公开(公告)号：EP3175913A1

公开(公告)日：2017-06-07

申请号：EP15197992.9

申请日：2015-12-04

申请人： Paul Scherrer Institut

发明人： Casati, Nicola ,  Ban, Voraksmy ,  Lange, Michael

IPC分类号： B01J2/12 ,  B02C17/14 ,  B02C17/10 ,  B02C17/16 ,  B02C17/18

CPC分类号： B02C17/14 ,  B02C17/04 ,  B02C17/10 ,  B02C17/1805

摘要： It is an objective of the present invention to provide a mechanomechanical device improving the quality of the analytical measurements done by diffraction or other analytical techniques (e.g. spectroscopic ones) during ball milling processes.
This objective is achieved according to the present invention by a mechanochemical device (2) for mixing and/or reacting at least one chemical compound to at least one reaction product (4), comprising:
a) a grinding container (6) having a milling chamber (7), milling elements (8) and at least one probing chamber (10) wherein the at least one probing chamber (10) is realized as a recess volume (12) of said milling chamber (7) and wherein the recess volume (12) has a cross-sectional opening towards the milling chamber (7) that is smaller than the dimensions of the milling elements (8) preventing the milling elements (8) from entering into the recess volume (12); and
b) a motor (14, 16) coupled to the grinding container (6) in order to rotate the grinding container (6) thereby bringing the recess volume (12) at least temporarily into a position allowing a gravitation driven release of the at least one compound and/or the at least one reaction product (4) that entered the recess volume (12) back into the milling chamber.
This device enables measurements done in a small part called probe chamber being specifically designed for analytical techniques. The features of the present invention make sure that the reaction product and/or its precursors (the ration strongly depends on the progress of the reaction of the precursors) is quasi-permanently present in the probe chamber which allows for an quasi-permanent analysis on the progress/evolution of the desired mechanochemical-induced reaction.

摘要翻译： 本发明目的在于提供一个mechanomechanical设备改善期间球磨处理由衍射或其它分析技术（E. G.光谱的）所做的分析测量的质量的目的。 （6）具有一个铣削）粉碎容器：该目的用于混合和/或使至少一种化学化合物，至少一种反应产物（4）实现，其包括雅丁到本发明利用机械装置（2） 室（7），铣削元件（8）和至少一个探测worin所述至少一个探测室（10）被实现作为所述研磨室（7）的凹部容积（12）和worin凹部容积室（10） （12）具有朝向所述研磨室（7）是比没有研磨元件的尺寸（8）进入到凹部体积（12）防止所述铣削元件（8）更小的横截面开口; 和b）以至少暂时旋转粉碎容器（6），从而使所述凹部的体积（12）转换成允许在的重力驱动的释放的位置耦合到所述粉碎容器（6）的电机（14，16） 至少一种化合物和/或所述至少一种反应产物（4）并进入所述凹部的体积（12）返回到研磨室。 此设备允许在一小部分进行的测量称为样品室被专门用于分析技术而设计的。 本发明的特征使surethat的反应产物和/或它的前体（口粮强烈地依赖于前体的反应的进行）是准永久存在于样品室，其用于对准永久分析允许 所需的机械化学诱导的反应的进程/演进。