1) [wherein X is a fluorine atom, a C 1-6 alkyl group or a C 1-6 fluoroalkyl group], and the solvent contains a cyclic carbonate.